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The kinetics of pyrite oxidation by Thiobacillus ferrooxidans bacteria were studied in different conditions of reaction (different size of pyrite sample relative to the leaching medium, medium pH and temperature). A model of the kinetics of the process has been proposed according to which it can be described by an autocatalytic reaction of order II, i.e. I order with respect to pyrite iron and I order with respect to the forming Fe(III) ions. On the basis of this model the rate constants and induction times of the reactions taking place in different conditions have been determined. The results obtained within the model enable us to show the optimum conditions of microbiological oxidation of pyrite.
This paper reports results of studies on the influence of the crystallographic mineral structure on the process of pyrite and marcasite leaching. Kinetic studies show that the crystallographic structure of minerals like FeS2 type does not influence the efficiency of the process.
Weathering – soil forming processes were studied on the spoil heaps of an abandoned pyrite mine in Wieściszowice (German: Rohnau, Lower Silesia, Poland). These heaps of waste material were formed during the 19th century, with the mining ceasing in 1902. The material was not homogenous texturally (loam and sandy loam layers) and did not show coloured genetic horizons. In the soil formations, the humus horizon was approximately 10 cm deep, and contained approximately 10% of organic matter in various stages of decomposition. The reaction in the whole soil profiles was acidic (pH approx. 4.0), and composition quartz, feldspars, chlorites and micas prevail in the mineral. Pyrite was not observed among the minerals, although secondary sulphate minerals were found such as: gypsum, jarosite, fibroferrite and iron oxides (mainly goethite). Clay minerals included chlorite, illitic material (K-mica and Na-mica), kaolinite and smectite as well as mixed-layered minerals of the mica/smectite type.
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