Municipal refuse may increase heavy metal concentration in soil, even at low levels, and their resulting long-term cumulative health effects are among the leading health concerns all over the world. In this study, we investigated the concentration of heavy metals in soils and edible plant leaves grown in an abandoned dumpsite along Akachi road in Owerri municipality. The soil samples were collected at each plot using a soil auger at the depth of 0-10 cm. Leaves of dominant edible plant species were selected and collected from each sample plot. The samples were dried in an oven with forced air at 40°C, milled to fine powder then digested with 10 ml concentrated HNO3 and 5 ml concentrated HClO4 and were analyzed for Cr, Cu, Fe, Mn, Al, and Zn, using an H183200 MultiParameter Bench Photometer. Result showed that metals in in the sampled soils included (in order of quantity) Cr: 150-280 >Fe: 116.50-203 >Cu: 12.4-18.8 >Mn: 0-20 >Al: 0.08-0.16 >Zn: 0-1.4 mg kg-1 Dw. Moreover, levels of metals in the edible plant leaves are in the order of: Zn>Fe>Cu>Al>Mn>Cr. Zn, in particular, was higher than FAO/WHO recommended limits. Still, application of Pollution Load Index and Ecological risk models showed that the area is unpolluted and safe for use. Daily Metal Intake estimates indicated that zinc is mostly consumed from the plant species. The trends in Transfer Factor for the heavy metal in vegetable samples studied were in order: Zn>Al>Cu>Mn>Fe>Cr. Therefore, abandoned solid waste dumpsites contained significant concentrations of heavy metals which are later absorbed and accumulated by plants growing it.
With increasing population and human activities, dumpsites experience diverse sources of waste with potential radiation hazards. Ionizing radiations have often been overlooked amongst researchers in third world countries, hence, information in this regard is lacking. In this study, nine dumpsites within Imo State University (IMSU) grounds were assessed for radiation levels using Geiger Muller counter Tube Mullard type ZP 1481 with assisted scalar and stopwatch. After calibration, the instrument was placed one meter above ground level and count rates recorded at 10 minutes interval for each location once in the morning, the afternoon and the evening for seven days. Results reveal higher dose equivalents in some morning periods than in the afternoon and evening. Site ETF2 had highest value of 0.69±0.08 mSv·yr-1, while Extension gate had lowest value of 0.56±0.01 mSv·yr-1. Compared to National Council for Radiation Protection maximum permissible level, these values are quite low. In conclusion, ionizing radiations levels at the studied dumpsites in Imo State University grounds are low and may not pose a threat to persons within the university.
The leaves of mistletoe (Viscum album) harvested from oil bean tree (Pentaclethra macrophylla) in Imo State South Eastern Nigeria was studied. The study was aimed at carrying out trace metal, Fourier Transform Infra-red (FTIR) and phytochemical analysis of ethanol leave extracts of Viscum album harvested from Pentaclethra macrophylla. The sample for trace metal analysis was digested with a mixture of concentrated HNO3 and HClO4 at a ratio of 1:1 for 24 hours. Ethanol was then used to extract the sample meant for FTIR and phytochemical analysis. Herein, trace metal determination indicates the presence of Mg, Zn, Fe, Cu and Cr, and the concentration of Ca and Mn is at < 0.00 mg/kg. The result of the phytochemical screening demonstrates the presence of flavonoids, alkaloids, phenols, saponins and tannins. FTIR analysis confirmed the presence of alcohols, amides, aromatics and carbonyl compounds in ethanol extracts of Viscum album harvested from Pentaclethra macrophylla. The presence of some trace metals and phytochemicals, as well as some important functional groups in the plant sample, as indicated by the result of the study, authenticates its use in traditional medicine.
Environmental pollution has resulted in several health and physiological problems in both plants and animals. This has witnessed growing number of models for assessment purposes. Some of these provide useful information, and reduce large data for easier understanding by policy-makers. In the current study of pollution, we used data from four locations: Oil Market, Trans Amadi, Borrokiri and GRA in Port Harcourt and a control taken from Federal Land Resource Umuahia (FLRU). A total of 25 composite soil samples were analyzed for physicochemical parameters and heavy metals, by means of a 969 Unicam AAS model series. The data obtained were then subjected to index models. Results showed iron (Fe) to be most abundant metal, ranging from 10.44 to 19.54 mg/kg, then Ni (8.03 to 13.6mg/kg), Cd (3.96 to 5.41 mg/kg), Pb (1.36 to 7.64 mg/kg), Zn (0.09 to 7.24 mg/kg), Cu (0.16 to 0.32) and As (0.07 to 0.11 mg/kg). All metal concentrations were below permissible limits set by NESRA. Contamination factor (Cf) and Igeo revealed moderate to heavy contamination by Cd and Zn. Anthropogenicity revealed that increasing metals in the environment are largely from anthropogenic inputs. The Pollution Index revealed that soils were unpolluted (PLI < 1) with the heavy metals. Furthermore, the Sodium absorption ratio showed that the soils are less sodic and could be good soils for plant growth. All four sites showed a linear relationship between anthropogenicity and geoaccumulation indexes, and so both indexes furnish basically the same information However, pollution from these metals in the study area should be under routine check for possible pollution in the near future, as some metals showed elevated concentrations above background values.
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