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2019 | 28 | 4 |

Tytuł artykułu

Synthesizing and characterizing Sawdust biochar/Fe3O4 nanocomposites and its potential application in textile wastewater treatment

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
The present research deals with the synthesis and viability of Sawdust biochar/Fe3O4 nanocomposite toward textile waste water treatment. The structure, functionality, and morphology of the nanocomposite were determined by FT-IR, powder XRD, and SEM. Removal of the textile dye Reactive Blue 21 (RB21) was almost 75% under optimum conditions. The value of Langmuir dimensionless separation factor RL indicated a favorable adsorption (0<RL<1). Langmuir constant (KL, i.e., 0.15) symbolizes that there is high affinity of the adsorbent for the adsorbate. The value of Freundlich constant was found to be 2.78 (n>1), hence denoting favorable sorption. The negative values for free energy indicated a spontaneous reaction. Positive value for enthalpy suggested the endothermic nature of adsorption. The kinetic data showed a pseudo first-order kinetic model. The calculated value of qt agreed with the experimental value of qt at equilibrium. The results depicted that sawdust biochar/Fe3O4 nanocomposites are efficient adsorbents for removing RB21 and has potential application in treatment of textile wastewater.

Słowa kluczowe

Wydawca

-

Rocznik

Tom

28

Numer

4

Opis fizyczny

p.2311-2319,fig.,ref.

Twórcy

autor
  • College of Earth and Environmental Sciences, University of the Punjab, Lahore, Pakistan
autor
  • College of Earth and Environmental Sciences, University of the Punjab, Lahore, Pakistan
autor
  • College of Earth and Environmental Sciences, University of the Punjab, Lahore, Pakistan
autor
  • College of Earth and Environmental Sciences, University of the Punjab, Lahore, Pakistan
autor
  • College of Earth and Environmental Sciences, University of the Punjab, Lahore, Pakistan
autor
  • College of Earth and Environmental Sciences, University of the Punjab, Lahore, Pakistan
autor
  • College of Earth and Environmental Sciences, University of the Punjab, Lahore, Pakistan
autor
  • College of Earth and Environmental Sciences, University of the Punjab, Lahore, Pakistan
autor
  • College of Earth and Environmental Sciences, University of the Punjab, Lahore, Pakistan

Bibliografia

  • 1. ASGHER M. Biosorption of reactive dyes: a review. Water Air Soil Pollut. 223 (5), 2417, 2012.
  • 2. FAGUNDES-KLEN M.R., CERVELIN P.C., VEIT M.T., GONCALVES G.C., BERGAMASCO R., DA SILVA F.V. Adsorption kinetics of blue 5G dye from aqueous solution on dead floating aquatic macrophyte: effect of pH, temperature, and pretreatment. Water Air Soil Pollut. 223 (7), 4369, 2012.
  • 3. SHIRZAD S.M., SAMARGHANDI M., AZIZIAN S., KIM W., LEE S. The removal of hexavalent chromium from aqueous solutions using modified holly sawdust: equilibrium and kinetics studies. Environmental Engineering Research. 16 (2), 55, 2011.
  • 4. MAKARCHUK O.V., DONTSOVA T.A., ASTRELIN I.M. Magnetic nanocomposites as efficient sorption materials for removing dyes from aqueous solutions. Nanoscale Res Lett. 11 (1), 161, 2016.
  • 5. YU S., CHEN Z., CHENG Q., LU Z., LIU M., GAO C. Application of thin-film composite hollow fiber membrane to submerged nanofiltration of anionic dye aqueous solutions. Sep Purif Technol. 88, 121, 2015.
  • 6. VERMA A.K., DASH R.R., BHUNIA P. A review on chemical coagulation/flocculation technologies for removal of colour from textile wastewater. Journal of Environmental Management. 93 (1), 154, 2012.
  • 7. CUIPING B., XIANFENG X., WENQI G., DEXIN F., MO X., ZHONGXUE G., NIAN X. Removal of Rhodamine B, by ozone-based advanced oxidation process. Desalination. 278 (1), 84, 2011.
  • 8. PATIL B.N., NAIK D.B., SHRIVASTAVA V.S. Photocatalytic degradation of hazardous Ponceau-S dye from industrial wastewater using nanosized niobium pentoxide with carbon. Desalination. 269 (1), 276, 2011.
  • 9. FARROKHI M., HOSSEINI S.C., YANG J.K., SHIRZAD-SIBONI M. Application of ZnO–Fe3O4 Nanocomposite on the removal of azo dye from aqueous solutions: kinetics and equilibrium studies. Water Air Soil Pollut. 225 (9), 2113, 2014.
  • 10. JAIN R., SHARMA N., RADHAPYARI K. Electrochemical treatment of pharmaceutical azo dye amaranth from wastewater. J. Appl. Electrochem. 39 (5), 577, 2009.
  • 11. TAN I.A.W., AHMAD A.L., HAMEED B.H. Adsorption of basic dye using activated carbon prepared from oil palm shell: batch and fixed bed studies. Desalination. 225 (1-3), 13, 2008.
  • 12. DE YUSO A.M., RUBIO B., IZQUIERDO M.T. Influence of activation atmosphere used in the chemical activation of almond shell on the characteristics and adsorption performance of activation carbon. Fuel Processing Technology. 119, 74, 2014.
  • 13. GUPTA V.K. Application of low-cost adsorbents for dye removal – A review, Journal of Environmental Management. 90 (8), 2313, 2009.
  • 14. GUPTA V.K., MITTAL A., JAIN R., MATHUR M., SIKARWAR S., Adsorption of Safranin-T from wastewater using waste materials - activated carbon and activated rice husks. J. Colloid Interface Sci. 303 (1), 80, 2006.
  • 15. THINAKARAN N., PANNEERSELVAM P., BASKARALINGAM P., ELANGO D., SIVANESAN S. Equilibrium and kinetic studies on the removal of acid red 114 from aqueous solutions using activated carbons prepared from seed shells, J Hazard Mater. 158 (1), 142, 2008.
  • 16. VIJAYARAGHAVAN K., WON S. W., YUN Y. Treatment of Complex Remazol Dye Effluent Using Sawdust- and Coal-Based Activated Carbons. J Hazard Mater. 167 (1), 790, 2009.
  • 17. SHARMA Y.C., UPADHYAY S.N.U. Removal of a cationic dye from wastewaters by adsorption on activatedcarbon developed from coconut coir. Energy Fuels. 23 (6), 2983, 2009.
  • 18. MAHMOODI N.M., HAYATI B., LAN C. Adsorption of textile dyes on pine cone from colored wastewater: kinetic, equilibrium and thermodynamic studies. Desalination. 268 (1), 117, 2011.
  • 19. SAHA P.D., DEY A., MARIK P. Batch removal of chromium (VI) from aqueous solutions using wheat shell as adsorbent: process optimization using response surface methodology. Desalin Water Treat. 39 (1-3), 95,2012.
  • 20. TAN X.F., LIU Y.G., GU Y.I., XU Y., ZENG G.M., HU X.J., LIU S.B., WANG X., LIU S.M., LI J. Biochar-based nanocomposites for the decontamination of wastewater: A review. Bioresour Technol. 212, 318, 2016.
  • 21. XU P., ZENG G.M., HUANG D.L., FENG C.L., HU S., ZHAO M.H., LAI C., WEI Z., HUANG C., XIE G.X., LIU, Z. F. Use of iron oxide nanomaterials in wastewater treatment: a review. Sci Total Environ. 424, 1, 2012.
  • 22. ZHANG M., GAO B. Removal of arsenic, methylene blue, and phosphate by biochar/AlOOH nanocomposite. Chemical Engineering Journal. 226, 286, 2013.
  • 23. BRAADBAART F., POOLE I., HUISMAN H.D., VAN OS B. Fuel, fire and heat: an experimental approach to highlight the potential of studying ash and char remains from archaeological contexts. J. Archaeol. Sci. 39 (4), 836, 2012.
  • 24. PEREZ G. Morphology Control of Iron Oxide Nanoparticles Produced by Co-precipitation. Microscopy and Microanalysis. 18 (S2), 250, 2012.
  • 25. SHARMA P., DAS M.R. Removal of a cationic dye from aqueous solution using graphene oxide nanosheets: investigation of adsorption parameters. J. Chem. Eng. Data. 58 (1), 151, 2012.
  • 26. AI L., LI M., LI L. Adsorption of methylene blue from aqueous solution with activated carbon/cobalt ferrite/alginate composite beads: kinetics, isotherms, and thermodynamics. J. Chem. Eng. Data, 56 (8), 3475, 2011.
  • 27. BOJIC D.V., RANDELOVIC M.S., ZARUBICA A.R., MITROVIC J.Z. RADOVIC M.D., PURENOVIC M.M., BOJIC A.L., Comparison of new biosorbents based on chemically modified Lagenaria vulgaris shell. Desalin Water Treat, 51 (34-36), 6871, 2013.
  • 28. MADRAKIAN T., AFKHAMI A., MAHMOODKASHNI H., AHMADI M. Adsorption of some cationic and anionic dyes on magnetite nanoparticles-modified activated carbon from aqueous solutions: equilibrium and kinetics study. J. Iran. Chem. Soc. 10 (3) 481, 2013.
  • 29. LO S.F., WANG S.Y., TSAI M.J., LIN L.D. Adsorption capacity and removal efficiency of heavy metal ions by Moso and Ma bamboo activated carbons. Chem. Eng. Res. Des. 90 (9), 1397, 2012.
  • 30. STANKOVIC V., BOZIC D., GORGIEVSKI M., BOGDANOVIC G. Heavy metal ions adsorption from mine waters by sawdust. Chemical Chem. Ind. Chem. Eng. Q. 15 (4), 237, 2009.
  • 31. WANG H., SHEN Y., SHEN C., WEN Y., LI H. Enhanced adsorption of dye on magnetic Fe304via Hcl-assisted sonication pretreatment. Desalination. 284, 122, 2012.
  • 32. RAO A.N., LATHASREE S., SIVASANKAR B., SADASIVAM V., RENGARAJ K. Removal of azo dyes from aqueous solutions using activated carbon as an adsorbent. J Environ Sci Eng. 46 (2), 172, 2004.
  • 33. WANG X., ZHU N., YIN B. Preparation of sludge-based activated carbon and its application in dye wastewater treatment. J Hazard Mater. 153 (1), 22, 2008.
  • 34. AL-DEGS Y.S., EL-BARGHOUTHI M.I., EL-SHEIKH A.H., WALKER G.M., Effect of solution pH, ionic strength, and temperature on adsorption behavior of reactive dyes on activated carbon. Dyes Pigments. 77 (1), 16, 2008.
  • 35. BHATNAGAR A., MINOCHA A. Conventional and nonconventional adsorbents for removal of pollutants from Water. Indian J. Technol. 13, 203, 2006.
  • 36. BOSTROM M., LIMA E.R.A., TAVARES F.W., NINHAM B.W. The influence of ion binding and ion specific potentials on the double layer pressure between charged bilayers at low salt concentrations. J. Chem. Phys. 128 (13), 04B604, 2008.
  • 37. ZHENG H., LIU D., ZHENG Y., LIANG S., LIU Z. Sorption isotherm and kinetic modeling of aniline on Cr-bentonite. J Hazard Mater. 167 (1), 141, 2009.
  • 38. TANHAEI B., AYATI A., LAHTINEN M., SILLANPAA M. Preparation and characterization of a novel chitosan/Al2O3/ magnetite nanoparticles composite adsorbent for kinetic, thermodynamic and isotherm studies of Methyl Orange adsorption. Chem. Eng. J. 259, 1, 2015.
  • 39. KONSTANTINOU I.K., ALBANIS T.A. Adsorptiondesorption studies of selected herbicides in soil-Fly ash mixtures. J. Agric. Food. Chem. 48 (10), 4780, 2000.
  • 40. IQBAL M.J., ASHIQ M.N. Thermodynamics of adsorption of dyes from aqueous media on activated charcoal. Journal of Research in Science. 18 (2), 91, 2007.

Typ dokumentu

Bibliografia

Identyfikatory

Identyfikator YADDA

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