The synergetic effects in a Fenton-like system catalyzed by nano zero-valent iron (nZVI)

• Autorzy: Yao H. , Hu S. , Wu Y. , Fan L.
• Języki publikacji: EN

Abstrakty

EN

In this study, the synergetic effects in a Fenton-like system catalyzed by nano zero-valent iron (nZVI Fenton-like system) were studied using nitrobenzene (NB) as a model contaminant. The results showed that homogeneous and heterogeneous Fenton processes existed simultaneously in the nZVI Fenton-like system, and a synergetic removal effect between these processes played a considerable role in NB removal. Through quantitative analysis, 36.5% of NB degradation was attributed to the synergetic degradation effect, which was caused by a synergetic catalytic effect between nZVI and dissolved iron ions (Fe3+ and Fe2+). In the bulk solution, the Fe3+/Fe2+ redox rate was accelerated by nZVI, resulting in the efficiency improvement of homogeneous catalysis; in the surface of nZVI, these dissolved iron ions promoted the electrons transfer from nZVI core to shell, enhancing the efficiency of heterogeneous catalysis. The synergetic catalytic effect also improved the utilization-rate of H2O2 by reducing the decomposition caused by Fe3+/Fe2+ redox compared to that in the homogeneous Fenton system. Based on these results, a possible mechanism of synergetic effects in the nZVI Fenton-like system was proposed. These results could provide insight into an nZVI Fenton-like system.

• Wydawca: -
• Czasopismo: Polish Journal of Environmental Studies
• Rocznik: 2019
• Tom: 28
• Numer: 4
• Opis fizyczny: p.2491-2499,fig.,ref.

Twórcy

autor

Yao H.

• Department of Chemistry, Northwestern Polytechnical University, Xi’an, Shaanxi, China

autor

Hu S.

• Department of Chemistry, Northwestern Polytechnical University, Xi’an, Shaanxi, China

autor

Wu Y.

• Department of Chemistry, Northwestern Polytechnical University, Xi’an, Shaanxi, China

autor

Fan L.

• Department of Chemistry, Northwestern Polytechnical University, Xi’an, Shaanxi, China

Bibliografia

• 1. DIAO Y., YAN Z., GUO M., WANG X. Magnetic multimetal co-doped magnesium ferrite nanoparticles: An efficient visible light-assisted heterogeneous Fenton-like catalyst synthesized from saprolite laterite ore, J Hazard Mater, 344, 829, 2018.
• 2. TIAN X., JIN H., NIE Y., ZHOU Z., YANG C., LI Y., WANG Y. Heterogeneous Fenton-like degradation of ofloxacin over a wide pH range of 3.6-10.0 over modified mesoporous iron oxide, Chemical Engineering Journal, 328, 397, 2017.
• 3. RODRIGUES C.S.D., SOARES O.S.G.P., PINHO M.T.,PEREIRA M.F.R., MADEIRA L.M. P-Nitrophenol degradation by heterogeneous Fenton’s oxidation over activated carbon-based catalysts, Applied Catalysis B: Environmental, 219, 109, 2017.
• 4. XU L., WANG J. Magnetic nanoscaled Fe3O4/CeO2 composite as an efficient Fenton-like heterogeneous catalyst for degradation of 4-chlorophenol, Environ Sci Technol, 46 (18), 10145, 2012.
• 5. LI W., WANG Y., IRINI A. Effect of pH and H2O2 dosage on catechol oxidation in nano-Fe3O4 catalyzing UV-Fenton and identification of reactive oxygen species, Chemical Engineering Journal, 244, 1, 2014.
• 6. GUO S., ZHANG G., WANG J. Photo-Fenton degradation of rhodamine B using Fe2O3-Kaolin as heterogeneous catalyst: characterization, process optimization and mechanism, J Colloid Interface Sci, 433, 1, 2014.
• 7. JARAMILLO-P EZ C., NAV O J.A., HIDALGO M.C., BOUZIANI A., AZZOUZI M.E. Mixed α-Fe2O3/Bi2WO6 oxides for photoassisted hetero-Fenton degradation of Methyl Orange and Phenol, Journal of Photochemistry and Photobiology A: Chemistry, 332, 521, 2017.
• 8. 8. ZHANG Y., ZHANG K., DAI C., ZHOU X., SI H. An enhanced Fenton reaction catalyzed by natural heterogeneous pyrite for nitrobenzene degradation in an aqueous solution, Chemical Engineering Journal, 244, 438, 2014.
• 9. DIAO Z.H., XU X.R., JIANG D., LI G., LIU J.J., KONG L.J., ZUO L.Z. Enhanced catalytic degradation of ciprofloxacin with FeS2/SiO2 microspheres as heterogeneous Fenton catalyst: Kinetics, reaction pathways and mechanism, J Hazard Mater, 327, 108, 2017.
• 10. LIU T., YOU H. Photoassisted Fenton-like degradation of polyacrylamide aqueous solutions using iron oxide/TiO2/Al2O3 heterogeneous catalysts, Reaction Kinetics, Mechanisms and Catalysis, 109 (1), 233, 2013.
• 11. WANG Y., FANG J., CRITTENDEN J.C., SHEN C. Novel RGO/alpha-FeOOH supported catalyst for Fenton oxidation of phenol at a wide pH range using solar-lightdriven irradiation, J Hazard Mater, 329, 321, 2017.
• 12. LIU Y., LIU X., ZHAO Y., DIONYSIOU D.D. Aligned α-FeOOH nanorods anchored on a graphene oxide-carbon nanotubes aerogel can serve as an effective Fenton-like oxidation catalyst, Applied Catalysis B: Environmental, 213, 74, 2017.
• 13. SONG R., BAI B., PUMA G.L., WANG H., SUO Y. Biosorption of azo dyes by raspberry-like Fe3O4@yeast magnetic microspheres and their efficient regeneration using heterogeneous Fenton-like catalytic processes over an up-flow packed reactor, Reaction Kinetics, Mechanisms and Catalysis, 115 (2), 547, 2015.
• 14. GOGOI A., NAVGIRE M., SARMA K.C., GOGOI P. Fe3O4-CeO2 metal oxide nanocomposite as a Fentonlike heterogeneous catalyst for degradation of catechol, Chemical Engineering Journal, 311, 153, 2017.
• 15. MIKHAILOV I., KOMAROV S., LEVINA V., GUSEV A., ISSI J.P., KUZNETSOV D. Nanosized zero-valent iron as Fenton-like reagent for ultrasonic-assisted leaching of zinc from blast furnace sludge, J Hazard Mater, 321, 557, 2017.
• 16. YIRSAW B.D., MEGHARAJ M., CHEN Z., NAIDU R. Environmental application and ecological significance of nano-zero valent iron, J Environ Sci (China), 44, 88, 2016.
• 17. BAGAL M.V., GOGATE P.R. Wastewater treatment using hybrid treatment schemes based on cavitation and Fenton chemistry: a review, Ultrason Sonochem, 21 (1), 1, 2014.
• 18. YAMAGUCHI R., KUROSU S., SUZUKI M., KAWASE Y. Hydroxyl radical generation by zero-valent iron/Cu(ZVI/Cu) bimetallic catalyst in wastewater treatment: Heterogeneous Fenton/Fenton-like reactions by Fenton reagents formed in-situ under oxic conditions, Chemical Engineering Journal, 334, 1537, 2018.
• 19. VILARDI G., SEBASTIANI D., MILIZIANO S., VERDONE N., DI PALMA L. Heterogeneous nZVI-induced Fenton oxidation process to enhance biodegradability of excavation by-products, Chemical Engineering Journal, 335, 309, 2018.
• 20. FU F., DIONYSIOU D.D., LIU H. The use of zerovalent iron for groundwater remediation and wastewater treatment: a review, J Hazard Mater, 267, 194, 2014.
• 21. LI J., LIU Q., JI Q.Q., LAI B. Degradation of p -nitrophenol (PNP) in aqueous solution by Fe 0 -PM-PS system throughresponse surface methodology (RSM), Applied Catalysis B: Environmental, 200, 633, 2017.
• 22. JI F., YIN H., ZHANG H., ZHANG Y., LAI B. Treatment of military primary explosives wastewater containing lead styphnate (LS) and lead azide (LA) by mFe 0-PS-O3 process, Journal of Cleaner Production, 188, 860, 2018.
• 23. GOMATHI DEVI L., GIRISH KUMAR S., MOHAN REDDY K., MUNIKRISHNAPPA C. Photo degradation of methyl orange an azo dye by advanced Fenton process using zero valent metallic iron: influence of various reaction parameters and its degradation mechanism, J Hazard Mater, 164 (2-3), 459, 2009.
• 24. WANG W., ZHOU M., MAO Q., YUE J., WANG X. Novel NaY zeolite-supported nanoscale zero-valent iron as an efficient heterogeneous Fenton catalyst, Catalysis Communications, 11 (11), 937, 2010.
• 25. GARRIDO-RAM REZ E.G., THENG B.K.G., MORA M.L. Clays and oxide minerals as catalysts and nanocatalysts in Fenton-like reactions – A review, Applied Clay Science, 47 (3-4), 182, 2010.
• 26. WANG Q., TIAN S., NING P. Degradation Mechanism of Methylene Blue in a Heterogeneous Fenton-like Reaction Catalyzed by Ferrocene, Industrial & Engineering Chemistry Research, 53 (2), 643, 2014.
• 27. HU S., WU Y., YAO H., LU C., ZHANG C. Enhanced Fenton-like removal of nitrobenzene via internal microelectrolysis in nano zerovalent iron/activated carbon composite, Water Sci Technol, 73 (1), 153, 2016.
• 28. SHI J., AI Z., ZHANG L. Fe@Fe2O3 core-shell nanowires enhanced Fenton oxidation by accelerating the Fe(III)/ Fe(II) cycles, Water Research, 59, 145, 2014.
• 29. LIU W., AI Z., CAO M., ZHANG L. Ferrous ions promoted aerobic simazine degradation with Fe@Fe2O3 core–shell nanowires, Applied Catalysis B: Environmental, 150-151, 1, 2014.
• 30. LEE H., LEE H.J., KIM H.E., KWEON J., LEE B.D., LEE C. Oxidant production from corrosion of nanoand microparticulate zero-valent iron in the presence of oxygen: a comparative study, J Hazard Mater, 265, 201, 2014.
• 31. DU B., SU H., WANG S. Palladium supported on carbon nanofiber coated monoliths for three-phase nitrobenzene hydrogenation: Influence of reduction temperature and oxidation pre-treatment, Journal Of Industrial And Engineering Chemistry, 21, 997, 2015.
• 32. WU Y., YAO H., KHAN S., HU S., WANG L. Characteristics and Mechanisms of Kaolinite-Supported Zero-Valent Iron/H2O2 System for Nitrobenzene Degradation, CLEAN - Soil, Air, Water, 45 (3), 1600826, 2017.
• 33. FANG G.D., ZHOU D.M., DIONYSIOU D.D. Superoxide mediated production of hydroxyl radicals by magnetite nanoparticles: Demonstration in the degradation of 2-chlorobiphenyl, Journal Of Hazardous Materials, 250-251 (4), 377, 2013.
• 34. RONAVARI A., BALAZS M., TOLMACSOV P., MOLNAR C., KISS I., KUKOVECZ A., KONYA Z. Impact of the morphology and reactivity of nanoscale zero-valent iron (NZVI) on dechlorinating bacteria, Water Research, 95, 165, 2016.
• 35. SUN Y.P., LI X.Q., CAO J., ZHANG W.X., WANG H.P. Characterization of zero-valent iron nanoparticles, Advances in Colloid & Interface Science, 120 (1-3), 47, 2006.
• 36. KIM S.A., KAMALA-KANNAN S., LEE K.J., PARK Y.J., SHEA P.J., LEE W.H., KIM H.M., OH B.T. Removal of Pb(II) from aqueous solution by a zeolite–nanoscale zero-valent iron composite, Chemical Engineering Journal, 217 (1), 54, 2013.
• 37. SHIMIZU A., TOKUMURA M., NAKAJIMA K., KAWASE Y. Phenol removal using zero-valent iron powder in the presence of dissolved oxygen: Roles ofdecomposition by the Fenton reaction and adsorption/precipitation, Journal Of Hazardous Materials, s 201-202 (1), 60, 2012.
• 38. XIONG Z., LAI B., YUAN Y., CAO J., YANG P., ZHOU Y. Degradation of p -nitrophenol (PNP) in aqueous solution by a micro-size Fe0/O3 process (mFe0/O3): Optimization, kinetic, performance and mechanism, Chemical Engineering Journal, 302, 137, 2016.
• 39. WANG Q., TIAN S., NING P. Ferrocene-Catalyzed Heterogeneous Fenton-like Degradation of Methylene Blue: Influence of Initial Solution pH, Industrial & Engineering Chemistry Research, 53 (15), 6334, 2014.
• 40. MIRZAEI A., CHEN Z., HAGHIGHAT F., YERUSHALMI L. Removal of pharmaceuticals from water by homo/heterogonous Fenton-type processes – A review, Chemosphere, 174, 665, 2017.
• 41. DONG H., HE Q., ZENG G., TANG L., ZHANG L., XIE Y., ZENG Y., ZHAO F. Degradation of trichloroethene by nanoscale zero-valent iron (nZVI) and nZVI activated persulfate in the absence and presence of EDTA, Chemical Engineering Journal, 316, 410, 2017.
• 42. SHI J. On the synergetic catalytic effect in heterogeneous nanocomposite catalysts, Chemical Reviews, 113 (3), 2139, 2013.
• 43. XIONG Z., YUAN Y., LAI B., YANG P., ZHOU Y. Mineralization of ammunition wastewater by a micronsize Fe0/O3process (mFe0/O3), RSC Adv., 6 (61), 55726, 2016.
• 44. YUAN Y., LAI B., TANG Y.-Y. Combined Fe0/air and Fenton process for the treatment of dinitrodiazophenol (DDNP) industry wastewater, Chemical Engineering Journal, 283, 1514, 2016.
• 45. LI J., JI Q., LAI B., YUAN D. Degradation of p-nitrophenol by Fe0/H2O2 /persulfate system: Optimization, performance and mechanisms, Journal of the Taiwan Institute of Chemical Engineers, 80, 686, 2017.

Identyfikatory

DOI

10.15244/pjoes/91939