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The study presents the results obtained following the analysis of the so-called Granger causality between daily and monthly temperatures of air and water for the period 1987–2013 carried out for the Noteć river and its two main tributaries: Drawa and Gwda. Granger causality relates to a situation where the data concerning past values of one time series provide important information helping to predict values of another series not included in the information about its past values. The analysis was based on the Granger causality test (of the first order). A causality relationship was established for daily temperature series both for the air-water and water-air directions of influence, which means that forecasting the pattern of river water temperatures from changes to air temperatures can yield better results when done based on data from the previous day. The model forecasting daily water temperature in the Noteć river on the basis of water and air temperatures from the previous day explained 0.07–0.27% of unique variance more than the model that used only water temperature from the previous day. The model forecasting the daily air temperature based on air and water temperatures from the previous day explained 0.3–0.79% of the variance more than the model, which uses only the air temperature from the previous day. For monthly series of water and air temperatures, different configurations of correlations in terms of Granger causality were established: one-way in water-air direction or no correlation, which may result from the river water thermal regime being disturbed by the local impact of anthropogenic factors. In addition, the analysed effect of Granger causality between series of random fluctuations of both temperature models confirmed that causal dependencies occur in both directions. The identification of causal relationships in terms of Granger causality confirms the influence of one data series on the evolution on another data series, and it defines the application potential of study results for the purpose of forecasting the changeability of thermal parameters of river waters. The obtained results may help improve the quality of forecasting changes in water thermal conditions, which is important for managing their environmental condition properly.
Our study attempts to determine the influence of bacterial reduction on sulphate concentrations in groundwaters. A buried valley in a southeastern section of the Gwda River drainage basin was selected for fieldwork near the towns of Wysoka and Bądecz. Deep aquifers in the area are known for their high sulphate concentrations that result from pyrite oxidation by the Thiobacillus denitrificans bacteria. Isotope compositions of SO₄²⁻ ions show ³⁴S enrichment at lower sulphate concentrations, which might indicate bacterial reduction processes. Theoretical curves of SO₄²⁻ isotope composition and ion concentration change, drawn using a Rayleigh formula and the results of the determination of δ¹⁸O (SO₄²⁻) and δ³⁴S (SO₄²⁻) suggest widely varying intensities of the sulphate reduction processes. It can be estimated that bacterial reduction eliminated between 30% and in excess of 50% of the initial concentrations of SO₄²⁻ ions in individual cases.
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