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2006 | 15 | 3 |

Tytuł artykułu

Decomposition of detergents present in car-wash sewage by titania photo-assisted oxidation

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
Advanced oxidation process (AOP) has been shown to be effective in water and air decontamination. Ultraviolet-oxidation has been evaluated for most contaminants. In this work UV/TiO₂/O₂ version of AOP method was used to decompose surfactants and, applied in car washing installations, commercial products. The influence of such parameters like the amount of TiO₂ catalyst's dose, the acidity of aqueous solution and the type of applied UV lamp were examined. Additionally, in order to evaluate the effects associated with photocatalysis, studies of the contributions like adsorption of surfactants on catalysts and photooxidation were undertaken. photocatalytic oxidation of Cleentex aqueous solution was investigated, using TiO₂ and 10% - Tio₂/SiO₂ as catalysts The most efficient process appeared to occur in weakly basic solution pH = 8.9 with TiO₂ catalyst dose about 1.5 g dm⁻³. The photo-efficiency of UV lamps should be verified in order to avoid the excessive losses of light power. All detergents showed a high affinity for photocatalytic decomposition and final degree of COD reduction was in the range 35-60 %, depending on detergent composition. The degree of TOC reduction was slightly lower.

Wydawca

-

Rocznik

Tom

15

Numer

3

Opis fizyczny

p.457-465,fig.,ref.

Twórcy

autor
  • Institute of Applied Radiation Chemistry, Wroblewskiego 15, 93-590 Lodz, Poland
autor
autor
autor

Bibliografia

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  • 10. HORIKOSHI S., WATANABE N., ONIHI H., HIDAKA H., SERPONE N., Photodecomposition of nonylphenol polyethoxylate surfactant in a cylindrical photoreactor with TiO₂ immobilized fiberglass cloth. Applied Catalysis B: Environmental 37, 117, 2002.
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  • 16. HIDAKA H., ZHAO J., SATOH Y., NOHARA K., PELIZZETTI E., SERPONE N., Photodegradation of surfactants. Part XII: Photocatalyzed mineralization of phosphorus – containing surfactants at TiO₂/H₂O interfaces. Jurnal of Molecular Catalysis 88, 239, 1994.
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Typ dokumentu

Bibliografia

Identyfikatory

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