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For the purpose of this work an epiphytic lichen species, Hypogymnia physodes (L.)Nyl., was used. Thalli of the lichen were treated with solutions of nitrate salts of heavy metals, including Zn(NO3)(2), Cu(NO3)(2), Pb(NO3)(2), and Cd(NO3)(2). To simulate the acid rain impact, pH of the metal mixture was lowered to pH 4, using Na2S2O5. Content of heavy metals was determined after a standard UV mineralization method (water solution) and burning method (in temperature 450 degreesC- thalli), using a Microcomputer Voltage-ammeter Analyser (MAW). After two months exposure of the lichen to the mixture of heavy metal nitrates it was ascertained that there was an increase of accumulation of Zn, Pb, Cu, and Cd in the thalli; a decrease of thalli pH caused increased uptake of toxic elements by the lichen; Pb and Cd remained mainly on the surface of the thalli and in the cell walls, whilst Zn and Cu penetrated to the protoplast.
The effect of aluminum complexation on the net decomposition rate of purified humic acid (HA) and fulvic acid (FA), extracted from a podzol B horizon in the Netherlands, were studied at room temperature (20°C). Net decomposition rates were determined from C02 evolution from samples as measured by gas-chromatography. Increasing aluminum additions significantly reduced the decomposition rate of HA, of FA ,and of organic matter in podzol B horizons, whereas pH had no notable effect on decompostion rates. Results indicate that at the current high depletion rates of organically-bound soil Al, due to acid rain, the decomposition of soil humic compounds may increase significantly. This may have serious consequences for the ecologically relevant pool of humic compounds in forest soils.
The concentrations of total iron were determined in the 30 rainwater samples collected at Gdynia station, located in the coastal zone of Gulf of Gdansk. The samples were assembled from December 2002 to November 2003. Total iron concentrations were measured using a colorimetric method with bathophenanthroline. The concentrations of major rain components (Na⁺, NO₃⁻-, Cl⁻, SO₄²⁻) were also determined. Concentrations of Fetot ranged from 0.26 μg·dm⁻³ to 0.51·10⁻³ μg·dm⁻³. The total annual flux of Fetot was 11.22 mg·m⁻²yr⁻¹, which suggests that wet deposition can be one iron source for phytoplankton in the Southern Baltic. Iron in rain came from both terrestrial areas and seawater. Particularly at E&SE winds the swash zone saturated with marigenic aerosols was a significant source of iron. In these causes an anthropogenic influence on rain acidification was found to be minimal.
Relatively little is known about the direct influence of acid rain (AR) on pro-and antioxidative changes in plant cells. Intercompartmental differences between cytosol and mitochondria were not studied before. Aboveground parts of plants treated with different pH variants of AR and prooxidative changes (lipid peroxidation) as well as antioxidative enzyme activities (ascorbate peroxidase, APx; glutathione peroxidase, GSH-Px) in the cytosolic and mitochondrial fractions were examined. The character of changes in antioxidative enzyme activities and of prooxidative alterations was closely connected with the cell com partment as well as with pH and time after treatment. The activity of both APx and GSH-Px increased more intensively in cytosol. Contrastingly, strong induction of lipid peroxides formation was observed in the mitochondrial fraction. The results suggest that cucumber mitochondria are more susceptible to oxidative damage caused by AR than cytosol. Antioxidative defense of cytosol appeared to provide sufficient protection against the oxidative stress imposed by AR.
The structure of the social wasp communities was studied in the forest areas of the Karkonosze Mts. transformed by acid rains in 1989 and 1994. A significant increase of species diversity (H') was observed in the season of the even year, which resulted from the increased competing interactions between queen mothers. Whereas the distribution of the species' number decreased together with the altitude proportionally to natural distribution of the species' number recorded in the Tatra Mts. On the other hand, the only significantly increased value in the dynamics of Vespinae density in vegetation zones of the Karkonosze Mts. was recorded for the lower subalpine forest. While observing the progressing successive restoration of forests, one can assume that the recorded structural changes in communities of social wasps represent their transitional state.
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Water quality challenges and impact

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Man’s activities on the environment often results in pollution and degradation of water bodies. Water bodies must therefore be jealously guided and protected from being polluted, which will affect water quality and availability for desired usage. Causes of water quality impairment are urban and rural storm water runoff, inadequate waste water treatment, nutrient entrophication, atmospheric deposition and acid rain, pollutant in sediments and fish, and nuisance aquatic weed growth and invasive species. Other factors include unhygienic disposal and inadequate treatment of human and livestock wastes, indecent management and treatment of industrial residues, inappropriate agricultural practices and unsafe solid waste discharge. Suggested strategies to combat water quality problems which should form the basis of policy solution for improving water quality include: (i) prevention of pollution; (ii) treatment of polluted water; (iii) safe use of waste water; and (iv) restoration and protection of ecosystem. It is recommended that our water bodies and the environment in general should be protected through appropriate legislation guidelines and public literacy campaign and mass education to sensitize, educate and make the people a fully environmentally literate society. Taking these steps internationally, nationally and locally will mean better water quality for our present society and future generation.
In 1990-1991 the total annual input of investigated ions (Ca²+, Mg²+, K+, Na+, NH4+, NO3-, Cl-, S04²-, PO4³-) with rainfall amounted to 16.0-18.7 g m-² y-1 (a high percentage of sulphate ions in Kraków, and magnesium, potassium, phosphorus, and ammonium ions at Polanka Haller). The input of sulphur (1.98-3.35 g m-2 y-1) was high in comparison with that noted in western and northern Europe. The input of nitrogen (0.44-0.58 g m-2 y-1) was relatively small. The reaction of precipitations was not acid (pH value on average 6.3) owing to the neutralising effect of alkali metals. The sum of ions in throughfall under oaks and beeches was on average nearly double, and under spruces 3-5 times as great as in rainfall.
Soot and hydrocarbons are usually found in diesel exhaust gases. They are formed when the fuel is burnt out incompletely. Polycyclic aromatic hydrocarbons (PAH) are sorbed on the soot, and may cause cancerous diseases, asthma and other diseases. The purpose of this work was to evaluate the dependence of smoke opacity and amount of polycyclic aromatic hydrocarbons in engine emissions on multi-component biodiesel fuel composition. We analyzed the composition of exhaust gases when diesel engine was fuelled with rapeseed oil methyl esters (RME ), RME mixtures with linseed oil methyl esters (LSME ) and fatty acid methyl esters (FA ME) of animal origin, assessing the smoke opacity and qualitative and quantitative composition of PAH. It was determined that smoke opacity of exhaust gases decreases at different rotation speeds (1200 and 2000 min⁻¹) when the amount of FA ME, containing a greater amount of saturated fatty acids, is increasing. Total PAH concentration in exhaust gases of biofuel mixtures with pork lard fatty acid methyl esters (LME ) is lower than in the case of mixtures with beef tallow fatty acid methyl esters (TME ). The amount of PAH at a rotation speed of 1200 min⁻¹ reduced down to 57%, if compared to pure RME , and down to 30%, when the rotation speed was 2000 min⁻¹. In the exhaust gases of biofuel mixtures with pork lard fatty acid methyl esters there are fewer PAHs with highly expressed mutagenic and carcinogenic effects if compared to pure RME and its mixtures, containing tallow fatty acid methyl esters. The most effective from an environmental point of view is use of a fuel mixture containing 80% RME , 4% LSME and 16% LME.
A three-year study (1991-1993) on the chemistry of streams was carried out in two valleys of different bedrock in the Polish Tatra Mountains. Significant seasonal fluctuations in the concentration of most of the studied elements of the granitic Waksmundzki and carbonate Miętusi Streams were observed. The chemistry of the Miętusi Stream was dominated by calcium and magnesium ions and the Waksmundzki Stream by sulphate ions. The drawing of general conclusions on changes in the stream chemistry over the last 30 years is impossible because of the different analytical methods used and only a single samplings of the stream water taken by the investigation carried out in the 60’s.
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