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2000 | 26 |

Tytuł artykułu

Contact angle and surface free energy of selected peat-moorsh soils

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Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
Surface free energy and contact angle for peat-moorsh soils were determined on soil samples consisted of two kinds of moorsh formations, i.e., peaty moorsh (Z1) and proper moorsh (Z3). The samples represented peat soil mass in different state of its secondary transformation, so they essentially differed in values of W1 index. In study a thin-layer (TLW) technique based on Wash- burns equation was used. For this purpose the penetration rate of n-alkanes and diodomethane were measured. If the content of humous compounds in the soil exceeds 40%, wetting rate measurements can only be performed using apolar liquids, such as diiodomethane and alkanes. Polar liquids, on the other hand, such as water or formamide, do not penetrate porous soil layers. This shows that the tested material displays only dispersion-type surface interactions. Therefore, for "mor" and peat soils, the technique of thin-layer wicking with n-octane could only be used to determine the dispersive component . The investigated peat soil no exhibit a polar interactions because the water does not penetrate into yiLW the sample. For the peaty-moorsh soils only dispersive surface free energy components can be determined by the technique of thin-column wicking (TCW). Contact angles can be calculated from the determined dispersive surface free energy components and water surface tension by Young equation. Ranges of water contact angles for peat-moorsh soils are 97.5°<9 <102.0°.

Wydawca

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Rocznik

Tom

26

Opis fizyczny

p.75-83,fig.

Twórcy

autor
  • Polish Academy of Sciences, Doswiadczalna 4, 20-290 Lublin, Poland

Bibliografia

  • 1. Busetti S.Ci., Tschapek M.: Thermodynamics of water vapour adsorption by mixtures of mont- morillonite and humate. Geoderma 8, 281-290, 1972.
  • 2. Chibowski E.: Solid surface free energy components determination by the thin-layer wicking technique, J. Adhesion Sci. Technol., 6 (9): 1069-1090, 1992.
  • 3. Chibonski E., Gonzales-Caballero F.: Theory and practice of thin-layer wicking, Langmuir 9; 330, 1993.
  • 4. Chibowski E., Hotysz L.: Use of the Washburn equation for surface free energy determination, Langmuir 8:710-716, 1992.
  • 5. Dragunov S.S., Bogdanov G.V. Perrase E,: Viscosity and surface tension of humate solutions, Kolloid 7,h„ 8: 397-400, 1946.
  • 6. Ehrenberg, P., and Schultz K.: The difficulty of wetting dust and fine powders, Kolloid Z., 15: 183-192, 1914.
  • 7. Fowkes F.M: Attractive forces at interface, Ind, Eng. Chem., 56: 12, 56:40, 1964.
  • 8. Fowkes F.M.: I lydrophobic Surface, Acad.Press, New York, London, 1969.
  • 9. Gawlik J.: The useful Ines of water holding capacity index for evaluation of the state of secondary transformation of the peat soils (in Polish). Wiad. IMUZ, XV111 (4), 197-216, 1996.
  • 10. Grood R.J., Chaudhury M.K.: Theory of adhesive forces across interfaces, 1. The Lifshitz-van der Waals component of interaction and adhesion. Fundamentals of adhesion. (Ed. L.H.Lee) plenum Press, N.Y., 1991.
  • 11. Hajnos M.: Surfacc energy and its components as parameters determining wettability and aggregation stale of selected clay minerals and soils (in Polish). Acta Agrophysica 17, 3-112, 1999,
  • 12. Ramann E.: Bodenkunde, 4 Aufl., Springer, Berlin, 619, 1911,
  • 13. Stadnikov Neue Torfchemie, Steinkopff, Dresden, 167, 1930.
  • 14. Stelwaag A.: Untersuchungen über Temperaturhohung verschiedener Bodenkonstituenten und Bodenarten bei Kondensation von flussigem und dampfformigem Wasser sowie von Gasen, Forsch. Geb. Agrikult. Physik. 5: 210-228, 1982.
  • 15. Tschapek M.: Zur phys.-chemischen Erscheinung des Benstzungswiderstandes von Torf gegen Wasser, Kolloid-Z., 66: 91-95, 1934
  • 16. Tschapek M., Pozzo Ardizzi C., de Bussetti S.G.: Wettability of humic acid and its salts, Z. Pflanzenemnachr. Bodenkd., 135(1): 16-31, 1973.
  • 16, van Oss C.J.: Interacial Forces in Aqueous Media, Marcel Dekker, Inc., New York, 1994.
  • 17, Wladychenskij S.A.: Colioidehemieal properties of soil humus. Kolloid-Zh. 6: 683-694, 1940.
  • 18, Zisman W.A,: Influence of constitution on adhesion, ln.Eng.Chem., 55(10): 18-38, 1963.

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Bibliografia

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