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Background. Fruit and vegetables have health and nutritional value, but can also be a source of toxic contaminants such as pesticide residues. Objective. The aim of this study was to evaluate presence of pesticide residues in fruit and vegetable crops from the central and eastern region of Poland in order to check the compliance of these products with the maximum residue levels’ (MRLs) requirements set in legal EU regulation for products present in the market. Material and methods. Samples of fruit and vegetables were obtained from production farms as a part of an official premarket monitoring of pesticide residues conducted on behalf of the Ministry of Agriculture and Rural Development, implemented in cooperation with the regional Inspectorates of Plant Health and Seed Inspection. The tests covered determination of 207 pesticides. Results. In 2014, a total of 317 samples of fruit and vegetables, collected from the central and eastern region of Poland, were analysed for the presence of pesticide residues. Pesticide residues were detected in 89 (28.1%) analysed samples: in 65 (38.2%) samples of fruit, and in 24 (16.3%) samples of vegetables. MRLs were exceeded in 2 samples (0.6%). Most often, the pesticide residues were found in gooseberry (100% of gooseberry samples) and apple (71.4%). Conclusions. Monitoring of pesticide residues in the agricultural crops at premarket stage should be continued to prevent market from the penetration by products with non-acceptable residues of pesticides and to protect consumers against excessive exposure to pesticide residues.
A method for the fast identification of trace levels of pesticide residues in agricultural crops was developed using low pressure gas chromatography/mass spectrometry (LP-GC/MS). The finalchromatographic determination took 12 minutes per sample while conventional GC/MS required at least 30 minutes. Also, improved peak shapes for dichlorvos, dimethoate, chlorothalonil, pirymethanil, pirimicarb, carbaryl, myclobutanil, flusilazole tebuconazole, fenarimol and iprodione were obtained which generally enabled lower limits of detection. The method was successfully applied to analysis of more than 40 pesticides in 120 samples of fruits, vegetables and cereals. With the aid of LP-GC/MS the number of samples analysed on the particular instrument could be at least doubled.
Silicon (Si) is the second most abundant element present in the lithosphere, and it constitutes one of the major inorganic nutrient elements of many plants. Although Si is a nonessential nutrient element, its beneficial role in stimulating the growth and development of many plant species has been generally recognized. Silicon is known to effectively reduce disease severity in many plant pathosystems. The key mechanisms of Si-mediated increased plant disease resistance involve improving mechanical properties of cell walls, activating multiple signaling pathways leading to the expression of defense responsive genes and producing antimicrobial compounds. This article highlights the importance and applicability of Si fertilizers in integrated disease management for crops.
Following the limitations regarding the use of the neonicotinoids: clothianidin, thiamethoxam and imidacloprid there are no currently available insecticide seed dressings for oilseed rape in Poland. For maize here is only one seed dressing containing methiocarb available with a very narrow registered scope of use. The impact of limitations on protection possibilities of other major Polish agricultural crops is either negligible or non-existent. In consequence a group of economically important insect pests of maize [dungbeetles (Melolonthidae); click beetles (Elateridae); noctuid moths (Agrotinae)] and oilseed rape [leaf miners (Agromyzidae), turnip sawfly (Athalia colibri Christ.), cabbage weevils (Curculionidae), cabbage root fly (Hylemyia brassicae Bche.), diamond-back moth (Plutella maculipennis Curt.)] is left without any legal possibility of chemical control. For the other important pests of the early growth stage of oilseed rape development, there are only pyrethroids available together with one product containing chloropiryfos that can be applied once per vegetation season. Since both maize and oilseed rape are grown in Poland on the area of approximately 1 million ha (each crop), this situation raises concerns about production possibilities as well as development of pest resistance.
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