Structural characterization of fatty acid films on rain water: a scaling approach using physical attributes

• Autorzy: Mazurek A Z , Pogorzelski S.J. , Kogut A.D.
• Języki publikacji: EN

Abstrakty

EN

A complete compositional or structural description of naturally-occurring surfactants on rain water is not currently feasible. A main limitation of previous work has been the lack of means for correlating force-area char­acteristics with the chemical makeup of the films. Instead of analyzing the chemical composition of rain water film-forming organics, it is postulated here to introduce the novel scaling procedures (2D virial equation of state and 2D polymer film scaling theory) applied to the surface pressure-area (n-A) isotherms and surface pressure- temperature (n-T) isochors and resulting from generalized physical formalisms modified to a multicomponent surfactant film. A set of the introduced structural film state parameters (n, r, Alim, Eisoth, y, R, Mw, Ps) could become sensitive indicators for surface-active source-specific organic matter pathway tracing, where the measurement of surfactant concentration and chemical analyses are avoided. The concept is quantified using the Langmuir trough film and disdrometer data on a set of rain water events observed in Gdańsk, Poland in May 2002.

Słowa kluczowe

EN

physicochemical property; isotherm scaling; rain water film; measurement; film structure quantification; source-specific surfactant; structural parameter; atmospheric water

• Wydawca: -
• Czasopismo: Polish Journal of Environmental Studies
• Rocznik: 2006
• Tom: 15
• Numer: 6
• Opis fizyczny: p.877-884,fig.,ref.

Twórcy

autor

Mazurek A Z

• University of Gdansk, Wita Stwosza 57, 80-952 Gdansk, Poland

autor

Pogorzelski S.J.

autor

Kogut A.D.

Bibliografia

• 1. CAPEL, P. D., GUNDE, R., GIGER, W. Carbon speciation and surface tension on fog. Environ. Sci. Technol. 24, 722, 1990.
• 2. FACCHINI, M. C., MIRCEA, M., FUZZI, S., CHARLSON, R. J. Cloud albedo enhancement by surface-active organic solutes in growing droplets. Nature 401, 257, 1999.
• 3. SEIDL, W. Model for a surface film of fatty acids on rain wa­ter and aerosol particles. Atmos. Environ. 34, 4917, 2000.
• 4. CECINATO, A., MABILIA, R., MARINO, F. Relevant or­ganic components in ambient particulate matter collected at Svalbard Islands (Norway). Atmos. Environ. 34, 5061, 2000.
• 5. GELENCSER, A., MESZAROS, T., BLAZSO, M., KISS, G. , KRIVACSY, Z., MOLNAR, A., MESZAROS, E. Struc­tural characterization of organic matter in fine tropospheric aerosol by pyrolysis-gas chromatography-mass spectrometry. J. Atmos. Sci. 37, 173, 2000.
• 6. GRAHAM, B., GUYON, P., TAYLOR, P., ARTAXO, P., MAENHAUT, W., GLOVSKY, M., FLAGAN, R., ANDRE- AE, M. Organic compounds present in the natural Amazo­nian aerosol: Characterization by gas chromatography-mass spectrometry. J. Geophys. Res. 108, D4766, 2003.
• 7. TERVAHATTU, H., JUHANOJA, J., VAIDA, V., TUCK, A. F., NIEMI, J., KUPIAINEN, K., VEHKAMAKI, K. M., VEHKAMAKI, H. Fatty acids on continental sulfate aerosol particles. J. Geophys. Res. 110, D06207, 2005.
• 8. GAGOSIAN, R. B., ZAFIRIOU, O. C., PELTZER, E. T., AL- FORD, J. B. Lipids in aerosols from the tropical north Pacific: Temporal variability. J. Geophys. Res. 87C, 11133, 1982.
• 9. MEYERS, P. A., HITES, R. A. Extractable organic com­pounds in Midwest rain and snow. Atmos. Environ. 16, 2169, 1982.
• 10. GILL, P. S., GRAEDEL, T. E., WESCHLER, C. J. Organic films on atmospheric aerosol particles, fog droplets, cloud droplets, raindrops, and snowflakes. Rev. Geophys. Space Phys. 21, 903, 1983.
• 11. POLZER, J., BACHMANN, K. Determination of fatty acids in atmospheric samples via GC/MS. Fresenius Journal of Analytical Chemistry 340, 555, 1991.
• 12. MAZUREK, M., MASONJONES, M. C., MASONJONES, H. D., SALMON, L. G., CASS, G. R., HALLOCK, K. A., LEAITCH, M. Visibility-reducing organic aerosols in the vicinity of Grand Canyon National Park: Properties ob­served by high-resolution gas chromatography. J. Geophys. Res. 102D, 3779, 1997.
• 13. ROGGE, W. F., MAZUREK, M. A., HILDEMANN, L. M., CASS, G. R., SIMONEIT, B. R. T. Quantification of urban or­ganic aerosols at a molecular level: Identification, abundance and seasonal variation. Atmos. Environ. 27A, 1309, 1993.
• 14. ZHENG, M., WAN, T. S. M., FANG, M., WANG, F. Char­acterization of the non-volatile organic compounds in the aerosol of Hong Kong: Identification, abundance and origin. Atmos. Environ. 31, 227, 1997.
• 15. DECESARI, S., FACCHINI, M. C., FUZZI, S., TAGLIAVI- NI, E. Characterization of water-soluble organic compounds in atmosphere aerosol: A new approach. J. Geophys. Res. 105, 1481, 2000.
• 16. FUZZI, S., DECESARI, S., FACCHINI, M. C., MATTA, E., MIRCEA, M., TAGLIAVINI, E. A simplified model of the water soluble organic component of atmospheric aerosols. Geophys. Res. Lett. 28, 4079, 2001.
• 17. BARGER, W. R., GARRETT, W. D. Surface active organic material in the marine atmosphere. J. Geophys. Res. 75, 4561, 1970.
• 18. MOCHIDA, M., KITAMORE, Y, KAWAMURA, K., NOJIRI, Y., SUZUKI, K. Fatty acids in the marine atmosphere: Factors governing their concentration and evaluation of organic films on sea-salt particles. J. Geophys. Res. 107, 4325, 2002.
• 19. RUSSELL, L. M., MARIA, S. F., MYNENI, S. C. B. Map­ping organic coatings on atmospheric particles. Geophys. Res. Lett. 29, 16, 2002.
• 20. TERVAHATTU, H., HARTONEN, K., KERMINEM, V.­M., KUPIAINEN, K., AARNIO, P., KOSKENTALO, T., TUCK, A. F., VAIDA, V. New evidence of an organic layer on marine aerosols. J. Geophys. Res. 107, D7, 2002.
• 21. TERVAHATTU, H., JUHANOJA, J., KUPIAINEN, K. Iden­tification of an organic coating on marine aerosol particles by TOF-SIMS. J. Geophys. Res. 107, D16, 2002.
• 22. MOCHIDA, M., KAWAMURA, K., UMEMOTO, N., KO- BAYASHI, M., MATSUNAGA, S., LIM, H. -J., TURPIN, B., BATES, T., SIMONEIT, B. Spatial distribution of oxy­genated organic compounds (dicarboxylic acids, fatty acids, and levoglucosan) in marine environments over the western Pacific and off the coast of East Asia: Continental outflow of organic aerosols during the ACE-Asia campaign. J. Geo- phys. Res. 108, D23, 2003.
• 23. SIMONEIT, B. R. T., MAZUREK, M. A. Organic matter of the troposphere - II. Natural background of biogenic lipid matter in aerosols over the rural western United States. At- mos. Environ. 16, 2139, 1982.
• 24. ROGGE, W. F., HILDEMANN, L. M., MAZUREK, M. A., CASS, G. R., SIMONEIT, B. R. T. Sources of fine organic aerosol. 2. Noncatalyst and catalyst-equipped automobiles and heavy-duty diesel trucks. Environ. Sci. Technol. 27, 636, 1993.
• 25. ROGGE, W. F., HILDEMANN, L. M., MAZUREK, M. A., CASS, G. R., SIMONEIT, B. R. T. Sources of fine organic aerosol. 3. Road dust, tire debris, and organometallic brake lining dust: Roads as sources and sinks. Environ. Sci. Tech- nol. 27, 1892, 1993.
• 26. SIMONEIT, B. R. T. Biomass burning: A review of organic tracers for smoke from incomplete combustion. Appl. Geo- chem. 17, 129, 2002.
• 27. ROGGE, W. F., HILDEMANN, L. M., MAZUREK, M. A., CASS, G. R. Sources of fine organic aerosol. 1. Charbroil- ers and meat cooking operations. Environ. Sci. Techol. 25, 1112, 1991.
• 28. POGORZELSKI, S. J. Structural and thermodynamic char­acteristics of natural marine films derived from force-area studies. Colloids Surfaces A: Physicochem. Eng. Aspects 189, 163, 2001.
• 29. POGORZELSKI, S. J., KOGUT, A. D. Structural and thermodynamic signatures of marine microlayer surfactant films. J. Sea Res. 49, 347, 2003.
• 30. POGORZELSKI, S. J., KOGuT, A. D. Adsorptive proper­ties of natural water surfactant films. Dead Vistula catch­ment water studies. Oceanologia 45, 373, 2003.
• 31. KIEBER, R. J., PEAKE, B., WILLEY, J. D., BROOKS AVERY, G. Dissolved organic carbon and organic acids in coastal New Zealand rainwater. Atmos. Environ. 36, 3557, 2002.
• 32. BALASUBRAMANIAN, R., VICTOR, T., CHUN, N. Chemical and statistical analysis of precipitation in Singa­pore. Water, Air and Soil Pollut. 130, 451, 2001.
• 33. FACCHINI, M. C., FUZZI, S., ZAPPOLI, S., ANDRAC- CHIO, A., GELENCER, A., KISS, GY., KRIVACSY, Z., MESZAROS, E., HANSON, H. C., ALSBERG, T., ZE- BUHR, Y. Partitioning of the organic aerosol component between fog droplets and interstitial air. J. Geophys. Res. 104, 26821, 1999.
• 34. ADAMSON, A. W. Physical Chemistry of Surfaces, Wiley, New York, 1982.
• 35. BARGER, W. R., MEANS, J. S. Clues to the structure of ma­rine organic material from the study of physical properties of surface films. In A.C. Sigleo and A. Hattori (eds.), Marine and Estuarine Geochemistry, Levis Publishers: Chelsea, pp. 47-67, 1985.
• 36. BOCK, E. J., FREW, N.M. Static and dynamic response of natural multicomponent oceanic surface films to compres­sion and dilation: Laboratory and field observations. J. Geo- phys. Res. 98, 14599, 1993.
• 37. POGORZELSKI, S. J., STORTINI, A. M., LOGLIO, G. Natural surface film studies in shallow coastal waters of the Baltic and Mediterranean Seas. Cont. Shelf. Res. 14, 1621, 1994.
• 38. POGORZELSKI, S. J. Application of 2D polymer film scal­ing theory to natural sea surface films. Colloids Surfaces A: Physicochem. Eng. Aspects 114, 297, 1996.
• 39. ROSENHOLM, J. B., IHALAINEN, P., PELTONEN, J. Thermodynamic characterization of Langmuir monolayers of thiolipids: A conceptual analysis. Colloids Surfaces A: Physicochem. Eng. Aspects 228, 119, 2003.
• 40. DAVIES, J. T., RIDEAL, E. K. Interfacial Phenomena, Aca­demic Press, New York, Chapter 5, 1961.
• 41. GONG, KE., FENG, SI.- S., GO, M. L., SOEW, P. H. Ef­fects of pH on the stability and compressibility of DPPC/ cholesterol monolayers at the air-water interface. Colloids Surfaces A: Physicochem. Eng. Aspects 207, 113, 2002.
• 42. CHIBOWSKI, E. Surface free energy of a solid from contact angle hysteresis. Adv. Colloid Interface Sci. 103, 149, 2003.
• 43. HARKINS, W. D. The Physical Chemistry of Surface Films, Reinhold, New York, 1952.
• 44. SEIDL, W., HANEL, G. Surface-active substances on rain­water and atmospheric particles. Pure and Applied Geophys­ics 121, 1077, 1983.
• 45. MIRANDA, P. B., DU, Q., SHEN, Y. R. Interaction of water with a fatty acid Langmuir film. Chem. Phys. Lett. 286, 1, 1998.
• 46. BRIDGES, K. S., JICKELLS, T. D., DAVIES, T. D., ZE­MAN, Z., HUNOVA, I. Aerosol, precipitation and cloud water chemistry observations on the Czech Krusne Hory plateau adjacent to heavily industrialized valley. Atmos. En­viron. 36, 353, 2002.
• 47. POGORZELSKI, S. J., KOGUT, A. D., MAZUREK, A. Z. Surface rheology parameters of source - specific surfactant films as indicators of organic matter dynamics. Hydrobiolo­gia 554, 67, 2006.
• 48. FROST, A. E., SEAVER, M. Ionic effects on solid phase formation in 1-octadecanol films on levitated water drops. Thin Solid Films 247, 184, 1994.
• 49. LAI, C. C., YANG, S. H., FINLAYSON-PITTS, B. J. Inter­actions of monolayers of unsaturated phosphocholines with ozone at the air-water interface. Langmuir 10, 4637, 1994.