Przydatność metody z zastosowaniem azomethiny-H w oznaczaniu boru w roślinie i glebie

• Autorzy: Benedycka Z , Rusak E.
• Języki publikacji: PL

Abstrakty

PL

Na podstawie literatury przedstawiono charakterystykę metody oznaczania boru w roślinie i glebie z zastosowaniem azomethiny-H, uwzględniając dotychczasowe modyfikacje i udoskonalenia. Azomethina-H, z borem w środowisku wodnym daje barwny kompleks, który podlega prawu Lamberta-Bera w szerokim zakresie stężeń. Reakcja przebiega szybko w temperaturze pokojowej. Maskowania buforem (EDTA) wymagają obecne w badanym materiale jony Cu2+, Fe3+ i A13+. Prostota tej metody, a jednocześnie porównywalna czułość do metod klasycznych zadecydowały o jej wielkiej przydatności w analizie gleby, rośliny, wody i ścieków.

EN

A review of the literature was made to characterize the methods used to determine boron in plants and soil with the application of azomethine-H, with attention paid to all known modifications and improvements. Azomethine-H produces with boron a coloured complex in the aquatic environment, which is subject to Lambert-Ber's law in a large range of concentrations. The reactions is rapid in room temperature. Masking with the buffer (EDTA) must be performed when the materiał contains Cu2+, Fe3+ and Al3+ ions. Simplicity of the method and its sensitivity comparable to classical methods result in its high suitability in the analyses of soil, plants, water and wastes.

Słowa kluczowe

PL

chemia rolna; gleboznawstwo; gleby; analiza roslin; analiza gleby; azomethina-H; oznaczanie; bor [chem.]; metody oznaczania

EN

agricultural chemistry; soil science; soil; plant analysis; soil analysis; azomethine; boron; determination method

• Wydawca: -
• Czasopismo: Acta Academiae Agriculturae ac Technicae Olstenensis. Agricultura
• Rocznik: 1994
• Tom: 58
• Opis fizyczny: s.85-92,rys.,tab.,bibliogr.

Twórcy

autor

Benedycka Z

• Akademia Rolniczo-Techniczna, Olsztyn

autor

Rusak E.

Bibliografia

• 1. Basson W. D, Bohmer R. G, Stanton D. A, 1969. An automated procedure for the determination of boron in plant tissue. Analyst 94: 1135-1141.
• 2. Berger K. C., Truog E., 1944. Boron tests and determination for soils and plants Soil Sci,57:25-36.
• 3. Bogushave B., 1959. Ferrous metallurgical analist. A review. Analyst, 84: 475-504.
• 4. Czerniawska W., Strahl A., 1980. Spektrometryczna metoda oznaczania boru z zastosowaniem kurkuminy w glebach i materiałach roślinnych. Rocz. gleb., 31: (1) 27 - 36.
• 5. Edwards R. A.,1980. Automatic determination of boron (0,10-10,0 mgl-1l) in raw and waste waters. Anatyst, 105: 139-146.
• 6. Gaines T. P., Mitchell G. A. 1979. Boron determination in plant tissue by the azomethine H method. Comm. Soil Sci. Plant Anal,10: 1099-1108.
• 7. Gopal N. H., 1969. Need for Ca(OH)2 in boron determination in plant vegetative tissue and oilseeds. J. Agric. Food Chem, 17: 1146-1147.
• 8. Gupta U. C., 1967. A simplifled method for determining hot-soluble boron in podzol soils. Soil Sci., 103: 424-428.
• 9. Gupta U. C. 1967. The boron determination of some plant material as determined with and without adding CaO before ashing. Plant and Soil, 26: 202-204.
• 10. Hatcher J. T., Wilcox L. V., 1950. Colorimetric determination of boron using carmine. Anal. Chem.. 22:567-569.
• 11. John M. K., 1973. A batch-handling technique for hot-water extraction of boron from soils. Soil Sci. Soc. Amer. Proc., 37: 332-333.
• 12. John M. K, Chunh H. H, Neufeld J.H., 1975. Application of improved azomethine-H method to the determination of boron in soils and plants. Anal. Lett, 8: 559-568.
• 13. Kozai S., Hoshina T., 1981. Determination of hot water soluble boron in tea garden soils by azomethine H method. Chagyo Kenkyu Hokoku, 54: 32-35.
• 14. Lohse G., 1982. Microanalytical azomethine-H method for boron determination in plant tissue.Comm. Soil Sci. Plant Anal., 13: 127-134.
• 15. Odom J. W., 1980. Kinetics of the hot water soluble boron soil test. Comm. Soil Sci. Plant Anal, 11: 759-765.
• 16. Parker D. R, Gardner E. H, 1981. The determination of hot-watersoluble boron in some acid Oregon soils using a modified azomethine-H procedure. Comm. Soil Sci. Plat Anal, 12: 1311-1322.
• 17. Saarela I, 1985. Plat-available boron in soils and the boron requirement of spring oilseed rapes. Ann. Agric. Fen, 24: 183 - 265.
• 18. Samochvalov S. G, Celikova N. A, 1975. Fotokolorimetričeskoe opredelenie bora w rastitelnych materijalach s pomoščju azometina H. Agrochimija, 5: 134 - 138.
• 19. Samochvalov S. G, Celikova N. A, 1978. Fotokolorimetričeskoe opredelenie podvižnogo bora w počvach s izpolzowaniem azometina H. Chim. v Sel'. Choz, 16: 23 - 25.
• 20. Sippola J, Eryio R, 1977. Determination of boron in soils and plants by the azomethine-H method. Finn. Chem. Lett, 138-140.
• 21. Šanina T. M, Gelman N. E, Michajlovska V. S, 1967. Količestvennyj analiz elementoorganičeskich soedinenij. Spektrofotometričeskoe mikroopredelenie bora. Žurnal Anal. Chem, 22: 782-787.
• 22. Watanabe K, Imai T, Fujii H, Okada K, Nakano K, Take M, 1981. The determination of hot-water-soluble boron from soils using azomethine-H. Hyogo-ken Nogyo Sogo Senta Kenkyu Hokuku, 29: 29-34.
• 23. Williams D. E, Vlamis J, 1961. Boron analysis of plant tissue. Soil Sci, 92: 161-165.
• 24. Williams D. E., Vlamis J., 1970. A critical examination of the curcumin method for boron analysis of plant tissues, waters and soil extracts. I. Sample size. Comm. Soil Sci. Plant Anal., 1: 131-138.
• 25. Williams W. J., 1985. Oznaczanie anionów. PWN Warszawa.
• 26. Wolf B., 1974. Improvements in the azomethine-H method for the determination of boron. Comm. Soil Sci. Plant Anal., 5: 39-44