This paper describes the results of research concerning the binding of heavy metals and arsenic (HM+As) by [3-(2-Aminoethylamino)propyl]trimethoxysilane. The studies have been carried out on soils sampled from areas affected by emissions from the Głogów Copper Smelter and Refinery. The currently applied technique of soil stabilization of HMs by pH changing does not guarantee their permanent blocking in a sorption complex. The research aims to increase food safety in areas of industrial impact.
Faculty of Chemistry, Adam Mickiewicz University, Umultowska 89b, 61-614 Poznan, Poland
Bibliografia
1. ROSADA J. The condition of agricultural environment in the area of the impact of Głogów Copper Smelter and Refinery GŁOGOW. RN IOR - PIB, 2008 [In Polish].
2. KABATA-PENDIAS A., PENDIAS H. Biogeochemistry of Trace Elements. PWN Warszawa 1993 [In Polish].
3. KABATA-PENDIAS A., PIOTROWSKA M., WITEK T. Evaluation of the quality and capabilities of the agricultural use of the soils contaminated by heavy metals in rat. “Assessment of the degree of soil and plant contamination with heavy metals and sulfur.” Framework guidelines for agriculture. IUNG Puławy 1993 [In Polish].
4. GRZESIAK P., KURCZEWSKA J., SCHROEDER G. Nanotechnology for Agriculture in rat. Environment and Industry. Vol. 2, Cursiva Poznań, pp. 15-34, 2011 [In Polish].
5. GRZESIAK P., ŁUKASZYK J., GROBELA M., MOTAŁA R. SCHROEDER G., BENDZIŃSKA-BERUS W. The research studies of heavy metal binding by selected silane nano-agents in rat. Environment and Industry. Vol. 3, Cursiva Poznań, pp. 177-198, 2012 [In Polish].
6. GRZESIAK P., ŁUKASZYK J., SCHROEDER G., KURCZEWSKA J. The binding of industrial deposits of heavy metals and arsenic in the soil by 3-aminopropyltrimethoxysilane. Pol. J. Chem. Techn. 2014 [In Polish, In Print].
7. GRZESIAK P. ŁUKASZYK J., GROBELA M., MOTAŁA R. Development of guidelines and the applicability of nanoand photocatalytic processes in agriculture. Report IOR-PIB Poznań, 213, 2012 [In Polish].
8. Methodology for determination of heavy metals in soil samples. The materials of certified Environmental Analysis Laboratory IOR-PIB Poznań, 2011 [In Polish].
9. TESSIER A., CAMPBELL P.G., BISSION M. Sequential extraction procedure for the speciation of particulate trace metals. Anal. Chem. 51, 844, 1979.
10. KARCZEWSKA A. Heavy metals in soils contaminated with emissions from copper smelters – forms and solubility [in Polish]. Zesz. Nauk. AR in Wrocław, No. 432, 2002.
11. KURCZEWSKA J., SCHROEDER G. Silica surface modified by aliphatic amines as effective copper complexing agents, Inter. J. Mater. Res. 101, (8), 1037, 2010.
12. KURCZEWSKA J., SCHROEDER G. Synthesis of silica chemically bonded with poly(ethylene oxide) 4-arm, amineterminated for copper cation removal, Water Environ. Res. 82, (12), 2387, 2010.
13. KURCZEWSKA J., SCHROEDER G. Copper removal by carbon nanomaterials bearing cyclam-functionalized silica, Cent. Eur. J. Chem. 8, (2), 341, 2010.