Studies of competitive Cu2plus, Co2plus and Cr3plus sorption in grey-brown podzolic soils

• Autorzy: Paszko T
• Języki publikacji: EN

Abstrakty

EN

Studies of competitive sorption were carried out using the three-component solution CuCl2, CoCl2 and CrCl3 in two grey-brown podzolic soils saturated with Ca2+ cations. In most cases in batch experiments the Freundlich equation was the best to describe the sorption process. The linear sorption equation was success-fully applied to describe Cr3+ and Cu2+ sorption in column experiments. A significant effect of Cu2+ and Cr3+ on Co2+ sorption was found in both column and batch experiments. Sorption of ions of the studied heavy metals was not equivalent to Ca2+ desorption from soil.

Słowa kluczowe

EN

sorption process; podzolic soil; Freundlich equation; competitive sorption; soil; metal ion; grey-brown podzolic soil; linear sorption equation; heavy metal

• Wydawca: -
• Czasopismo: Polish Journal of Environmental Studies
• Rocznik: 2003
• Tom: 12
• Numer: 4
• Opis fizyczny: p.439-446,fig.

Twórcy

autor

Paszko T

• University of Agriculture, Akademicka 15, 20-950 Lublin, Poland

Bibliografia

• 1. ABRAMOWITZ M., STEGUN I.A. Handbook of math­ematical functions. Dover Pub. New York 1964.
• 2. BAJRACHARYA K., BARRY D.A. MCMFIT: efficient op­timal fitting of a generalized nonlinear advection-dispersion model to experimental data. Computers & Geosciences. 21, 61, 1995.
• 3. BASTA N.T., TABATABAI M.A. Effect of cropping sys­tems on adsorption of metals by soils: III. Competitive adsorption. Soil Sci. 153, 331, 1992.
• 4. BRUSSEAU M.L., RAO P.S.C., JESSUP R.E., DAVIDSON J.M. Flow interuption: a method for investigating sorption nonequilibrium. J. Contam. Hydr. 4, 223, 1989.
• 5. BURGLSSER C. S., CERNIK M., BORKOVEC M., STICHER H. Determination of nonlinear adsorption iso­therms from column experiments: an alternative to batch studies. Environ. Sci. Technol. 27, 943, 1993.
• 6. DAGAN G. Flow and transport in porous formations. Springer. New York. 1989.
• 7. ELPRINCE A.M., Day P.R. Fitting solute breakthrough equations to data using two adjustable parameters. Soil Sci. Soc. Am. J. 41, 39, 1977.
• 8. GAMBUŚ F. The applicability of the Langmuir and Freund­lich equations to describe copper sorption in the soil depend­ing on its pH and granulometric composition. Polish J. Soil Sci. 20, 11, 1987.
• 9. GĄSZCZYK R., MUSZYŃSKI P. Dynamics of competitive sorption of heavy metal cations in mineral soils. Acta Agrophysica, 35, 69, 2000.
• 10. GODFRIN J.M., VAN BLADEL R. Influence du pH sur l'adsorption du cuivre et du zinc par le soles. Sci. du Sol. 28, 15, 1990.
• 11. HARTER R.D. Competitive sorption of cobalt, copper, and nickel ions by a calcium saturated soil. Soil Sci. Soc. Am. J., 56, 444, 1992.
• 12. KITHOME M., PAUL J.W., LAVKULICH L.M., BOMKE A.A. Kinetics of ammonium adsorption and desorption by the natural zeolite clinoptilolite. Soil Sci. Soc. Am. J. 62, 622, 1998.
• 13. KOOL J.B., PARKER J.C., ZELAZNY L.W. On the estima­tion of cation exchange parameters from column displace­ment experiments. Soil Sci. Soc. Am. J. 53, 1347, 1989.
• 14. MARAQA M.A. Effects of fundamental differences be­tween batch and miscible displacement techniques on sorp­tion distribution coefficient. Environmental Geology. 41, 219. 2001.
• 15. MARAQA M.A., ZHAO X., WALLACE R.B., VOICE T.C. Retardation coefficients of nonionic organic compounds determined by batch and column techniques. Soil Sci. Soc. Am. J. 62, 142, 1998.
• 16. MARTIN R.J., AL-BAHRANI K.S. Adsorption studies us­ing gas-liquid chromatography: 2 Competitive adsorption. Water Res., 11, 991, 1977.
• 17. MCBRIDE M.B. Environmental chemistry of soils. Oxford University Press, New York, Oxford. 1994.
• 18. MCBRIDE M.B. Reactions controlling heavy metal solubil­ity in soils. Adv. Soil Sci. 10, 1, 1989.
• 19. MCLAREN R.G., CAREY P.L., CAMERON K.C. AD­AMS J.A., SEDCOLE J.R. Effect of soil properties and contact period on the leaching of copper, chromium and arsenic through undisturbed soils. Proceedings of 15th World Congress of Soil Science, Acapulco, Mexico, pp. 155-159, 1994.
• 20. MILLER J.E., HASSETT J.J., KOEPPE D.E. Interactions of lead and cadmium on metal uptake and growth of corn plants. J. Environ. Qual. 6, 18, 1977.
• 21. MOHAN D., CHANDLER S. Single component and multi- component adsorption of metal ions by activated carbons. Colloids Surfaces., 177, 183, 2001.
• 22. NKEDI-KIZZA P., BIGGAR J.M., VAN GENUCHTEN M.TH., WIERZENGA P.J., SELIM H.M., DAVIDSON J.M., NIELSEN D.R. Modeling tritium and chloride-36 through an aggregated Oxisol. Water Resour. Res. 19, 691, 1983.
• 23. PASZKO T. Influence of interactions between Cu2+, Zn2+ and Pb2+, Cr3+, Ni2+, Co2+ or Cd2+ cations on their sorption and desorption in grey-brown podzolic soils. Pol. J. Soil Sci., 34, 17, 2001.
• 24. PETRUZZELLI G., LUBRANO L. Soil sorption of heavy metals as influenced by sewage sludge addition. J. Environ. Sci. Health. 29, 31, 1994.
• 25. RANDLE K., HARTMANN E.H. Applications of the con­tinuous-flow stirred cell (CFSC) technique: II. The adsorp­tion behaviour of Na, Cs, Sr, Cu, Ni and Pb on humic acids. Eur. J. Soil Sci., 46, 303, 1995.
• 26. SCHECHER W.D. MINEQL+: A chemical equilibrium program for personal computers. Environ. Res. Software. Hallowel, Maine 1994.
• 27. SCHWEICH D., SARDIN M., GAUDET J.P. Measurment of a cation exchange isoterm from elution curves obtained in a soil column: preliminary results. Soil Sci. Soc. Am. J. 47, 32, 1983.
• 28. UZIAK S., KLIMOWICZ Z. Elementy geografii gleb i gle­boznawstwa. Wyd. UMCS, Lublin 2000.
• 29. VAN GENUCHTEN M.TH., PARKER J.C. Boundary con­ditions for displacement experiments through short labora­tory soil columns. Soil Sci. Soc. Am. J. 48, 703, 1984.
• 30. YAMAGUCHI T., MOLDRUP P., YOKOSI S. Using break­through curves for parameter estimation in the convection- dispersion model of solute transport. Soil Sci. Soc. Am. J. 53, 1635, 1989.