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2017 | 26 | 3 |

Tytuł artykułu

Advanced treatment of coal chemical industry wastewater by electro-catalysis with Gd-doped Ti/SnO2 anode

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
The preparation of a Gd-doped Ti/SnO₂ anode using the sol-gel method was employed in electrolysis as an advanced treatment of coal chemical industry wastewater. The optimal Gd-doped content and sintering temperature were 2% and 750ºC. The electro-catalytic performance was enhanced after doping with an adequate amount of Gd. The doped Gd accelerated the generation rate and content of hydroxyl radicals in the electrolysis process. Gd was mixed into the SnO₂ lattice by means of displacement to refine the SnO₂ crystalline grain. The diminution of grain size supplied more active sites on the electrode surface. The reaction of TOC degradation was between pseudo zero-order and first-order kinetics, and was more inclined to pseudo first-order kinetics. The performance and the stability test demonstrated that the prepared Ti/Gd-SnO₂ anode was competent and that electrolysis with the anode could serve as a technically feasible method with potential application for the advanced treatment of coal chemical industry wastewater.

Słowa kluczowe

Wydawca

-

Rocznik

Tom

26

Numer

3

Opis fizyczny

p.1097-1104,fig.,ref.

Twórcy

autor
  • Hunan Provincial Key Laboratory of Shale Gas Resource Utilization, Hunan University of Science and Technology, Xiangtan, 411201, China
autor
  • Hunan Provincial Key Laboratory of Shale Gas Resource Utilization, Hunan University of Science and Technology, Xiangtan, 411201, China
autor
  • Key Laboratory of Recycling and Eco-treatment of Waste Biomass of Zhejiang Province, Zhejiang University of Science and Technology, Hangzhou, 310023, China
autor
  • Xiangtan Sewage Treatment Co., Ltd, Xiangtan, 411100, China

Bibliografia

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  • 3. HOU B., HAN H., ZHUANG H., XU P., JIA S., LI K. A novel integration of three-dimensional electro-Fenton and biological activated carbon and its application in the advanced treatment of biologically pretreated Lurgi coal gasification wastewater. Bioresource Technology, 196, 721, 2015.
  • 4. ZHANG C., JIANG Y.H., LI Y.L., HU Z.X., ZHOU L., ZHOU M.H. Three-dimensional electrochemical process for wastewater treatment: A general review. Chemical Engineering Journal, 228, 455, 2013.
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  • 7. HOU B., HAN H., JIA S., ZHUANG H., XU P., WANG D. Heterogeneous electro-Fenton oxidation of catechol catalyzed by nano-Fe₃O₄: kinetics with the Fermi›s equation. Journal of the Taiwan Institute of Chemical Engineers, 56, 138, 2015.
  • 8. HOU B., HAN H., JIA S., ZHUANG H., XU P., LI K. Three-dimensional heterogeneous electro-Fenton oxidation of biologically pretreated coal gasification wastewater using sludge derived carbon as catalytic particle electrodes and catalyst. Journal of the Taiwan Institute of Chemical Engineers, 60, 352, 2016.
  • 9. BERGMANN M.E.H., KOPARAL A.S., IOURTCHOUK T. Electrochemical Advanced Oxidation Processes, Formation of Halogenate and Perhalogenate Species: A Critical Review. Critical Reviews in Environmental Science and Technology, 44 (4), 348, 2014.
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  • 12. TORRES-MARTINEZ L.M., GOMEZ R., VAZQUEZ-CUCHILLO O., JUAREZ-RAMIREZ I., CRUZ-LOPEZ A., ALEJANDRE-SANDOVAL F.J. Enhanced photocatalytic water splitting hydrogen production on RuO₂/La NaTaO₃ prepared by sol-gel method. Catalysis Communications, 12 (4), 268, 2010.
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  • 14. TRIVEDI P., GUPTA P., SRIVASTAVA S., JAYAGANTHAN R., CHANDRA R., ROY P. Characterization and in vitro biocompatibility study of Ti-Si-N nanocomposite coatings developed by using physical vapor deposition. Applied Surface Science, 293, 143, 2014.
  • 15. CUI Y.H., FENG Y.J., LIU J.F., REN N.Q. Comparison of various organic compounds destruction on rare earths doped Ti/Sb-SnO₂ electrodes. Journal of Hazardous Materials, 239, 225, 2012.
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  • 18. CUI Y.H., FENG Y.J., LIU Z.Q. Influence of rare earths doping on the structure and electro-catalytic performance of Ti/Sb-SnO₂ electrodes. Electrochimica Acta, 54 (21), 4903, 2009.
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Typ dokumentu

Bibliografia

Identyfikatory

Identyfikator YADDA

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