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We report the use of laser-induced breakdown spectroscopy (LIBS) for determination of soil contamination due to effluents from the leather tanning industry in Kasur district of Punjab in Pakistan. The quantitative analysis was performed by making a calibration curve for Cr using LIBS spectral line at 427.48 nm. Chromium concentration of 839 mg·kg-1 in the vicinity of an effluent drain and 1,829 mg·kg-1 in the area of an old stagnant pool was found. The leaching of Cr due to seepage of industrial effluents from deteriorating bricklined drains in horizontal direction also was observed.
In the past 100 years, the annual global temperature has increased by almost 0.5ºC and is expected to increase further with time. This increase in temperature negatively affects the management of water resources globally as well as locally. Rain is an important phenomenon for agriculture, particularly in hilly areas where there is no feasible irrigation system. The present study is concerned with the analysis and modeling of the rain pattern, its variability, and prediction of monthly number of rainy days for the Abbottabad District, which is considered to be one of the greenest and most beautiful areas of Khyber Pakhtunkhwa, Pakistan, by incorporating both parametric and nonparametric techniques. Non-parametric statistical techniques are used for movement detection and significance testing; in this context, statistical tests were incorporated for inspection of homogeneity of rainy days among successive periods. A time series data for the period 1971-2013 was analyzed. Box Jenkins methodology and time series decomposition were applied for fitting the selected model, which was assessed for forecasting the monthly number of rainy days for 2015-2020. In this study several time series parametric and non-parametric approaches were applied to model rainfall data. The results showed that SARIMA (1, 0, 1) (0, 1, 1) was a better choice in predicting the monthly number of rainy days. Further analysis of the data suggests that January, March, May, July, and December have a considerable declining tendency in the number of rainy days.
This study combines air pollution tolerance index (APTI) and anticipated performance index (API) in order to determine the potential of trees and ornamental shrubs that are frequently growing on the roads of Quetta, Pakistan, and the campus of the University of Balochistan, in Quetta, for green belt development. Our investigation exposed that not only APTI is suitable for the fitness of trees for building green belts. It is used to categorize vulnerable plant species for only bio-monitoring. The grouping of APTI and API in the present study is a practical technique for decreasing air pollution control. Laboratory analysis for APTI was carry out by the four physico-biological factors such as leaf extract pH, total chlorophyll content, ascorbic acid content, and relative water content. API for different plant species (trees and ornamental shrubs) was determined depending upon the characteristic grading by allotted + or – to the plants. The standard for determining API is given in Table 2. For examining the relationships among these factors statistics were utilized. This study indicated that the APTI is used as an instrument for choosing suitable plants to reduce environmental urban heat. API designated that Morus alba L., Pinus halepensis Miller, Ficus carica L., and Pistacia vera L. with API = 6 are excellent performers for green belt development. Morus nigra L. and Malus pumila Miller had API 5 and are considered very good performers, and Fraxinus angustifolia Vahl., Prunus armeniaca L., and Platycladus orientalis L. showed 4 API values with good performance for green belt formation. All the other remaining investigated trees and ornamental shrubs demonstrated poor values of API and are not recommended for green belts as they act as bio-indicators. Data also exhibited that all the examined trees had higher API values then the ornamental shrubs. This study suggested that the integration of both APTI and API of plants is extremely beneficial for the construction of green belts.
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