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2016 | 25 | 1 |

Tytuł artykułu

Removal of copper using clay admixed with quarry fines as landfill liners

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
The liners in a sanitary landfill play a significant role in reducing the leachate migration and minimizing groundwater pollution. This research investigated a method for the removal of copper ions from aqueous solutions using natural clay admixed with quarry fines as a liner material in landfills. Batch experiments were carried out under different conditions such as pH, contact time, adsorbent dose, and metal concentration. The results showed that the metal ions uptake by clay (admixed with quarry fines) was rapid at from 3 to 15 minutes, after which adsorption of metal ions remains constant. The equilibrium was achieved practically in 15 min with a removal percentage of copper equal to 94.5%. The removal of copper increased when the pH increased from 2 to 5.6. At pH values higher than 5.6, a reduction in the removal efficiency was observed. The experimental results were mathematically modeled according to the two known adsorption models of Langmuir and Freundlich and the data better fit the Freundlich isotherm model. Thus, clay admixed with quarry fines used in this work, as adsorbent for Copper removal, revealed great retention capacity, making it very suitable for use as clay barriers in public landfills.

Słowa kluczowe

Wydawca

-

Rocznik

Tom

25

Numer

1

Opis fizyczny

p.377-384,fig.,ref.

Twórcy

  • Research Scholar, Department of Civil Engineering, University College of Engineering (BIT Campus), Anna University, Tiruchirappalli, India
  • Department of Civil Engineering, University College of Engineering, (BIT Campus), Anna University, Tiruchirappalli, India
  • Department of Civil Engineering, National Institute of Technology, Tiruchirappalli, India

Bibliografia

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  • 3. BELLIR K., LEHOEIKH M.B., MENIAI H., GHERBI N. Study of the retention of heavy metals by natural material used as liners in landfills. Desalination, 185, 111, 2005.
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  • 6. AHN W.Y., KANG M.S., YIM S.K., CHOI K.H. Advanced landfill leachate treatment using an integrated membrane process. Desalination, 149, 109, 2002.
  • 7. SEVIL VELI, BILGE ALYUZ. Adsorption of copper and zinc from aqueous solutions by using natural clay. Journal of Hazardous Materials, 149, 226, 2007.
  • 8. OLU-OWOLABIB.I., POPOOLA D.B., UNUABONAH E.I. Removal of Cu2+ and Cd2+ from Aqueous Solution by Bentonite Clay Modified with Binary Mixture of Goethite and Humic Acid. Water, Air and Soil Pollution, 211 (1-4), 459, 2010.
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  • 35. CHUN-RONG WANG, XIN REN, WEN-XIU LI, ZHIFEI HOU, CHAO KE, QI GENG. Adsorption of Zinc and Copper Heavy Metal Ions from Smelting Wastewater Using Modified Lava Particles. Pol. J. Environ. Stud. 22 (6),1863, 2013.
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Typ dokumentu

Bibliografia

Identyfikatory

Identyfikator YADDA

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