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1997 | 439 |

Tytuł artykułu

Wpływ formy nawozów potasowych i magnezowych na mobilność metali ciężkich w glebie lekkiej

Autorzy

Treść / Zawartość

Warianty tytułu

EN
Effect of potassium and magnesium fertilization form on the mobility of heavy metals in light soil

Języki publikacji

PL

Abstrakty

EN
Changes in the mobility of Zn, Cd, Pb and Cu in medium sand soil depending on forms of salts: K₂SO₄ + MgSO₄ or KC1 + MgCl₂ were studied. Those salts were applied at varying soil pH-value (5,4; 6,2; 7,0). Studies were carried out in the leaching experiments using laboratory columns. Heavy metals were leached by simulation 600 mm of rainfall, over a 6 month periods. Leachates were collected and analysed every 200 mm portion of simulated rainfall. Concentrations of Zn, Cd, Pb and Cu in leachates showed that significant increment in the mobility of tested heavy metals took place during the first 200 mm portion of rainfall simulation. It was confirmed that applied salts caused increasing in the leachability of Cd about 35-100 times, Zn about 45-50 times, Pb about 5-10 times and Cu about 3-5 times, comparing to unfertilized soil at pH-value 5,4. Those ranges in the mobilization of heavy metals were significant lower in case of using sulphate salts than chloride salts. In case of Cd, Pb and Cu, the effect of sulphate treatments at lower pH-value (5,4) was compared to chloride-treated soil at higher pH-value (6,2). On the base of the electrical conductivity of leachates, it was concluded that changes in the mobility of heavy metals by the salts application were determinated through different dynamics of certain bases cations (particularly Ca²⁺ ) between soil solid and soil solution. The lower dynamics of Ca²⁺ ions, and consequently decreasing in heavy metals desorption by K₂SO₄ application was influenced through CaSCO₄-precipitation in soil solution.

Wydawca

-

Rocznik

Tom

439

Opis fizyczny

s.132-140,rys.,tab.,bibliogr.

Twórcy

autor
  • Katedra Chemii Rolniczej, Szkoła Główna Gospodarstwa Wiejskiego, ul.Rakowiecka 26/30, 02-528 Warszawa
autor
  • Agrikulturchemisches Institut der Rheinischen, Friedrich-Wilhelms-Universitat, Bonin

Bibliografia

  • Bingham F.T., Sposito G., Strong J.E. 1984: The effect of chloride on the availability of cadmium. J. Environ. Qual. 13; 71-74.
  • Fulekar M.H., Dave J.M. 1991: Release and behaviour of Cr, Mn, Ni and Pb in a flyash/soil/water environment: column experiment. Int. J. Environ. Studies, 38,4:281-296.
  • Fuller W.H., Korte N.E., Niebla E.E., Alesii B.A. 1976: Contribution of the soil to the migration of certain common and trace elements. SoilSci.. 122:223-235.
  • Hartikainen H. 1985: Response of acid sulphate soils to different liming treatments. II Exchangeability of soil cations. Z. Pfianzenernahr. Bodenkd, 148,5:519-526.
  • Herms U., Brümmer G. 1984: Einflussgrössen der Schwermetalllöslichkeit und -bindung in Böden. Z Pflanzemahr. Bodenkd., 147,3:400-424.
  • Horak 0.1983: Die Beziehung zwischen der pflanzlichen Aufnahme einiger Mikroelemente und dereń wasserlöslichen Anteil im Boden. Landwirtschaftliche Forschung, Sonderheft 39:404-414.
  • Homburg V., Brümmer G. 1989: Untersuchungen zur Mobilität und Verfügbarkeit von Schwermetallen in Böden. Mitteilgn. Dtsch. Bodenkundt. Geseilsch., 59,2:727-732.
  • Mullins G.L., Sommers L.E., Barber S.A. 1986: Modelling the plant uptake of cadmium and zinc from soils treated with sewage sludge. SoilSci. Soc. Am. J., 50:1245-1250.
  • Sawhney B.L., Bugbee G.L., Stilwell D.E. 1994: Leachability of heavy metals from growth media containing source-separated municipal solid waste compost. J. Environ. Qual., 23,4:718-722.
  • Schachtschabel P., Blume H.P., Brümmer G., Hartge K.H., Schwertmann U. 1992: Lehrbuch der Bodenkunde. Enke, Stuttgart.
  • Sposito G., Bingham F.T. 1981: Computer modelling of trace metal speciation in soil solutions: Correlation with trace metal uptake by higher plants. J. Plant Nutr., 3:35-49.
  • Tiller K.G., Gerth J., Brümmer G. 1984: The sorption of Cd, Zn and Ni by soil clay fractions. Procedure for partion of bound forms and their interpretation. Geoderma. 34:1-16.
  • Willems M., Pedersen В., Jörgensen S.S. 1981: Accelerated leaching of some common and trace elements from soil mixed with sewage sludge or sludge ash. Acta Agric. Scand., 31,3:323-342.
  • Zeien H., Brümmer G.W. 1991: Chemische Extraktionen zur Bestimmung der Bindungsformen von Schwermetallen in Böden. Berichte aus der Ökologischen Forschung. 6:64-90.

Typ dokumentu

Bibliografia

Identyfikatory

Identyfikator YADDA

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