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In this work are presented the results of investigations related to total and sulphate sulphur contents in humus horizon of arable soils of 15 Poznań province and their soil reaction. On the basis of obtained results it was found that analysed soils of municipalities contained from 9.0 to 182.0 mg total S/100 g of soil. The data follows that the content of total sulphur was differentiated not only between soils of researched municipalities but also in limit of each other. The quantitative differences of sulphate sulphur, which one content range from 0.03 to 19.7 mg S-SO₄/100g of soil corresponded with the differentiation of total sulphur. Soil reaction of the researched soils like sulphur was differentiated and ranged from pH 3.8 to 7.9.
Advances in nanotechnologies and molecular assembly techniques have brought much attention to the problem of molecular wires studied with respect to disorder and to increased electronic connectivity. In this communication we aim to use the techniques of Random Matrix Theory (RMT) in the formalism of Free Random Variables (FRV) to analyze and predict electronic properties of one-dimensional disordered bridged molecular systems. We discuss possible application of the method in biological and chemical context. As an example, based on recent achievements in the theory of nonhermitian ensembles of random matrices, we outline here an efficient procedure to calculate electron transfer matrix in electron conducting disordered materials. The approach can be applied to the variety of problems like analysis of final state-selected spectra in unimolecular chemical reactions or population dynamics of biological species.
The principal aim of the report was to determine the values of the stability constants of vitamin С complexes with metals (II). The values obtained with the most popular methods: spectrophotometric, Potentiometrie, and Polarographie, were compared and contrasted. It was found that all the values were comprised within the range of 105 to 1010, with very small differences between the values determined by the three methods. Determination of the values of the stability constants may find application in other branches of science.
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