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2006 | 15 | 4 |

Tytuł artykułu

Removal of hazardous metals from groundwater by reserve osmosis

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
This EPA treatment technology project was designed to collect data on the performance of existing water treatment processes in order to remove arsenic on pilot-scale. Our paper contains verification testing of the reverse osmosis membrane module conducted over a 30-day period at the Spiro Tunnel Bulkhead water (Park City, Utah, USA), which is considered to be a ground water. The total arsenic concentration in the feedwater averaged 60 ppb during the test period and was reduced to an average of 1 ppb in the treated (permeate) water. The work reported here focused on obtaining accurate readings for arsenic valence states (III) and (V), using an anion exchange resin column. The dominant arsenic species in the abandoned silver mine tunnel feedwater was As(V). Results of analysis showed that 70% of the arsenic present in the feed- water was in dissolved form. Arsenic speciation for valence states (III) and (V) showed that arsenic (V) represented 76% of the dissolved arsenic in the source water. The method detection limit (MDL) for arsenic using ICP-MS was determined to be 0.1 ppb. Our matrix spiked recovery, spiked blank samples and refer­ence materials deviated only a few percentage points from the listed true values.

Wydawca

-

Rocznik

Tom

15

Numer

4

Opis fizyczny

p.579-583,ref.

Twórcy

autor
  • University of Technology and Agriculture, 3 Seminaryjna Street, 85-326 Bydgoszcz, Poland
autor
autor

Bibliografia

  • 1. BODZEK M., KONIECZNY K. Using membrane processes in water purification, Scientific Publishing Projprzem-EKO: Bydgoszcz, pp 65-197, 2005 (in Polish).
  • 2. OH J. I., YAMAMOTO K., KITAWAKI H., NAKAO S., SUGAWARA T., RAHMAN M. M., RAHMAN M. H. Ap­plication of low-pressure nanofiltration coupled with bicycle pump for the treatment of arsenic-contaminated ground wa­ter. Desalination 132, 307, 2000.
  • 3. SEIDEL A., WAYPA J. J., ELIMELECH M. Role of charge (Donnan) exclusion in removal of arsenic from water by a negatively charge porous nanofiltration membrane. Environ. Eng. Sci. 18, 105, 2001.
  • 4. BRANDHUBER P., AMY G. Alternative method for mem­brane filtration of arsenic from drinking water. Desalination 117, 1, 1998.
  • 5. VAN der BURGGEN B., VANDECASTEELE C. Removal of pollutants from surface water and groundwater by nano- filtration: overview of possible applications in the drinking water industry. Environ. Poll. 122, 435, 2003.
  • 6. WAYPA J. J., ELIMELECH M., HERING J. G. Arsenic removal by RO and NF membranes. J. Am. Water Works Asoc. 89, 102, 1997.
  • 7. BERG M., TRAN H. C., NGUYEN T. C., PHAM H. V., SCHERTENLEIB R., GIGER W. Arsenic contamination of groundwater and drinking water in Vietnam: a human health threat. Environ. Sci. Technol. 35, 2621, 2001.
  • 8. CHATTERJEE A., DAS D., MANDAL B. K., CHOWD- HURY T. R., SAMANTA, G., CHAKRABORTI D. Arsenic in ground water in six districts of West Bengal, India: the biggest arsenic calamity in the world. Part I. Arsenic spe­cies in drinking water and urine of the affected people. The Analyst 120, 643, 1995.
  • 9. CHEN C. J., CHEN C. W., WU M. M., KUO T. I. Cancer potential in liver, bladder and kidney due to ingested in­organic arsenic in drinking water. Brit. J. Cancer. 66, 888, 1992.
  • 10. CHRISTEN K. The arsenic threat worsens. Environ. Sci. Technol. 35, 286A, 2001.
  • 11. LEPKOWSKI W. Arsenic crisis in Bangladesh. Chem. Eng. News 76, 27, 1998.
  • 12. USA MCL, 2006. MCL will be 10 ppb on January 2006, now is 50 ppb.
  • 13. Health and Welfare Canada. Guidelines for Canadian Drink­ing Water Quality, Arsenic, August 1992.
  • 14. KARIM M. Arsenic in groundwater and health problems in Bangladesh. Water Res. 34, 304, 2000.
  • 15. SMITH A. H., GOYCOLEA M., HAQUE R., BIGGS M. L. Marked increase in bladder and lung cancer mortality in a region of Northern Chile due to arsenic in drinking water. Am. J. Epidemiol. 147, 660, 1998.
  • 16. CULLEN W. R., REIMER K. J. Arsenic speciation in the environment. Chem. Rev. 89, 713, 1989.
  • 17. Method 200.8, 1994. Determination of Trace Elements in Water and Wastes by ICP/MS. U.S. EPA Report # 600/R-94- 111, 1994.
  • 18. Method 200.7, 1994. Determination of Metals and Trace Elements by ICP/AES. U.S. EPA Report # 600/R-94-111, 1994.
  • 19. CLIFFORD D., CEBER L., CHOW S. Arsemc(III)/arsemc(V) separation by chloride-form ion-exchange resins. Proceed­ings of the XI AWWA Water Quality Technology Conference (WQTC), December 1983, Norfolk, VA, pp 223-236, 1984.
  • 20. EDWARDS M., PATEL S., McNEILL L., CHEN H., FREY M., EATON, A. D., ANTWEILER R. C., TAYLOR H. E. Considerations in As analysis and speciation. J. Am. Water Works Asoc. 90, 103, 1998.
  • 21. EDWARDS M. Chemistry of arsenic removal during coagu­lation and Fe-Mn oxidation. J. Am. Water Works Asoc. 89, 64, 1994.
  • 22. FICKLIN W. H. Separation of arsenic (III) and arsenic (V) in groundwaters by ion exchange. Talanta 30, 371, 1982.
  • 23. Battelle, February 2000. Evaluation of Treatment Technolo­gies for the Removal of Arsenic from Drinking Waters: Iron Removal. Report prepared for US EPA, 2000.
  • 24. EATON A., WANG H. C., NORTHINGTON J. Analytical Chemistry of Arsenic in Drinking Water [Project No. 914]. American Water Works Association Research Foundation (in: Batelle, 2000 cit. AWWARF Project 914, 1997), 1998.
  • 25. NSF Report 01/20/EPADW395, March 2001. Environmental Technology Verification Report. Removal of Arsenic in Drink­ing Water. Electronic copy available on EPA website: http:// www.epa.govetv or NSF website: http://www.nsf.org/etv.
  • 26. NSF Report 01/23/EPADW395, September 2001. Environ­mental Technology Verification Report. Removal of Arsenic in Drinking Water. Electronic copy available on EPA website: http://www.epa.gov/etv or NSF website: http://www.nsf.org/etv.
  • 27. NSF Report 01/25/EPAWD395, August 2001. Environmental Technology Verification Report. Removal of Arsenic in Drink­ing Water. Electronic copy available on EPA website: http:// www.epa.gov/etv or NSF website: http://www.nsf.org/etv.
  • 28. NSF Report No. 01/26/EPADW395, March 2001. Environ­mental Technology Verification Report. Removal of Arsenic in Drinking Water. Electronic copy available on EPA web­site: http://www.epa.gov/etv or NSF website: http://www. nsf.org/etv.
  • 29. Park City SWTP. http://www.parkcity.org/citydepartments/ water/projects/.

Typ dokumentu

Bibliografia

Identyfikatory

Identyfikator YADDA

bwmeta1.element.agro-article-712dace0-0b5a-44be-85ab-cbfa48f036bf
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