After the WTO accession, Ukraine will face a new stage in trade relationships with traditional partners - EU countries. Due to the integration processes in Europe, the importance of structural changes in relationships between European Union and Ukraine is significant. The EU has enlarged to 27 member states, with Poland, Slovakia, Hungary and Romania all directly bordering Ukraine. At the same time, Ukraine comes back to the leading positions at the world agri-food markets. In this context, we analyse the main indexes of relative trade advantages.