Treatment of electroplating rinse solution by continuous membrane extraction and diffusion dialysis

• Autorzy: Wodzki R , Szczepanski P.
• Języki publikacji: EN

Abstrakty

EN

This paper studies the recovery and concentration of Zn2+ and Cu2+ metal ions from industrial rinse water containing a mixture of Zn2+, Cu2+, Ca2+, Mg2+, K+, and Na+ salts. Transport and separation experiments were performed in a continuous membrane extraction (CME) system, i.e. in the membrane system composed of two contactors with a cation-exchange polymer membrane (Neosepta CMX) and an organic liquid (liquid membrane) circulating between. The organic solution was composed of kerosene and di-(2-ethylhexyl)-phosphoric acid or salicylaldoxyoxime (Acorga P-50) as the active extractant/carrier. The feed solution has been taken from a rinsing tank working in an industrial electroplating plant. Sulfuric acid (1 M) was applied as the stripping medium for metal ions. The total flux of target metals (Zn2+ and Cu2+) in the MHS with Acorga P-50 or D2EHPA was 97.1% and 71.4%, respectively. The product of the CME process can be further de-acidified by diffusion dialysis with the use of an anion-exchange membrane (Neosepta AFN-7). The coefficients of separation, enrichment, and up-hill transport characteristics indicate that the CME system with Acorga P-50 can be considered a part of a technology for the efficient recovery of Cu2+ and Zn2+ in metal finishing plants.

Słowa kluczowe

EN

diffusion dialysis; cation-exchange polymer membrane; zinc; copper; metal ion; membrane extraction

• Wydawca: -
• Czasopismo: Polish Journal of Environmental Studies
• Rocznik: 2001
• Tom: 10
• Numer: 2
• Opis fizyczny: p.101-111,fig.,ref.

Twórcy

autor

Wodzki R

• Nicolaus Copernicus University, Gagarina 7, 87-100 Torun, Poland

autor

Szczepanski P.

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