The value of the routine analyses, applied until present, of whole blood, serum and urine for bioelements is limited. The blood mineral level does not often correspond to the content of minerals in the whole body because the composition of plasma results from supplementation of deficiencies by different homeostatic mechanisms. Moreover, the blood concentration of bioelements is relatively low and depends on a current diet, therefore the diagnostic value of such analytical results may be fairly small. Studies have shown that the analysis of hair and nails are an appropriate alternative for blood and urine tests or for biopsy. Chemical treatments in agriculture, animal production and food processing introduce many food contaminants into the food chain. Organic methods in agriculture are safer and therefore very important. Nutrition based on organically produced foods and anthroposophic lifestyle can play an important role in health prophylaxis The objective of this study was to determine correlations between concentrations of 29 major and trace elements in cow’s milk and hair. The experimental material consisted of 33 cows of Polish Holstein-Fresian (HF) breed from three dairy organic farms. All the farms were located in one climatic zone and under similar soil conditions. The cows were kept in traditional tiedup barns. The feeding was traditional, with ration components given separately. The cows were grazed from May to October. Depending on pasture yield and availability of other feeds, the feeding ration was supplemented with hay, straw, silage and cereals. Samples of milk and hair for analyses of minerals were collected in September, i.e. during the pasture feeding. The hair was taken from the poll. The concentration of Ca, K, Mg, Na, P, S, B, Ba, Co, Cr, Cu, Fe, Ge, I, Li, Mn, Mo, Ni, Se, Si, Sn, Sr, V, Zn, Al, As, Cd, Hg, Pb was determined. The content of toxic elements in milk was low and below the admissible level. The statistically significant positive correlations between concentration in milk and in hair were detected for such elements as Ba, Ge, Mo and Pb. In the case of major elements K and Mg and trace elements Al, As, Co, Fe, Hg, Se, Sr, positive correlations were observed but they were not statistically significant. Negative correlations occurred for such elements as Cr, Cu, I, Li, Ni, S, Si, Sn, V and Zn. It was only for V and Zn that they were statistically significant. Very low values (near zero) of coefficient r were observed for Ca, Cd, Li, Mn, Na, Ni, P, S and Sn. It seems that broader investigations of mineral composition of cow’s hair could be useful for establishing reference values for some elements and would make a contribution to better animals’ welfare.
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