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Nanofiltration of cork wastewaters and their possible use in leather industry as tanning agents

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Geraldes V., Minhalma M., De P. M. N., Anil A., Ozgunay H., Bitlisli B. O., Sari O.

Polish Journal of Environmental Studies

2009

tom 18

nr 3

353-357

Cork processing wastewater is a very complex mixture of vegetal extracts and has, among other natural compounds, a very high content of phenolic/tannic colloidal matter that is responsible for severe environmental problems. In the present work, the concentration of this wastewater by nanofiltration was investigated with the aim of producing a cork tannin concentrate to be utilized in tanning. Permeation results showed that the permeate fluxes are controlled by both osmotic pressure and fouling/gel layer phenomena, leading to a rapid decrease of permeate fluxes with the concentration factor. The rejection coefficients to organic matter were higher than 95%, indicating that nanofiltration has a very good ability to concentrate the tannins and produce a permeate stream depleted from organic matter. The cork tannin concentrate obtained by nanofiltration and evaporation had total solids concentration of 34.8 g/l. The skins tanned by this concentrate were effectively converted to leather with a shrinking temperature of 71℃ .

Ograniczanie wyników

1 Polish Journal of Environmental Studies

1 Anil A.

1 Bitlisli B. O.

1 De P. M. N.

1 Geraldes V.

1 Minhalma M.

1 Ozgunay H.

1 Sari O.

1 2009

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Nanofiltration of cork wastewaters and their possible use in leather industry as tanning agents