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1996 | 05 | 2 |

Tytuł artykułu

Sorption of iodide on the surface of modified clinoptilolite

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
The possibility of using the monoionic Ag+ - form of clinoptilolite of domestic origin for radioactive iodide separation from waters has heen studied. The capacity of the silver form of clinoptilolite towards iodide exceeds many times that of the capacity of clinoptilolite in natural form. Due to low solubility the product Agl iodides generate precipitates on the surface of zeolite. SEM and rtg analyses of the silver form of clinoptilolite after sorption of iodide demonstrate the formation of new crystals on the zeolite surface. In comparison to the origin clinoptilolite sample, TG - analyses show that maximum water release occurs earlier. Sorption of iodide on the silver form of clinoptilolite was described as a second order reaction. The influence of interfering anions on the adsorption capacity of silver clinoptilolite towards iodide was also investigated.

Wydawca

-

Rocznik

Tom

05

Numer

2

Opis fizyczny

p.13-19,fig.,ref.

Twórcy

  • Commenius University, Bratislava, Slovakia
autor

Bibliografia

  • GłMIELEWSKA-HORVATHOVA E., LESNY J., HORVATH Sorption of some nuclear fission species on natural zeolite.km. Symposium on Zeolites and Microporous Crystals, Nagoya. Japan, August 22-25, p. 169, 1993.
  • GAŻO J. et al. General and Inorganic Chemistry (in Slovak), Alfa, Bratislava, 1981.
  • GRADEV C.D. Sorption of iodide ions on cationic forms of clinoptilolite. Journal of Radional. and Nuclear Chem., Articles, 116, No 2 (341-46), 1987.
  • HORVATHOVA E. Removal of Ammonium Nitrogen from Waters by Clinoptilolite. PhD Thesis. Research Institute of Water Economy - Slovak Technical University, Bratislava, 1985.
  • KOZAC J., OCENAŚ D. Determination of clinoptilolite content in zeolite tuffs (in Slovak). Min. Slov., p. 549-52, 1982.
  • THOMAS B.A., STAPLES and MURPHY L.P.: U.S. Patent 4, 088, 737: Recycling Iodide-Leoded Silver Zeolite.
  • CAMPBELL D.O., COLLINS E.D., KING L.J. KNAUER J.B. Evaluation of the Submerged Demineralizer System (SDS) Flowsheet for Decontamination of High - Activity - Level Water at the Three Mile Island Unit 2 Nuclear Power Station, ORNL/TM-7448, July 1980.
  • KIGOSHI, KATO Removal of Cs137 from aqueous solutions by zeolite, Hoken Butsuri 9, ll - 16, 1974.
  • EBBING DD. General Chemistry, Houghton Mifilin Company, Boston 1987

Typ dokumentu

Bibliografia

Identyfikatory

Identyfikator YADDA

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