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1996 | 05 | 4 |

Tytuł artykułu

Recovery of metal ions from electroplating rinse solutions using the Donnan dialysis technique

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
Electroplating rinse solutions contain considerable amounts of multivalent valuable or toxic metal ions. The attempt to recover them was made using the Donnan dialysis (DD) technique, applying a cation-exchange polymer membrane. Laboratory experiments dealing with processing two different solutions containing Zn(ll) [A], or Zn(II), Cu(II), Ni (II), Cr(III) and Fe(III) [B] were carried out. The results demonstrated DD to be efficient for recovering Zn(II) (soln.A) and other multivalent metals (soln.B) in the sequence Ni, Cu>Fe>Zn>Cr. Recovery factors amount to 80-90% and 74-94% for A and B solutions, respectively. The optimum concentration of sulfuric acid in the strip solution ranges from 0.25 to 0.5 M.

Słowa kluczowe

Wydawca

-

Rocznik

Tom

05

Numer

4

Opis fizyczny

p.45-50,fig.,ref.

Twórcy

autor
  • Nicolaus Copernicus University, 87-100 Torun, Poland

Bibliografia

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  • WALLACE R. M. Concentration and separation of ions by Donnan dialysis membrane equilibrium. Ind. Eng. Chem., Proc. Des. Dev. 6, 423-431, 1967.
  • BLAEDEL W. J., HAUPERT T. J. Exchange equilibrium through ion exchange membranes. Analytical application. Anal. Chem. 38, 1305, 1966.
  • BLAEDEL W. J., HAUPERT T. J., EVENSON M. A.Mechanism of trace counterions transport through ion-exchange me- mbranes. Anal. Chem. 41, 583-589, 1969.
  • WEN C. P., HAMIL H. F. Metal counterion transport in Donnan dialysis. J. Membrane Sci. 8, 51-68, 1981.
  • TOMBALAKIAN A. S. A correlation for the rate of cation interchange across an ion-exchange membrane. Can. J. Chem. Engng. 52, 841-844, 1974.
  • TOMBALAKIAN A. S. The dependence of cation interchange rate on the association constants of the counterions within the ion-exchange membrane. Can. J. Chem. Engng. 57, 768-769, 1979.
  • NG P. K., SNYDER D. D. Effect of concentration on ion transport in Donnan dialysis. J. Electrochem. Soc. 130, 2363-2365, 1983.
  • KTARI T., AUCLAIR B. Simplified flux equation in Donnan dialysis. J. Membrane Sci. 32. 251-265, 1987.
  • LAKE M. A., MELSHEIMER S. S. Mass transfer characterization of Donnan dialysis. AIChE J. 24,130-137, 1978.
  • SUDOH M., KAMEI H., NAKAMURA S. Donnan dialysis concentration of cupric ions. J . Chem. Engng. Jpn. 20, 34-40, 1987.
  • KELLY M. H., RANDALL D., WALLACE R. M. Documents Du Pont de Nemours cit. in SARRAZIN ]. La development industriel contemporain des membranes echangeuses d'ions. Bull. L.,Union des Physiciens, 80, 1427-1447, 1986.
  • SAWICKA B., BRAJTER K., TROJANOWICZ M., KADO B. Donnan dialysis of transition metal ions using anion exchange membrane modified with xylenol orange. Sep. Sci. Technol. 26, 717-728, 1991.
  • SIONKOWSKI G., WÓDZKI R. Recovery and concentration of metal ions. I. Donnan dialysis. Sep. Sci. Techno]. 30, 805-820, 1995.
  • VAUGHAN D. ]. ”Nafion”, an electrochemical traffic controller. Du Pont Innovation, 4, 11-13, 1973.
  • SUROWIEC ]. Fluorowe membrany kationowymienne typu Nafion - właściwości, zastosowania, modyfikacje, Przem. Chem. 63, 126-129, 1984.
  • CWIRKO E. H., CARBONELL R. G. A theoretical analysis of Donnan dialysis across charged porous membrane. ] . Membrane Sci. 48, 155-179, 1990.
  • COX J. A., GAJEK R., LITWINSKI G., CARNAHAN J., TROCHIMCZUK W. Optimization of ion exchange membrane structures for Donnan dialysis. Anal. Chem. 54, 1153-1157, 1982.
  • WIŚNIEWSKA G., WINNICKI T. Removal of nitrate ions from acidic wastewater by Donnan dialysis involving tubular exchange membranes. Desalination. 56, 161-173, 1985; Acidic wastewater treatment by Donnan dialysis involving tubular anion-exchange membranes. 68, 121-130, 1988.
  • POŻNIAK G., TROCHIMCZUK w. Tubular interpolymer ion-exchange membranes. Donnan dialysis through strong-base membranes. J. Membrane Sci. 49, 55-68, 1990.
  • WYCISK R., TROCHIMCZUK W. Salt. and base separation with interpolymer type carboxylic ion-exchange membrane. J. Membrane Sci. 65, 141-146, 1992.
  • MARHOL M. Mćniće iontu v chemii a radiochemii, Academia, Praha, pp. 28-29, 1976.
  • WÓDZKI R., SIONKOWSKI G. Recovery and concentration of metal ions. II. Multimembrane hybrid system. Sep. Sci. Technol. 30, 2763-2778, 1995.
  • WÓDZKI R., SI'ONKOWSKI G. Hybrid: Polymer-Liquid-Polymer Membrane System for Removal of Heavy Metal Ions from Waste Waters, in ”Towards Hybrid Membrane and BioTechnology Solution for Polish Environmental Problems (Howell J. A., Noworyta A., eds.), Wrocław. pp. 235-239, 1995.

Typ dokumentu

Bibliografia

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