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2018 | 27 | 5 |

Tytuł artykułu

Chemical reduction of nitrate using nanoscale bimetallic iron/copper particles

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
Nanoscale zero-valent iron (NZVI) as an effective material has been applied to reduce nitrate. Yet NZVI has defects of aggregation and oxidation. To overcome these disadvantages, nanoscale bimetallic iron/copper particles were introduced to reduce nitrate in this work. In this paper, nanoscale bimetallic Fe/Cu particles were prepared by the liquid phase chemical reduction method; the particles were characterized by scanning electron microscopy (SEM) and x-ray diffraction (XRD). The effect of prepared particles was evaluated by reducing synthetic nitrate wastewater, and batch experiments were conducted to investigate the effect of initial nitrate concentration and various Cu loading on nitrate reduction by nanoscale bimetallic Fe/Cu particles. The results indicated that nitrate could be completely removed in 20 min reaction by nanoscale bimetallic Fe/Cu particles when Cu loading was 5% and initial nitrate concentration was 80 mg/L. As a result, the nitrate in wastewater was converted into ammonium and nitrogen gas, with nitrite as an intermediate by-product.

Słowa kluczowe

Wydawca

-

Rocznik

Tom

27

Numer

5

Opis fizyczny

p.2023-2028,fig.,ref.

Twórcy

autor
  • School of Environmental Science and Engineering, Key Laboratory of Subsurface Hydrology and Ecology in Arid Areas of Education Ministry, Chang’an University, Xi’an, China
autor
  • School of Environmental Science and Engineering, Key Laboratory of Subsurface Hydrology and Ecology in Arid Areas of Education Ministry, Chang’an University, Xi’an, China
autor
  • School of Environmental Science and Engineering, Key Laboratory of Subsurface Hydrology and Ecology in Arid Areas of Education Ministry, Chang’an University, Xi’an, China
autor
  • School of Environmental Science and Engineering, Key Laboratory of Subsurface Hydrology and Ecology in Arid Areas of Education Ministry, Chang’an University, Xi’an, China
autor
  • School of Environmental Science and Engineering, Key Laboratory of Subsurface Hydrology and Ecology in Arid Areas of Education Ministry, Chang’an University, Xi’an, China
autor
  • School of Environmental Science and Engineering, Key Laboratory of Subsurface Hydrology and Ecology in Arid Areas of Education Ministry, Chang’an University, Xi’an, China
autor
  • School of Environmental Science and Engineering, Key Laboratory of Subsurface Hydrology and Ecology in Arid Areas of Education Ministry, Chang’an University, Xi’an, China

Bibliografia

  • 1. SIQINGXIA, FOHUAZHONG, YANHAOZHANG, HAIXIANGLI, XINYANG. Bio-reduction of nitrate from groundwater using ahydrogen-based membrane biofilm reactor. Journal of Environmental Sciences. 22 (2), 257, 2010.
  • 2. XIONG Z., ZHAO D., PAN G. Rapid and controlled transformation of nitrate in water and brine by stabilized iron nanoparticles. Journal of Nanoparticle Research. 11, 807, 2009.
  • 3. GHAFARI S., HASAN M., AROUA M.K. Bio-electrochemical removal of nitrate from water and wastewater--a review. Bioresource Technology. 99, 3965, 2008.
  • 4. DZIUBEK A.M., MAĆKIEWICZ J. Removal of nitrates from water by selective ion exchange. Environment Protection Engineering. 35 (1), 171, 2009.
  • 5. RAZI EPSZTEIN, ODED NIR, ORI LAHAV, MICHAL GREEN. Selective nitrate removal from groundwater using a hybrid nanofiltration – reverse osmosis filtration scheme. Chemical Engineering Journal. 279, 372, 2015.
  • 6. FATMA GUESMI, SOUMAYA HARBI, SAMEH AMOURI, ISLEM LOUATI, CHIRAZ HANNACHI, AND BÉCHIR HAMROUNI. Application of Response Surface Methodology to Optimize Nitrate Removal from Water by Electrodialysis. Chemistry Letters. 45(12), 1369, 2016.
  • 7. SRINU NAIK S., PYDI SETTY Y. Optimization of parameters using response surface methodologyand genetic algorithm for biological denitrification of wastewater. Interational Journal of Environmental Science and Technology. 11 (3), 823, 2013.
  • 8. ABBAS REZAEEHATAM, GODINISAID, DEHESTANIAHMAD, REZA YAZDANBAKHSHG-HOLAMREZA, MOSAVIANOSHIRAVAN KAZEMNEJAD Biological denitrification by Pseudomonas stutzeri immobilizedon microbial cellulose. World Journal of Microbiology&Biotechnology. 24 (11), 2397, 2008.
  • 9. HU S., ZHANG C., YAO H. Intensify chemical reduction to remove nitrate from groundwater via internal microelectrolysis existing in nano-zero valent iron/granular activated carbon composite. Desalination & Water Treatment. 57 (30), 14158, 2016.
  • 10. PARK J.Y., BYUN H.J., CHOI W.H. Cement paste column for simultaneous removal of fluoride, phosphate, and nitrate in acidic wastewater. Chemosphere. 70 (8), 1429, 2008.
  • 11. YIMING S.U., ADEYEMI S. ADELEYE, YUXIONG HUANG, XIAOYA SUN, CHAOMENG DAI, XUEFEI ZHOU, YALEI ZHANG, ARTURO A. KELLER. Simultaneous removal of cadmium and nitrate in aqueous media by nanoscalezerovalent iron (nZVI) and Au doped nZVI particles. Water Research. 63, 102, 2014.
  • 12. ZHANG J., HAO Z., ZHANG Z., YANG Y., XU X. Kinetics of nitrate reductive denitrification by nanoscale zero-valent iron. Process Safety & Environmental Protection. 88, 439, 2010.
  • 13. ZIAJAHROMI S., KHANIZADEH M., KHIADANI M., ZAND A.D., MEHRDAD M. Experimental evaluation of nitrate reduction from water using synthesis nanoscale zero-valent iron (NZVI) under aerobic conditions. Middle East Journal of Scientific Research. 16 (2), 205, 2013.
  • 14. PHENRAT T., SALEH N., SIRK K., TILTON R.D., LOWRY G.V. Aggregation and sedimentation of aqueous nanoscalezerovalent iron dispersions. Environmental Science & Technology. 41, 284, 2007.
  • 15. SHI L.N., ZHANG X., CHEN Z.L. Removal of Chromium (VI) from wastewater using bentonite-supported nanoscale zero-valent iron. Water research. 45, 886, 2011.
  • 16. ZHAN J., ZHENG T., PIRINGER G., DAY C., MCPHERSON G.L., LU Y., PAPADOPOULOS K., JOHN V.T. Transport characteristics of nanoscale functional zerovalent iron/silica composites for in situ remediation of trichloroethylene. Environmental Science & Technology. 42, 8871, 2008.
  • 17. TSENG H.H., SU J.G., LIANG C. Synthesis of granular activated carbon/zero valent iron composites for simultaneous adsorption/dechlorination of trichloroethylene. Journal of hazardous materials. 192, 500, 2011.
  • 18. LIU T., LIN Z., SUN D., XIN T. Entrapment of nanoscale zero-valent iron in chitosan beads for hexavalent chromium removal from wastewater. Journal of hazardous materials. 184, 724, 2010.
  • 19. ZHOU HONGYI, XU XINHUA, WANG DAHUI. Catalytic Dechlorination and Kinetics of o-Dichlorobenzene by Pd/Fe. Chinese Journal of Chemical Engineering. 12 (4), 505, 2004.
  • 20. FENG H.E., DONGYE ZHAO. Preparation and Characterization of a New Class of Starch-Stabilized Bimetallic Nanoparticles for Degradation of Chlorinated Hydrocarbons in Water. Environmental Science & Technology. 39 (9), 3314, 2005.
  • 21. WANG W., JIN Z.H., LI T.L., ZHANG H., GAO S. Preparation of spherical iron nanoclusters in ethanol-water solution for nitrate removal. Chemosphere. 65, 1396, 2006.
  • 22. ZHANG W.X. Nanoscale Iron Particles for Environmental Remediation: An Overview. Journal of Nanoparticle Research. 5, 323, 2003.
  • 23. HOSSEINI S.M., ATAIE-ASHTIANI B., KHOLGHI M. Nitrate reduction by nano-Fe/Cu particles in packed column. Desalination. 276, 214, 2011.
  • 24. XU XINHUA, WEI JIANJUN, WANGDAHUI. Studies on dechlorination of chlorophenols with Pd/Fe and nanoscale Pd/Fe.China Environmental Science. 24 (1), 76, 2004.
  • 25. ZHANG Y., LI Y., LI J., HU L., ZHENG X. Enhanced removal of nitrate by a novel composite: Nanoscale zero valent iron supported on pillared clay. Chemical Engineering Journal. 171, 526, 2011.
  • 26. LIOU Y.H., LO S.L., LIN C.J., KUAN W.H., WENG S.C. Chemical reduction of an unbuffered nitrate solution using catalyzed and uncatalyzednanoscale iron particles. Journal of hazardous materials. 127, 102, 2005.

Typ dokumentu

Bibliografia

Identyfikatory

Identyfikator YADDA

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