Role of municipal sewage sludge in incorporating Cr, Ni, Cu, and Zn into cement clinker

• Autorzy: Liu W. , Cao H. , Xu J. , Liu J. , Huang J. , Huang X. , Li G.
• Języki publikacji: EN

Abstrakty

EN

While simultaneous processing of heavy metal-rich waste and municipal sewage sludge (MSS) in cement kilns may be a useful measure for protecting the environment, simultaneous co-disposal of these two types of wastes has seldom been reported in detail. In this study, we examined how MSS influenced the fixation of heavy metals during clinkerization and determined the main controlling mechanisms through analyzing the polymorphism of tricalcium silicate (C₃S), mineral composition of MSS, and element distribution in the clinker. The results showed that MSS had negative effects on the fixation of heavy metals, with reductions of 12.9%, 8.7%, 3.2%, and 1.2% in the amounts of Cu, Ni, Cr, and Zn fixed, respectively. These changes were mainly attributed to the presence of trace elements – in particular phosphorus from the MSS, which caused the polymorphism of C₃S to change in the order: rhombohed ral→monoclinic→triclinic. As well as occurring as C₂S-C₃P, phosphorus also occurred in new phases of K₂NiP₂O₇, K₂Cu(PO₃)₄, and Cu₄O(PO₄)₂ in cement clinker. In general, trace elements from the MSS, especially phosphorus, decreased the solubility of heavy metals in cement clinker through changing the polymorphism of C₃S, and resulting in a decrease in the fixation ratios of heavy metals.

• Wydawca: -
• Czasopismo: Polish Journal of Environmental Studies
• Rocznik: 2018
• Tom: 27
• Numer: 4
• Opis fizyczny: p.1619-1628,fig.,ref.

Twórcy

autor

Liu W.

• College of Environmental Science and Engineering, State Key Laboratory of Pollution Control and Resource Reuse, Key Laboratory of Yangtze River Water Environment of Education Ministry, Tongji University, Shanghai 200092, China

autor

Cao H.

• College of Environmental Science and Engineering, State Key Laboratory of Pollution Control and Resource Reuse, Key Laboratory of Yangtze River Water Environment of Education Ministry, Tongji University, Shanghai 200092, China

autor

Xu J.

• College of Environmental Science and Engineering, State Key Laboratory of Pollution Control and Resource Reuse, Key Laboratory of Yangtze River Water Environment of Education Ministry, Tongji University, Shanghai 200092, China

autor

Liu J.

• College of Environmental Science and Engineering, State Key Laboratory of Pollution Control and Resource Reuse, Key Laboratory of Yangtze River Water Environment of Education Ministry, Tongji University, Shanghai 200092, China

autor

Huang J.

• College of Environmental Science and Engineering, State Key Laboratory of Pollution Control and Resource Reuse, Key Laboratory of Yangtze River Water Environment of Education Ministry, Tongji University, Shanghai 200092, China

autor

Huang X.

• College of Environmental Science and Engineering, State Key Laboratory of Pollution Control and Resource Reuse, Key Laboratory of Yangtze River Water Environment of Education Ministry, Tongji University, Shanghai 200092, China

autor

Li G.

• College of Environmental Science and Engineering, State Key Laboratory of Pollution Control and Resource Reuse, Key Laboratory of Yangtze River Water Environment of Education Ministry, Tongji University, Shanghai 200092, China

Bibliografia

• 1. ARANDA USÓN A., LÓPEZ-SABIRÓN A.M., FERREIRA G., LLERA SASTRESA E. Uses of alternative fuels and raw materials in the cement industry as sustainable waste management options. Renew. Sust. Energ. Rev. 23, 242, 2013.
• 2. Lv D., Zhu T.L., Liu R.W., Lv Q.Z., Sun Y., Wang H.M., Liu Y., Zhang F. Effects of co-processing sewage sludge in cement kiln on NOx, NH₃ and PAHs emissions. Chemosphere. 159, 595, 2016.
• 3. SHIH P.H., CHANG J.E., LU H.C., CHIANG L.C. Reuse of heavy metal-containing sludges in cement production. Cement. Concrete. Res., 35 (11), 2110, 2005.
• 4. CHEN Y.L., SHIH P.H., CHIANG L.C., CHANG Y.K., LU H.C., CHANG J.E. The influence of heavy metals on the polymorphs of dicalcium silicate in the belite-rich clinkers produced from electroplating sludge. J. Hazard. Mater. 170 (1), 443, 2009.
• 5. ZHANG J., LIU J., LI C., JIN Y., NIE Y., LI J. Comparison of the fixation effects of heavy metals by cement rotary kiln co-processing and cement based solidification/stabilization. J. Hazard. Mater. 165 (1-3), 1179, 2009.
• 6. YAN D.H., KARSTENSEN K.H., HUANG Q.F., WANG Q., CAI M.L. Co-processing of industrial and hazardous wastes in cement kilns: a review of current status and future need in China. Environ. Eng. Sci. 27 (1), 37, 2010.
• 7. VALDERRAMA C., GRANADOS R., CORTINA J.L., GASOL C.M., GUILLEM M., JOSA A. Comparative LCA of sewage sludge valorisation as both fuel and raw material substitute in clinker production. J. Clean. Prod. 51, 205, 2013.
• 8. STASTA P., BORAN J., BEBAR L., STEHLIK P., ORAL J. Appl. Therm. Eng. 26 (13), 1420, 2006.
• 9. NBSC. China Statistics Book 2011. 2012, Beijing: China Statistics Press.
• 10. MOHURD, AQSIQ. Code for Design of Industrial Waste Co-composition in Cement Kiln. China Planning Press: Beijing, 2010.
• 11. MOHURD, AQSIQ. Code for design of sludge co-processing in cement kilns. China Planning Press, Beijing, 2012.
• 12. THOMANETZ E. Solid recovered fuels in the cement industry with special respect to hazardous waste. Waste Manag. Res. 30 (4), 404, 2012.
• 13. HOKFORS B. Phase chemistry in process models for cement clinker and lime production, in http://umu.diva-portal. org/smash/get/diva2:696534/FULLTEXT01.pdf. Thermal Energy conversion Laboratory: Västerbotten, 2014.
• 14. MURAT M., SORRENTINO F. Effect of large additions of Cd, Pb, Cr, Zn, to cement raw meal on the composition and the properties of the clinker and the cement. Cement. Concrete. Res. 26 (3), 377, 1996.
• 15. SINYOUNG S., SONGSIRIRITTHIGUL P., ASAVAPISIT S., KAJITVICHYANUKUL P. Chromium behavior during cement-production processes: a clinkerization, hydration, and leaching study. J. Hazard. Mater. 191 (1-3), 296, 2011.
• 16. SINYOUNG S., ASAVAPISIT S., KAJITVICHYANUKUL P., SONGSIRIRITTHIGUL P.. Speciation of Cr in cement clinkers obtained from co-burning with Cr₂O₃. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment. 649 (1), 210, 2011.
• 17. YANG Y., XUE J., HUANG Q. Studies on the solidification mechanisms of Ni and Cd in cement clinker during cement kiln co-processing of hazardous wastes. Constr. Build. Mater. 57, 138, 2014.
• 18. MA X.W., CHEN H.X., WANG P.M. Effect of CuO on the formation of clinker minerals and the hydration properties. Cement. Concrete. Res. 40 (12), 1681, 2010.
• 19. ALI M.M., AGARWAL S.K., PAHUJA A. Potentials of copper slag utilisation in the manufacture of ordinary Portland cement. Adv. Cem. Res. 25 (4), 208, 2013.
• 20. GINEYS N., AOUAD G., SORRENTINO F., DAMIDOT D. Incorporation of trace elements in Portland cement clinker: Thresholds limits for Cu, Ni, Sn or Zn. Cement. Concrete. Res. 41 (11), 1177, 2011.
• 21. BOLIO-ARCEO H., GLASSER F.P. Zinc oxide in cement clinkering part 1. SystemsSystems CaO-ZnO-Al₂O₃ and CaO-ZnO-Fe₂O₃. Adv. Cem. Res. 10 (1), 25, 1998.
• 22. FANG P., TANG Z.J., HUANG J.H., CEN C.P., TANG Z.X., CHEN X.B. Using sewage sludge as a denitration agent and secondary fuel in a cement plant: A case study. Fuel Process. Tech. 137, 1, 2015.
• 23. LIN Y., ZHOU S., LI F., LIN Y. Utilization of municipal sewage sludge as additives for the production of eco-cement. J. Hazard. Mater. 213-214, 457, 2012.
• 24. HUSILLOS RODRÍGUEZ N., MARTÍNEZ-RAMÍREZ S., BLANCO-VARELA M.T., DONATELLO S., GUILLEM M., PUIG J. The effect of using thermally dried sewage sludge as an alternative fuel on Portland cement clinker production. J. Clean. Prod. 52, 94, 2013.
• 25. XIN W., CHENG L., BI-LAN Y., XU Z., JIANG Z., HUAN-ZHONG W. Statue and application of abroad and home co-processing of municipal solid waste by cement kiln. Bulletin of the Chinese ceramic society. 33 (8), 1989, 2014.
• 26. LIN KL, LIN DF, LUO HL. Influence of phosphate of the waste sludge on the hydration characteristics of eco-cement. J. Hazard. Mater. 168 (2-3), 1105, 2009.
• 27. LIN Y.M., ZHOU S.Q., LI F.Z., LIN Y.X. Utilization of municipal sewage sludge as additives for the production of eco-cement. J. Hazard. Mater. 213, 457, 2012.
• 28. Wang F.Z., Shang D.C., Wang M.G., Hu S.G., Li Y.Q. Incorporation and substitution mechanism of cadmium in cement clinker. J. Clean. Prod., 112, 2292, 2016.
• 29. KATYAL N.K., AHLUWALIA S.C., PARKASH R. Effect of Cr₂O₃ on the formation of C₃S in 3CaO:1SiO₂x:Cr₂O₃ system. Cement. Concrete. Res. 30, 1361, 2000.
• 30. LV Y., LI X., MA B., DE SCHUTTER G. Managing Zn wastes in C₃S: comparison of two incorporation methods. Mater. Struct. 48 (8), 2659, 2014.
• 31. TANG Y., CHUI S.S., SHIH K., ZHANG L.Copper stabilization via spinel formation during the sintering of simulated copper-laden sludge with aluminum-rich ceramic precursors. Environ. Sci. Technol. 45 (8), 3598, 2011.
• 32. STEPHAN D., MALEKI H., KNÖFEL D., B B.E., B R.H. Influence of Cr, Ni, and Zn on the properties of pure clinker phases Part I. C₃S. Cement. Concrete. Res. 29, 545, 1999.
• 33. PEIMING W., HAOXIN L., JIANGUO W. Formation of tricalcium silicate with different content of copper oxide. Journal of the chinese ceramic society. 35 (10), 1353, 2007.
• 34. ODLER I., ABDUL-MAULA S. Polymorphism and hydration of tricalcium silicate doped with ZnO. J. Am. Ceram. Soc. 66 (1), 1, 1983.
• 35. URABE K., SHIRAKAMI T., IWASHIMA M. Superstructure in a Triclinic Phase of Tricalcium Silicate. J. Am. Ceram. Soc. 83 (5), 1253, 2000.
• 36. LV Y., LI X., DE SCHUTTER G., MA B. Stabilization of Cr(III) wastes by C₃S and C₃S hydrated matrix: comparison of two incorporation methods. Mater. Struct. 49 (8), 3109, 2015.
• 37. DUÉE C., BOURGEL C., VÉRON E., ALLIX M., FAYON F., BODÉNAN F. Phosphorus speciation in dicalcium silicate phases: Application to the basic oxygen furnace (BOF) slag. Cement. Concrete. Res. 73, 207, 2015.
• 38. DE NOIRFONTAINE M.N., TUSSEAU-NENEZ S., SIGNES-FREHEL M., GASECKI G., GIROD-LABIANCA C. Effect of Phosphorus Impurity on Tricalcium Silicate T1: From Synthesis to Structural Characterization. J. Am. Ceram. Soc. 92 (10), 2337, 2009.
• 39. LIN K.L., LIN C.Y. Hydration characteristics of waste sludge ash utilized as raw cement material. Cement. Concrete. Res. 35 (10), 1999, 2005.
• 40. HUSILLOS RODRÍGUEZ N., MARTÍNEZ-RAMÍREZ S., BLANCO-VARELA M.T., GUILLEM M PUIG J., LARROTCHA E. Evaluation of spray-dried sludge from drinking water treatment plants as a prime material for clinker manufacture. Cement Concrete. Comp. 33 (2), 267, 2011.

Identyfikatory

DOI

10.15244/pjoes/76915