Advances in nanotechnologies and molecular assembly techniques have brought much attention to the problem of molecular wires studied with respect to disorder and to increased electronic connectivity. In this communication we aim to use the techniques of Random Matrix Theory (RMT) in the formalism of Free Random Variables (FRV) to analyze and predict electronic properties of one-dimensional disordered bridged molecular systems. We discuss possible application of the method in biological and chemical context. As an example, based on recent achievements in the theory of nonhermitian ensembles of random matrices, we outline here an efficient procedure to calculate electron transfer matrix in electron conducting disordered materials. The approach can be applied to the variety of problems like analysis of final state-selected spectra in unimolecular chemical reactions or population dynamics of biological species.
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.