PL EN


Preferencje help
Widoczny [Schowaj] Abstrakt
Liczba wyników
2014 | 23 | 2 |

Tytuł artykułu

Variability of molecular hydrogen in the urban atmosphere based on continuous measurements in Krakow

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
With respect to the atmospheric budget of molecular hydrogen (H₂), Kraków represents a typical central European urban agglomeration with intense traffic and a relatively high proportion of low-level emissions associated with burning of fossil fuel (mainly coal and gas) for heating. The vehicle fleet in the city still contains a relatively high fraction of cars without properly operating catalysts, which constitutes a considerable source of atmospheric hydrogen. The mixing ratios of hydrogen in near-ground atmosphere were measured quasi-continuously over two years (from 01.2007 till 12.2008) at two different locations within the urban area of Kraków: close to the city center and at the outskirts of the city. Although both measurement locations were under the influence of local traffic, they differ with respect to the structure of local terrain (proportions of buildings, roads, and area covered by vegetation), as well as by local micrometeorological conditions. A very wide range of H₂ mixing ratios was observed at both sites, with peak mixing ratios reaching 2,800 ppb. Distinct seasonality of H₂ mixing ratios was observed, with higher values recorded during winter months. Also, distinct daily variations of H₂ levels often were observed, with morning and evening H₂ maxima associated with traffic rush hours. Diurnal variation of hydrogen concentrations at both locations differs seasonally due to different micrometeorological conditions and source patterns, including car traffic intensity.

Słowa kluczowe

Wydawca

-

Rocznik

Tom

23

Numer

2

Opis fizyczny

p.427-434,fig.,ref.

Twórcy

autor
  • Faculty of Physics and Applied Computer Science, AGH-University of Science and Technology, al.Mickiewicza 30, 30-059 Krakow, Poland
autor
  • Faculty of Physics and Applied Computer Science, AGH-University of Science and Technology, al.Mickiewicza 30, 30-059 Krakow, Poland
  • Institute of Meteorology and Water Management, National Research Institute, Institute of Meteorology and Water Management-National Research Institute-IMGW-PIB Branch of Krakow, Piotra Borowego 14, 30-215 Krakow, Poland
autor
  • Institute of Nuclear Physics, Polish Academy of Science, Radzikowskiego 152, 31-342 Krakow, Poland
autor
  • Faculty of Physics and Applied Computer Science, AGH-University of Science and Technology, al.Mickiewicza 30, 30-059 Krakow, Poland

Bibliografia

  • 1. KHALIL M.A.K., RASMUSSEN R.A. Global increase of atmospheric molecular hydrogen. Nature 347, 743, 1990.
  • 2. SCHMIDT U. The latitudinal and vertical distribution of molecular hydrogen in the troposphere. J. Geophys. Res. 83, 941, 1978.
  • 3. SCRANTON M.I., BARGER W.R., HERR F.L. Molecular hydrogen in the urban troposphere: measurements of seasonal variability. J. Geophys. Res. 85, 5575, 1980.
  • 4. SIMMONDS P.G., DERWENT R.G., O’DOHERTY S., RYALL D.B., STEELE L.P., LANGENFELDS R.L., SALAMEH P., WANG H.J., DIMMER C.H., HUDSON L.E. Continuous high-frequency observations of hydrogen at the Mace Head baseline atmospheric monitoring station over the 1994-1998 period, J. Geophys. Res., 105, 12105, 2000.
  • 5. STEINBACHER M., FISCHER A., VOLLMER M.K., BUCHMANN B., REIMANN S., HUEGLIN C. Perennial observations of molecular hydrogen (H₂) at a suburban site in Switzerland. Atmos. Environ. 41, 2111, 2007.
  • 6. HAMMER S., LEVIN I. Seasonal variation of the molecular hydrogen uptake by soils inferred from continuous atmospheric observations in Heidelberg, southwest Germany. Tellus B, 61, (3), 556, 2009.
  • 7. GRANT A., STANLEY K.F., HENSHAW S.J., SHALLCROSS D.E., O’DOHERTY S. High-frequency urban measurements of molecular hydrogen and carbon monoxide in the United Kingdom, Atmos. Chem. Phys., 10, 4715, 2010.
  • 8. PRATHER M.J., An environmental experiment with H₂?. Science 302, 581, 2003.
  • 9. SCHULTZ M.G., DIEHL T., BRASSEUR G.P., ZITTEL W. Air pollution and climate-forcing impacts of a global hydrogen economy. Science 302, 624, 2003.
  • 10. TROMP T.K., SHIA R.-L., ALLEN M., EILER J.M., YUNG Y.L. Potential environmental impact of a hydrogen economy on the stratosphere. Science 300, 1740, 2003.
  • 11. WARWICK N.J., BEKKI S., NISBET E.G., PYLE J.A. Impact of a hydrogen economy on the stratosphere and troposphere studied in a 2-D model. Geophys. Res. Lett. 31, L05107 doi:10.1029/2003GL019224. 2004.
  • 12. CONSTANT P., POISSANT L., VILLEMUR R. Tropospheric H₂ budget and the response of its soil uptake under the changing environment. Sci. Total Environ., 407, 1809, 2009.
  • 13. EHHALT D.H., ROHRER F. The tropospheric cycle of H₂: a critical review. Tellus B, 61, 500, 2009.
  • 14. RAHN T., EILER J.M., BOERING K.A., WENNBERG P.O., McCARTHY M.C., TYLER S., SCHAUFFLER S., DONNELLY S., ATLAS E. Extreme deuterium enrichment in stratospheric hydrogen and the global atmospheric budget of H₂. Nature, 424, 918, 2003.
  • 15. NOVELLI P.C., LANG P.M., MASARIE K.A., HURST D.F., MYERS R., ELKINS J.W. Molecular hydrogen in the troposphere: Global distribution and budget, J. Geophys. Res., 104, 30427, 1999.
  • 16. PRICE H., JAEGL´E L., RICE A., QUAY P., NOVELLI P.C., GAMMON R. Global budget of molecular hydrogen and its deuterium content: constraints from ground station, cruise, and aircraft observations. J. Geophys. Res., 112, D22108, doi:10.1029/2006JD008152, 2007.
  • 17. CONRAD R., SEILER W. Influence of temperature, moisture and organic carbon on the flux of H₂ and CO between soil and atmosphere: Field studies in subtropical regions. J. Geophys. Res., 90, 5699, 1985.
  • 18. RHEE T.S., BRENNINKMEIJER C.A.M., ROCKMANN T. The overwhelming role of soils in the global atmospheric hydrogen cycle. Atmos. Chem. Phys., 6, 1611, 2006.
  • 19. SCHMITT S., HANSELMANN A., WOLLSSCHLAGER U., HAMMER S., LEVIN I. Investigation of parameters controlling the soil sink of atmospheric molecular hydrogen. Tellus B, 61, 416, 2009.
  • 20. XIAO X., PRINN R.G., SIMMONDS P., NOVELLI P.C., HUANG L., LANGENFELDS R.L., O’DOHERTY S., KRUMMEL P.B., FRASER P.J., PORTER L.W., WEISS R.F., SALAMEH P., WANG H.J. Optimal estimation of the soil uptake rate of molecular hydrogen from the Advanced Global Atmospheric Gases Experiment and other measurements. J. Geophys. Res., 112, D07303, doi:10.1029/2006JD007241, 2007.
  • 21. AALTO T., LALLO M., HATAKKA J., LAURILA T. Atmospheric hydrogen variations and traffic emissions at an urban site in Finland. Atmos. Chem. Phys., 9, 7387, 2009.
  • 22. VOLLMER M.K., JUERGENS N., STEINBACHER M., REIMANN S., WEILENMANN M., BUCHMANN B. Road vehicle emissions of molecular hydrogen (H₂) from a tunnel study. Atmos. Environ., 41, 8255, 2007.
  • 23. YVER C., SCHMIDT M., BOUSQUET P., ZAHOROWSKI W., RAMONET M. Estimation of the molecular hydrogen soil uptake and traffic emissions at a suburban site near Paris through hydrogen, carbon monoxide, and radon-222 semicontinuous measurements. J. Geophys. Res, 114, D18304, doi:10.1029/2009JD012122, 2009.
  • 24. LALLO M., AALTO T., HATAKKA J., LAURILA T. Hydrogen soil deposition at an urban site in Finland. Atmos. Chem. Phys., 9, 8559, 2009.
  • 25. BELLUCCI F., BOGNER J.E., STURCHIO N.C. Urban Geochemistry: Greenhouse Gas Emissions at the Urban Scale. Elements, 8, 445, 2012.
  • 26. HAMMER S., VOGEL F., KAUL M., LEVIN I. The H₂/CO ratio of emissions from combustion sources: comparison of top-down with bottom-up measurements in southwest Germany, Tellus B, 61, (3), 547, 2009.
  • 27. YVER C.E., PISON I.C., FORTEMS-CHEINEY A., SCHMIDT M., CHEVALLIER F., RAMONET M., JORDAN A., SØVDE O.A., ENGEL A., FISHER R.E., LOWRY D., NISBET E.G., LEVIN I., HAMMER S., NECKI J., BARTYZEL J., REIMANN S., VOLLMER M. K., STEINBACHER M., AALTO T., MAIONE M., ARDUINI J., O'DOHERTY S., GRANT A., STURGES W.T., FORSTER G.L., LUNDER C.R., PRIVALOV V., PARAMONOVA N., WERNER A., BOUSQUET P. A new estimation of the recent tropospheric molecular hydrogen budget using atmospheric observations and variational inversion. Atmos. Chem. Phys., 11, 3375, 2011.
  • 28. BARNES D.H., WOFSY S.C., FEHLAU B.P., GOTTLIEB E.W., ELKINS J.W., DUTTON G.S., NOVELLI P.C. Hydrogen in the atmosphere: observations above a forest canopy in a polluted environment, J. Geophys. Res., 108, 4197, doi:10.1029/2001JD001199, 2003.
  • 29. SANDERSON M.G., COLLINS W.J., DERWENT R.G., JOHNSON C.E. Simulation of global hydrogen levels using a Lagrangian three-dimensional model. J. Atmos. Chem., 43, 15, 2003.
  • 30. WIOŚ Kraków – National report about state of environment – Malopolska province, 2008.
  • 31. A comprehensive assessment of the safety of traffic on the national road network subordinated to DODP Krakow for the years 1995-1997. Office of Design and Research Roads and Bridges “Transprojekt – Warszawa,” Warszawa, maj, 1998.
  • 32. GROMBIK I. Elaboration a gas chromatographic method for the continuous hydrogen concentration measurement in the air, PhD Thesis, Institute of Nuclear Physics Polish Academy of Sciences, Krakow 2009 [In Polish], http://www.ifj.edu.pl/msd/rozprawy_dr/rozpr_Grombik.pdf
  • 33. GROMBIK I., LASA J., ŚLIWKA I., MOCHALSKI P., PUSZ J., JACKOWICZ-KORCZYŃSKI M. The new methodology of hydrogen measurement in the air; Environment Protection Engineering, 32, No.3/2006, PL ISSN 3024-8828, Index 357200, 75, 2006.
  • 34. JORDAN A., STEINBERG B. Calibrating Measurements of Atmospheric Hydrogen, Atmos. Meas. Tech., 4, 509, 2011.
  • 35. VOLLMER M.K., WALTER S., BOND S.W., SOLTIC P., RÖCKMANN T. Molecular hydrogen (H₂) emissions and their isotopic signatures (H/D) from a motor vehicle: implications on atmospheric H₂. Atmos. Chem. Phys., 10, 5707, 2010.
  • 36. ZIMNOCH M., JELEN D., GALKOWSKI M., KUC T., NECKI J., CHMURA L., GORCZYCA Z., JASEK A., ROŻAŃSKI K. Partitioning of atmospheric carbon dioxide over Central Europe: insights from combined measurements of CO₂ mixing ratios and their carbon isotope composition. Isot. Environ. Healt. S., 48, (3), 421, 2012.
  • 37. BARTYZEL J., NECKI J.M., ZIEBA D., ROZANSKI K., GASIOREK M. Uptake of atmospheric hydrogen by soils: a case study from southern Poland. Eur. J. Soil Sci., 64, 597, 2013.
  • 38. BOND S.W., VOLLMER M.K., STEINBACHER M., HENNE S., REIMANN S. Atmospheric molecular hydrogen (H₂): observations at the high-altitude site Jungfraujoch, Switzerland, Tellus B, 63, (1), 64, 2011.
  • 39. PAWLAK W., FORTUNIAK K., SIEDLECKI M. Carbon dioxide flux in the centre of Łódź, Poland – analysis of a 2-year eddy covariance measurement data set. Int. J. Climatol., 31, 232, 2011.

Typ dokumentu

Bibliografia

Identyfikatory

Identyfikator YADDA

bwmeta1.element.agro-92752ab1-841a-4679-b19b-2ba07e328b1e
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.