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Degradation of polyethylene was performed over MCM-41 molecular sieves modified with heteropoly acid H₃PW₁₂O₄₀ (HPW) and its caesium salt CsHPW₁₂O₄₀ (CsHPW). High silica zeolite ZSM-5 has also been used as degradation catalyst. The applied catalysts (HPW/MCM-41, CsHPW/MCM-41 and ZSM-5 zeolite) resulted in lowering of temperature of HDPE degradation when compared to the thermal pyrolysis as well as influenced the distribution of the products formed as a result of the cracking process. HPW/ MCM-41 use resulted in low amount of gas products and almost 80 wt.% of liquids while cracking over HZSM-5 produced gas hydrocarbons with selectivity about 50 wt.%. Liquid product obtained in the presence of HPW/MCM-41 comprised aliphatic hydrocarbons (olefins and paraffins) while cracking carried out over ZSM-5 zeolite resulted mainly in the formation of aromatic compounds.
The properties of materials made from the composite of potato starch and ethylene-co-acrylic acid with polyethylene or glycerine added in different amounts were studied. As it has been found, the increasing proportion of easily degradable starch composite increased its solubility in water, methanol and chloroform. Besides, water absorption and resistance to break also increased, but elongation at break and flow coefficient were reduced. The decreasing proportion of polyethylene reduced suitability of the material for commercial use, but in the majority of samples, the reduction was not linear. When polyethylene addition was reduced to 40-50%, the properties of the material obtained were still acceptable.
Insulation boards from thermoplastic bonded bark. Within this work, boards from thermoplastic bonded bark were made. Grinded bark of coniferous species and recycled polyethylene were used. Four variants of boards were manufactured: three of varying polyethylene weight ratio: 30, 40 and 50%, and fourth UF resin bonded. Assumed density of boards was 300 kg/m3, and thickness of 18 mm. Manufactured boards were examined for density, thermal properties, MOR, and swelling. Research has shown that production of insulation boards from PE bonded bark is possible. With the increase in thermoplastic weight ratio, thermal insulation of boards decreases, and their mechanical properties increases.
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