PL EN


Preferencje help
Widoczny [Schowaj] Abstrakt
Liczba wyników
1993 | 02 | 2 |

Tytuł artykułu

Research on the determination of toxic organic compounds in airborne particulate matter in Upper Silesia

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
Four separate analytical procedures were applied to determine polycyclic aromatic hydrocarbons (PAH's) and their oxygen and nitrogen derivatives including carbazoles, nitrocompounds and aza compounds. The basic method applied in all four procedures was chromatography, utilized in different variations aimed at obtaining PAH concentrates and their derivatives, before identification analysis. Capillary gas chromatography and the GC-MS system were applied in the identification of individual compounds and in quantity determinations. In the airborne particulate matter in Upper Silesia — the Polish region considered to be the most ecologically degraded — the following compounds have been determined among many others: several PAH's; oxygen derivatives such as 9-fluorenone, anthraquinone, benzanthrone, 1-nitropyrene and/or 2-nitrofluoranthene; carbazole; quinoline; and benzoquinoline. Except for PAH, the enumerated compounds have so far not been determined in environmental samples all over the country.

Wydawca

-

Rocznik

Tom

02

Numer

2

Opis fizyczny

p.13-22,fig.,ref.

Twórcy

autor
  • Silesian Medical Academy, Jordana 19, Zabrze, Poland
autor

Bibliografia

  • Bulletin of Sanepid, Katowice, 1991.
  • PRZYBOŚ E, KOMALA Z., BODZEK D, LUKS-BET- LEJ K. Effect of fraction of polycyclic aromatic hydrocarbons on test organisms (Paramecium Sp., Tubifex Sp., Ra¬na Temporaria). Arch. Ochr. Środow., 1, 79 — 95,1992. (in Polish)
  • JACOB J., KARCHER W. Polycyclic aromatic compounds of environmental and occupational importance their occurance, toxicity and the development of high purity certified reference matterials, Fresenius Z. Anal. Chem., 317, 101-114,1984.
  • ROSENKRANZ H.S, KLAPMAN G. Case the computer automated structure evolution method, correctly predicts the low mutagenicity for Salmonella of nitrated cyc- lopenta — fused polycylic aromatic hydrocarbons. Mutat. Res., 199, 95-101, 1988.
  • RAMDAHL T., BECHER G. Characterization of polynu-clear aromatic hydrocarbon derivative in emissions from wood and cereal straw combustion. Anal. Chim. Acta, 144, 83-91,1982.
  • LEE M.L, NOVOTNY M.V., BARTLE K.D. Analytical Chemistry of Polycyclic Aromatic Compounds. Academic Press, Inc., 1981.
  • WARZECHA L., LUKS-BETLEJ K., BODZEK D. The analytical methods of polycyclic aromatic hydrocarbons from human natural environment. Chem. Anal., 33, 21-53,1988.
  • GIGER W., SCHAFFNER CH. Determination of polycyclic aromatic hydrocarbons in the environment by glass capillary gas chromatography. Anal. Chem., 50, 243—249, 1978.
  • KONIG J., BALFANZ E, FUNCKE W., ROMANOW- SKI T. Determination of oxygenated polycyclic aromatic hydrocarbons in airborne particulate matter by capillary gas chromatography and gas chromatography/mass spect¬rometry. Anal. Chem., 55, 599 — 603,1983.
  • CAMPBELL R.M., LEE M.L. Capillary column gas chromatographic determination of nitro polycyclicaromatic compounds in particulate extracts. Anal. Chem., 56, 1026-1030,1984.
  • LATER D.W., ANDROS T.G, LEE M.L. Isolation and identification of amino polycyclic aromatic hydrocarbons from coal — derived products. Anal. Chem., 55, 2126-2132,1983.
  • ALSBERG T., STRANDELL M, WESTERHOLM R„ STENBERG V. Fractionation and chemical analysis of gasoline exhaust particulate extracts in connection with biological testing. Environ. Sci. Technol., 11, 249 — 257, 1985.
  • BODZEK D, LUKS-BETLEJ K, WARZECHA L. Determination of associated polycyclic aromatic hydrocarbons in ambient air samples from the Upper Silesia region of Poland. Atmos. Environ., 27A (in press), 1993.
  • LUKS-BETLEJ K, PIWOWAR Z, WARZECHA L., BODZEK D. The separation of polycyclic aromatic hydrocarbons using the column liquid chromatography method with different adsorbents. Arch. Ochr. £rod., 1—2, 33-51,1989.
  • JAKLIN J., KRENMAYER P. A routine method for the quantitative determination of polycyclic aromatic hydrocarbons in urban air. Int. J. Environ. Anal. Chem., 21, 33-42,1985.
  • MUEL B., SAGUEM S. Determination of 23 polycyclic aromatic hydrocarbons in atmospheric particulate matter of the Paris area and photolysis by sunlight. Inter. J. En¬viron. Anal. Chem., 19, 111 — 131, 1985.
  • PITTS J.N. Nitration of gaseous polycyclic hydrocarbons in simulated and ambient urban atmospheres: a source of mutagenic nitroarenes. Atmos. Environ., 21, 2531—2547, 1987.
  • NIELSEN T., RAMDAHL T, BJORSETH A. The fate of airborne polycyclic organic matter. Environ. Health Per- spect., 47, 103-114,1983.
  • BODZEK D., TYRPIEN K., WARZECHA L. Identification of oxygen derivatives of polycyclic aromatic hydrocarbons in airborne particulate matter of Upper Silesia (Poland). Intern. J. Environ. Anal. Chem. (in press) 1993.
  • TYRPIEŃ K., BODZEK D., JANOSZKA B. Separation of polycyclic aromatic hydrocarbons and heterocompounds from airborne particulate matter by thin layer chromatography. J. of Planar Chrom., 4, 309—312,1991.
  • PITTS J.N. Jr., SWEETMAN J.A., ZIELIŃSKA B, ATKINSON R, WINER A.M., HARGER W.P. Determination of 2-nitrofluoranthene and 2-nitropyrene in ambient particulate organic matter: evidence for atmospheric reac¬tions. Atmos. Environ., 19, 1601 — 1608, 1985.
  • KAMENS R.M, GUO J., GUO Z, Mc DOW S.R. Poly- nuclear aromatic hydrocarbon degradation by heteroge¬nous reactions with N2Os on atmospheric particles. Atmos. Environ., 24A, 1161 — 1173, 1990.
  • ATKINSON R., AREY J, ZIELIŃSKA B., ASCHMANN
  • S.M. Kinetics and nitro — products of gas — phase OH and N03 radical — initiated reactions of naphthalene — d18, fluoranthene — d10, and pyrene. Int. J. Chem. Ki- net, 22, 999-1014,1990.
  • ATKINSON R., TUAZON E.C, AREY J. Reactions of naphthalene in N2Os—N03—N02 — air mixtures. Int J. Chem. Kinet, 22, 1071-1082, 1990.
  • WARZECHA L. JANOSZKA B, BODZEK D. Separation and analysis of biological active nitrogen derivatives of PAH from airborne particulate matter. Environ. Prot. Engineering (in press).

Typ dokumentu

Bibliografia

Identyfikatory

Identyfikator YADDA

bwmeta1.element.agro-article-3eada461-4772-41dc-a97e-c8dca7912edf
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.