PL EN


Preferencje help
Widoczny [Schowaj] Abstrakt
Liczba wyników
2003 | 12 | 5 |

Tytuł artykułu

Seasonal variation in the chemical composition and morphology of aerosol particles in the centre of Katowice, Poland

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
PM-2.5 and PM-10 samples were collected in the centre of Katowice, Poland during February to May 2001. They were analyzed by gravimetry, X-ray photoelectron spectroscopy and scanning electron microscopy combined with an energy dispersive spectrometer and electron paramagnetic resonance. The combination of these methods allows us to analyze elemental composition, size and morphology of more than three hundred individual atmospheric particles. The composition of the aerosol particles is strongly influenced by meteorological conditions such as wind speed and direction. Mineral elements mainly existed in large-size particles. The anthropogenic pol­lution elements, however, are contained in corpuscles (< 2 ^m). In comparison with the situation in the wintertime, the number of particles rich in some heavy metals in springtime was found to be lower. The EPR spectra are complex and their features correspond to: I type: Cu2+ centra in a low-symmetry host site, II type: radical species in the soot, which appears as the paramagnetic pyrolyzed product.

Wydawca

-

Rocznik

Tom

12

Numer

5

Opis fizyczny

p.619-627,fig.

Twórcy

autor
  • University of Silesia, 4 Uniwersytecka St., 40-007 Katowice, Poland
autor
autor
autor

Bibliografia

  • 1. WAWROŚ A., TALIK E., PASTUSZKA J.S. Investigation of aerosols from Świętochłowice, Pszczyna and Kielce by XPS method. J. Alloys Comp. 328, 171, 2001.
  • 2. PASTUSZKA J.S., WAWROŚ A., TALIK E., PAW U K.T. Optical and chemical characteristics of the atmospheric aerosol in four towns in southern Poland. Sci. Total Envi­ron., submitted.
  • 3. JABŁOŃSKA M., RIETMEIJER F.J.M., JANECZEK J. Fine-grained barite in coal fly ash from the Upper Silesia Industrial Region. Environ. Geol. 40, 941, 2001.
  • 4. WAWROŚ A., TALIK E., PASTUSZKA J.S. Investigation of winter atmospheric aerosol particles in downtown Kato­wice using XPS and SEM. Microsc. Microanal., submitted.
  • 5. LIGHTY J.S., VERANTH J.M., SAROFIM A.F. Combus­tion aerosols: factors governing their size and composition and implications to human health. J. Air Waste Manage. As­soc. 50, 1565, 2000.
  • 6. MOULDER J.F., STICKLE W.F., SOBOL P.E., BOMBEN K.D. Handbook of X-ray Photoelectron Spectroscopy Phys­ical Electronics, 1995.
  • 7. SMART J.V. Rare Earths. Mineral Information Leaflet No2. Department of Mines and Energy, The State of Queensland, 1999. http:/www.nrm.gld.gov.au/mines/rarearth.pdf
  • 8. ZHANG D., IWASAKA Y., BAI Y., SHI G. Aerosol par­ticles around Lhasa City, Tibet, China, in summer 1988: Individual particle analysis. J. Aerosol Sci. 31 (Suppl. 1), 319, 2000.
  • 9. SOBANSKA S., COEUR C., PAUWELS B., MAENHAUT W., ADAMS F. Micro-characterisation of tropospheric aero­sols from the Negev Desert, Israel. J. Aerosol Sci. 31 (Suppl. 1), 344, 2000.
  • 10. EBERT M., WEINBRUCH S., HOFFMANN P., ORTNER H.M. Chemical characterisation of North Sea aerosol par­ticles. J. Aerosol Sci. 33, 613, 2000.
  • 11. MIRANDA R.M., ANDRADE M.F., WOROBIEC A., GRIEKEN R.V. Characterisation of aerosol particles in Sao Paulo Metropolitan. Area. Atmos. Environ. 36, 345, 2002.
  • 12. ANDRADE F., ORSINI C., MAENHAUT W. Relation between aerosol source and meteorological parameters for inhalable atmospheric particles in Sao Paulo City, Brazil. Atmos. Environ. 28, 2307, 1994.
  • 13. SEINFELD J.H., PANDISS.N. Atmospheric chemistry and physics from air pollution to climate change. Wiley, New York, 1998.
  • 14. PIERSON W.R., BRACHACZEK W.W. Particulate matter associated with vehicles on the road. II. Aerosol Sci. Tech- nol. 2, 1, 1983.
  • 15. HUANG X, OLMEZ I., ARAS K., GORDON G.E. Emis­sion of trace elements from motor vehicles: potential marker elements and source composition profile. Atmos. Environ. 28, 1385, 1994.
  • 16. SÖRME L., BERGBÄCK B., LOHM U. Goods in the anthroposphere as a metal emissions source - a case study of Stock­holm, Sweden. Water, Air, and Soil Pollut. 1, 213, 2001.
  • 17. BIALAS-BORGIEL K., SKRZYPEK D., ZIPPER E. The effect of paramagnetic impurities on EPR linewidth in KMnF3. Experimental and theoretical studies. J. Phys. C 13, 6251, 1980.
  • 18. CANTIN C., DAUBRIC H., KLIAVA J., KAHN O. Coex­istence of anisotropic and motionally averaged EPR spectra in a Jahn-Teller system: Cu2+ ion in [Fe(NH2trz)3(NO3)]2 compound Sol. St. Comm. 108, 17, 1998.
  • 19. YORDANOV N.D., LUBENOVA S., SOKOLOVA S. On the possibility for separate determination of pyrolyzed prod­ucts (soot and polycyclic aromatic hydrocarbons) in aero­sols by EPR spectrometry. Atmos. Environ. 35, 827, 2001.

Typ dokumentu

Bibliografia

Identyfikatory

Identyfikator YADDA

bwmeta1.element.agro-article-617ed911-87e9-40a9-92d0-00d8d323c7bb
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.