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Przedstawiono wyniki badań pozostałości pestycydów chloroorganicznych i polichlorowanych bifenyli (PCB) w tkance tłuszczowej zwierząt, mleku i jajach pobranych z terenu całego kraju w latach 1990-1994.
The occurrence and concentrations of organochlorine pesticides and polychlorinated biphenyls (PCBs) were determined in 158 muscle samples of bream (Abramis brama) and roach (Rutilus rutilus), and 84 samples of sediments collected from 10 river and lake sampling sites in 2011 and 2012. The concentrations of DDTs (p,p'-DDT, o,p'-DDT, p,p'-DDE, and p,p'-DDD), HCH isomers (α-, ß-, and γ-HCH), HCB, and PCBs (six indicator PCB congeners 28, 52, 101, 138, 153 and 180) were determined using the capillary gas chromatography. The mean concentrations of DDTs in bream and roach were in the range of 11.2-654 and 4.5-121 µg/kg wet weight respectively, and PCBs were in the range of 1.3-75.9 and 1.1-112 µg/kg wet weight, respectively. Mean concentrations of DDTs and PCBs in sediments were 0.5-270 µg/kg dry weight and <0.1-2.2 µg/kg dry weight respectively. The study showed clear spatial differences in the levels of organochlorine pesticides and PCBs in fish and sediments from different aquatic ecosystems. The highest levels of contaminants were detected in fish and sediments from the Vistula River in vicinity of Cracow. The possible risk to the fish meat consumers and ecological risk were evaluated.
The paper presents the results of monitoring of PCB residues in food of animal origin for the 12 year period of 1997-2008. The residue control plan included analysis of PCB congeners IUPAC No 28, 52, 101, 118, 138, 153 and 180 in a variety of food samples. The residue control program exists in accordance with Council Directive 96/23/EC and legislation of the Ministry of Agriculture and Rural Development. The residue examinations are performed by the National Veterinary Research Institute in Puławy (National Reference Laboratory) and Veterinary Inspection Laboratories (ZHW) located in Białystok, Gdańsk, Katowice, Poznań, Warsaw and Wrocław. The determinations of PCB congeners were conducted using capillary gas chromatography with electron capture detection. Over the period of 12 years residues of PCB congeners were determined in 19 767 samples. The examinations involved the adipose tissue of pigs, cattle, sheep, horses, game (wild boar, roe deer, and deer), chickens, geese, turkeys, ducks and rabbits, farmed fish muscles, cow milk, eggs, honey and import food (mainly marine fish). More than 35% of the samples were found to contain low concentrations of PCBs. In swine and poultry tissues the lowest frequency of PCB residues has been noted. The following highly chlorinated congeners were most frequently detected: PCB 153, PCB 138 and PCB 180. The mean concentrations of indicator PCB congeners were higher in fish and game animals then in other animal species. Generally the levels of PCB congeners were several times lower in comparison to the permitted maximum residue limits in other countries. The regular testing within the national residue control program indicates that Polish food of animal origin contains low levels of these contaminants and is safe for consumers.
Przedstawiono wyniki badań pozostałości pestycydów chloroorganicznych i polichlorowanych bifenyli (PCB) w serach twarogowych i serach twardych dojrzewających pobranych z terenu całego kraju. Potwierdzono opinię o niskim skażeniu chlorowanymi węglowodorami aromatycznymi mleka i przetworów mleczarskich w Polsce.
The paper presents the results of monitoring pesticide residues in food of animal origin for the 10-year-period of 1997 – 2006. The control plan included the analysis of organochlorine pesticides, organophosphorous compounds, pyrethroids, and carbamates in a variety of food samples: fat, muscle and liver from different animal species, milk, eggs and honey. The residue program exists in accordance with Council Directive 96/23/EC and legislation of the Ministry of Agriculture and Rural Development. The residue examinations are performed by the National Veterinary Research Institute in Puławy (National Reference Laboratory) and Regional Veterinary Inspection Laboratories (ZHW) located in Białystok, Gdańsk, Katowice, Poznań, Warsaw and Wrocław. Over the period of 10 years more than 24 500 samples were tested for pesticide residues in all food commodities and only a few samples were non-compliant. The occurrence of organochlorine pesticides was recorded quite frequently, although their concentrations were comparatively low, even several times lower in comparison to the permitted maximum residue levels (MRL). The residues of other groups of pesticides were detected in none of the tested samples. Regular testing within the national residue control program indicates that Polish food of animal origin contains low levels of these contaminants and is safe for consumers.
Przedstawiono wyniki badań pozostałości pestycydów chloroorganicznych i polichlorowanych bifenyli ( PCB) w jajach kur przyzagrodowych i fermowych pobranych z terenu całego kraju. Oznaczone stężenia porównano z wynikami prac wcześniejszych.
Przedstawiono wyniki badań pozostałości pestycydów chloroorganicznych i polichlorowanych bifenyli (PCB) w mleku krowim z terenu całego kraju. Oznaczone stężenia porównano z wynikami prac wcześniejszych.
A method for simultaneous determination of residues of six organophosphorus pesticides in animal liver samples has been developed and validated. The method is based on the extraction of organophosphorus pesticides with a mixture of acetone-petroleum ether, clean up on a gel permeation chromatography, further clean up on a small silica gel column, and finally determination by gas chromatographx with flame photometric detection. The recovery, investigated by analysing blank liver samples spiked with chlorpyrifos-methyl, chlorpyrifos, diazinon, parathion, and pirimiphos-methyl at levels of 5, 25, 50, and 75 µg/kg, and with chlorfenvinphos at levels of 5, 10, and 15 µg/kg, ranged from 75.6% to 107.5%. Performance characteristics, such as repeatability and within-laboratory reproducibility, expressed as coefficient of variation, were less than 20%, and uncertainty <21%. Linearity ranged between 5 and 1,000 ng/mL. The limits of quantification were 5 µg/kg for all compounds and allowed determination of residues below the MRLs set by the European Union. The satisfacton z-score results of international proficiency tests confirmed good accuracy, reproducibility, and reliability of the developed method.
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