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2019 | 52 | 2 |

Tytuł artykułu

Dissipation of nitrapyrin (nitrification inhibitor) in subtropical soils

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
Nitrapyrin (2-chloro-6-(trichloromethyl)pyridine) is a specific nitrification inhibitor, applied in soils for reducing the nitrification process of nitrogenous fertilizers. The overall effect of nitrapyrin is enhancing the efficiency of nitrogenous fertilizers in soils and also controlling environmental pollution in water by preventing nitrate leaching in soils. Dissipation of nitrapyrin was evaluated in subtropical soils at two fortification levels of 2 and 4 µg·g⁻¹. The extraction of nitrapyrin was done by quick, easy, cheap, rugged and safe (QuEChERS) method and quantitative analysis – by high-performance liquid chromatography (HPLC). Nitrapyrin residues declined consistently with time in both types of soils and were not detectable (<0.05 µg·g⁻¹) on the 45th day at 2 µg·g⁻¹ and on the 60th day at 4 µg·g⁻¹ application rate. Dissipation of nitrapyrin occurred in a single phase with the persistence data fitting well to the first-order kinetics. The half-life of nitrapyrin was 9.6 and 9.9 d at 2 µg·g⁻¹ and 16.1 d and 17.3 d at 4 µg·g⁻¹ application rate in both types of soils. The results revealed higher persistence of nitrapyrin at higher concentration (4 µg·g⁻¹) in both types of soils, probably because of high temperature and humidity in subtropical soils.

Słowa kluczowe

Wydawca

-

Rocznik

Tom

52

Numer

2

Opis fizyczny

p.173-181,fig.,ref.

Twórcy

autor
  • Department of Chemistry, College of Basic Sciences and Humanities, Govind Ballabh Pant University of Agriculture and Technology, Pantnagar-263145, India
  • Department of Chemistry, College of Basic Sciences and Humanities, Govind Ballabh Pant University of Agriculture and Technology, Pantnagar-263145, India
  • Department of Soil Science, College of Basic Sciences and Humanities, Govind Ballabh Pant University of Agriculture and Technology, Pantnagar-263145, India

Bibliografia

  • [1] Ali, R., Iqbal, J., Tahiri, G.R., Mahmood, T., 2008. Effect of 3,5-dimethylpyrazole and nitrapyrin on nitrification under high soil temperature. Pakistan Journal of Botany, 40(3): 1053–1062.
  • [2] Amberger, A., 1989. Research on dicyandiamide as a nitrification inhibitor and future outlook. Communications in Soil Science and Plant Analysis, 20: 1933–1955. DOI: 10.1080/00103628909368195.
  • [3] Anastassiades, M., Lehotay, S.J., Stajnbaher, D., Schenck, F.J., 2003. Fast and easy multi-residue method employing acetonitrile extraction/partitioning and dispersive solid-phase extraction for the determination of pesticide residues in produce. Journal of the Association of Analytical Chemist International, 86(2): 412–431.
  • [4] Burzaco, J.P., Smith, D.R., Vyn, T.J., 2013. Nitrous oxide emissions in Midwest US maize production vary widely with band-injected N fertilizer rates, timing and nitrapyrin presence. Environmental Research Letters, 8: 11.
  • [5] Chemical Fact Sheet (CFS) 6/85 for nitrapyrin, (1985).
  • [6] Forster, P., Ramaswamy, V., Artaxo, P., 2007. Changes in atmospheric constituents and in radiative forcing. In: S. Solomon, D. Qin, M. Manning, et al. (Eds.), Climate change 2007: The physical science basis. Contribution of Working Group I to the fourth assessment report of the intergovernmental panel on climate change. New York–Cambridge, UK: Cambridge University Press.
  • [7] Gavrilescu, M., 2005. Fate of pesticides in the environment and its bioremediation. Engineering in Life Sciences, 5(6): 497–526.
  • [8] Habibullah, H., Nelson, K.A., Motavalli, P.P., 2018. Management of Nitrapyrin and Pronitridine Nitrification Inhibitors with Urea Ammonium Nitrate for Winter Wheat Production. Agronomy, 8: 204–216.
  • [9] McCarty, G.W., Bremner, J.M., 1990. Persistence of effects of nitrification inhibitors added to soils. Communications in Soil Science and Plant Analysis, 21: 639–648.
  • [10] Laskowski, D.A., Swann, R.L., McCall, P.J., Bidlock, H.D., 1983. Soil degradation studies. Residue Review, 85: 139– 47.
  • [11] Liu, T., Liang, Y., Chu, G., 2017. Nitrapyrin addition mitigates nitrous oxide emissions and raises nitrogen use efficiency in plastic-film-mulched drip-fertigated cotton field. PLOS ONE, 12(5): e0176305.
  • [12] Luo, Y., Monica B., Hao, B.X., 2017. Nutrient uptake and leaching from soil amended with cattle manure and nitrapyrin. Communications in Soil Science and Plant Analysis, 48: 1438–1454.
  • [13] Page, A.L., Miller, R.H., Kenney, D.R., 1982. Methods of soil analysis. Part 2, No. 9 Agronomy Series ASA-SSSA Publisher, Madison.
  • [14] Prasad, R. 2009. Efficient fertilizer use: The key to food security and better environment. Journal of Tropical Agriculture and Food Science, 47(1–2): 1–17.
  • [15] Srivastava, A., Rawat, K.S., Bhatt, S.C., Rawat, D., Srivastava, P.C., 2016. Degradation of AM nitrification inhibitor in soil of Subtropical region. Communications in Soil Science and Plant Analysis, 47(17): 1961–1966.
  • [16] Touchton, J.T., Hoeft, R.G., Welch, L.F., Argyilan, W.L., 1979. Loss of nitrapyrin from soils as affected by pH and temperature. Agronomy Journal, 71(5): 865–869.
  • [17] Zerulla, W., Barth, T., Dressel, J., Erhardt, K., Von Locquenghien, K.H., Pasda, G., Radle, M., Wissemeier, A.H., 2001. 3,4-Dimethylpyrazole phosphate (DMPP) – a new nitrification inhibitor for agriculture and horticulture. An Introduction to Biology and Fertility of Soils, 34: 79–84. DOI: 10.1007/s003740100380.

Typ dokumentu

Bibliografia

Identyfikatory

Identyfikator YADDA

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