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The aim of this study was to determine the rate of removal of heavy metals depending on a treatment method applied to leachate from a municipal waste landfill. After the biological treatment, concentrations of Cu, Zn and Ni were observed to have increased. Application of the reagent Fenton caused further growth in Cu, Zn, and also Pb concentrations. The highest concentrations of Cu, Zn and Ni were observed when the Fe2+: H2O2 ratio in Fenton was 1:3. The lowest concentrations of these heavy metals were observed at a 1:5 ratio of Fe2+ : H2O2. The concentration lead, for example, was over 30-fold higher than in raw leachate. There was not correlation between the COD values in raw leachate or in biologically or chemically processed leachate and the concentrations of the analysed metals.
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Results of analyses of underground waters on a municipal landfill site conducted in 2004-2008, prior to leachate cleaning were presented and discussed in the paper. The sewage quality analysis comprised pH, electrolytic conductivity, TOC, Cr+6, Pb, Cd, Cu, Hg, Zn and PAHs. Results of leachate water testing were compared with standard values and subjected to comparative analysis taking into consideration also atmospheric precipitation amount. The aim of the paper was to assess the leachate water quality in conditions of exploited municipal landfill. The analyzed waters were characterized by variability of composition evidenced by increasing pH values, electrolytic conductivity and heavy metal concentrations (Cr, Hg) total organic carbon (TOC) and PAHs, but also by a decline in heavy metal contents (Pb, Cd, Cu and Zn).
The aim of the present study was to determine the influence of solid filling on the effectiveness of removal of organic substances (as COD) and ammonium from leachate from municipal landfills in SBR and SBBR reactors. The reactors worked on a laboratory scale reactors working under aerobic conditions at constant hydraulic retention time (HRT) of 3 d.COD values in outflow were similar: on average 635 mg O2·dm-3 (SBR) and 646 mg O2·dm-3 (SBBR). Regardless of the presence or absence of filling, nitrate dominated in the effluent. The average concentration was 693 mg NNQ3·dm3·h-1 in SBR and 699 mg NNQ3·dm3 in SBBR. The concentrations of ammonium and nitrite were low, less than 2.9 mg NNH4·dm-3 and 0.5 mg NNO2·dm-3 (SBR), and 3.2 mg NNH4·dm-3 and 0.3 mg NNO2·dm-3 (SBBR). The results indicate that the presence of solid filling did not influence the effectiveness of nitrification in activated sludge.
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