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Opracowano i sprawdzono na pilotowej instalacji w skali technicznej metodę oczyszczania ścieków pestycydowych pochodzących z mycia aparatury ochrony roślin na uaktywnionym chemicznie pyle lotnym. Oczyszczalnia pracuje w obiegu zamkniętym - oczyszczana woda jest używana do ponownego mycia sprzętu agrochemicznego lub przyrządzania nowych roztworów roboczych. Pozytywne wyniki testów biologicznych pozwalają na rolnicze wykorzystanie mieszaniny osadu poreakcyjnego z wapnem nawozowym.
The aim of this study was to estimate the long-term effect of orcharding utilization on the total content of Cu, Zn, Mn, Fe and their available forms in soils. For the investigation three apples tree orchards planted on the Cambisols from the Brda Valley Region were selected. The content of Cu and Zn in the humus horizon was much higher than in parent material due to the anthropogenic pollution. In the analyzed soils it was observed that, total Cu and Zn content and DTPA-extractable Cu, Zn, Mn, Fe was statistically positively correlated with the content of organic carbon. The content of DTPA-extractable Cu to the total content of Cu was high and reached up to 24,6% at the humus horizon. It was stated, that available forms of copper, manganese and iron was statistically positively correlated with the acid reaction. The total content of Cu, Zn, Mn and Fe did not exceed acceptable concentrations for uncontaminated soils.
Opracowano metodę oczyszczania ścieków alkaliczno-olejowych oraz ich regeneracji. Skuteczność oczyszczania roztworu myjącego z zanieczyszczeń olejowych i zawiesiny stałej, jak i możliwości regeneracji ubytku środków myjących oraz własności myjących takiego roztworu sprawdzono na prototypowym stanowisku w ZNMR Słupsk w skali technicznej.
In the present study, local background concentrations of heavy metals were determined in soils which have been minimally influenced by human activities. The ground moraine landscape of the Inowrocławska Plain is dominated by Phaeozems, which occur in numerous associations with Luvisols and Cambisols. Four profiles of Phaeozems, three profiles of Luvisols and two profiles of Cambisols had been researched earlier, especially their morphology, selected physicochemical properties, texture and mineralogical composition. Selected properties were also measured to determine their influence on the content and distribution of trace elements in soil profiles. For determination of the concentration of metals in the soil profiles, the following indices were used: distribution factor (DI), enrichment factor (EF) and transfer factor (TF). The total content of metals in the genetic horizons and the local geochemical background level of metals in soils were determined. With the knowledge of the natural content of elements in the parent material, assumed to be the geochemical background, a degree of contamination of surface soil horizons can be evaluated. The content of Zn, Cu, Ni, Pb, Cr, Mn (mg kg–1) and Fe and Ti (g kg–1), which was defined as the content of the local background, was: 40.6; 12.6; 14.3; 12.9; 5.5; 309.9 and 16.5; 1.4, respectively. The distribution of Ni, Cr, Cu, Mn and Fe in the soil profiles can be explained as the effect of pedogenic factors, although in the case of, a tendency towards accumulation of Zn and Pb in the humus horizons as a result of anthropogenic input was observed. The distribution of pedogenic Ni, Cu, Cr and Mn was influenced by specific adsorption of metals on Fe oxides. The results indicate that the metals were bound more strongly to iron oxides than to organic matter. Based on the results of geochemical studies on selected arable soils from the Iowrocławska Plain, an integrated method was applied to assess the local background using an iterative 2s-technique (mean + 2 standard deviation). The relationships between trace elements and the conservative element such as Fe were used to predict the expected values of trace elements in topsoil. The results substantiate the importance of determining local background concentrations.
Soil richness in available magnesium, phosphorus and potassium forms is one of the key factors of fertility, which ensures the potential of soil for satisfying nutritional requirements of plants. The aim of the present research has been to determine the effect of crop rotation and varied mineral and organic fertilisation on the content of available Mg, K and P forms. Soil was sampled from a long-term experiment, carried out on Luvisol formed from sandy loam (soil valuation class IVa, very good rye complex). The experiment was performed in a 3-factor design, which included two types of crop rotation as well as FYM and nitrogen fertilisation. Basic physicochemical properties of soil were determined. The content of available forms of magnesium was defined with Schachtschabel method and the content of potassium and phosphorus – with Egner-Riehm method (DL). The reaction in the arable-humus horizon of the soils ranged from 4.7 to 6.2. It was found that the Corg to Nt ratio in the arable-humus horizon of soils of all the experiment variants was typical of biologically active soils. The content of available magnesium ranged from 27.8 to 58.3 mg kg–1 of soil, while its water-soluble forms varied from 3.5 to 6.8 mg kg–1 of soil. The highest content of magnesium, potassium and phosphorus forms available to plants was observed after the application of FYM in the doses of 60 and 80 t ha–1 combined with mineral nitrogen fertilisation, in both crop rotation regimes. The content of magnesium and phosphorus forms available to plants was significantly positively correlated with the content of organic carbon. Soil sampled from those plots demonstrated higher classes of the content of that element. The research data proved that the analysed soils showed moderate and high richness in nutrients available to plants. High doses of organic and mineral fertilisation, however, did not increase significantly the electrolytic conductivity of the soil solution.
Some trace elements, because of their high capacity for bioaccumulation, can pose a threat to the adequate development and growth of plants, animals and humans, which concerns mostly mercury (Hg) and its compounds that characterize by strong toxic properties. The aim of the research was to compare the Hg content in the Arenosols of arable fields (food plots), referred to as hunting plots, as well as in the soils of neighbouring forests. Research was performed in the Szubin Forest District (northern Poland). To assess the effect of mercury on the environment, we used dandelion (Taraxacum officinale) as a bioindicator. The samples were collected from the soil profiles from 8 hunting plots and 8 woodland areas in close vicinity of these plots. Mercury was assayed with the atomic absorption spectrometry applying the AMA 254 analyser. The mercury contamination factor (CF) and the potential ecological risk index (Er) values were determined with the local Hg value of the geochemical background (5.7 µg/kg). Assuming such very low Hg concentration as the reference value for the parent material of the soils, the mean CF value points to a considerable anthropogenic mercury accumulation in the surface horizons. The soils of hunting plots as well as forest soils are not contaminated with mercury. The total Hg content falls within the natural content level and reaches in the mineral horizons – from 3.5 to 20.7 µg/kg, while in the litter layer – from 60.3 to 166.7 µg/kg. The mercury bioconcentration factor (BCF) and translocation factor (TF) values point to a clear accumulation in the aboveground parts of dandelion. We found a significantly positive correlation between the content of mercury and organic carbon as well as the clay fraction. The mercury content in the soils under study varies and it depends on the soil origin and the effect of anthropogenic factors. In the forest soils of the Pomorze and Kujawy Province the mercury content of the geochemical background is relatively low. The areas of the Szubin Forest District do not undergo an excessive anthropopressure and sources of Hg depositions in soil surfaces can be the deposition of mercury from air.
Na podstawie profilowego rozmieszczenia form żelaza określono wskaźniki pedo- i litogenezy dla niecałkowitych gleb płowych z Pojezierza Dobrzyńskiego.
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