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2015 | 58 | 195 |

Tytuł artykułu

The effect of alkyd resin on the stability of binding (3-aminopropyl) triethoxysilane with cellulose and wood

Treść / Zawartość

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
Experiments were conducted using (3-aminopropyl) triethoxysilane (APTES) and alkyd resin in order to improve the reactivity of wood protective preparations with wood. The results presented concern a structural analysis (FTIR, AAS) of modified cellulose and wood, both after chemical reactions with silanes and after water extraction. The FTIR spectrum of pine wood powder was presented after a reaction with organosilane preparations and with the addition of alkyd resin, and then after water extraction. The FTIR analysis detected vibrations of Si-C, Si-O and N-H groups, indicating permanent bonding with the organosilane preparation. The presence of bands at 710 cm-1 (characteristic of vibrations of the silicon bond with an atom of carbon and oxygen) and at 1600-1580 cm-1 (characteristic of deformation vibrations of N–H coming from the amine group) confirmed the reactivity of these preparations with the wood. The results of atomic absorption spectrometry confirmed the stability of the organosilane bonds with the cellulose and the wood.

Wydawca

-

Rocznik

Tom

58

Numer

195

Opis fizyczny

p.91-99,fig.,ref.

Twórcy

autor
  • Department of Chemistry, Poznan University of Life Sciences, Poznan, Poland
autor
  • Department of Chemistry, Poznan University of Life Sciences, Poznan, Poland
autor
  • Department of Chemistry, Poznan University of Life Sciences, Poznan, Poland
autor
  • Department of Chemistry, Poznan University of Life Sciences, Poznan, Poland
autor
  • Institute of Chemical Wood Technology, Poznan University of Life Sciences, Poznan, Poland

Bibliografia

  • Hill, C.A.S., Farahani, M.R.M, Hale, M.D.C. [2004]: The use of organo alkoxysilane coupling agents for wood preservation. Holzforschung 58 [3]: 316–325
  • Hochmańska P., Mazela B., Westin M. [2007]: Biological durability of wood treated with silanes and siloxanes. Annals of Warsaw University of Life Sciences – SGGW, Forestry and Wood Technology 61: 258–262
  • Hochmańska P., Mazela B., Krystofiak T. [2014]: Hydrophobicity and weathering resistance of wood treated with silane-modified protective systems. Drewno 57 [191]: 99–110
  • Mai, C., Millitz, H. [2004] Modification of wood with silicon compounds. Inorganic silicon compounds and sol-gel systems: a review, Wood Science Technology 37: 339–348
  • Muromachi T., Tsujino T., Kamitani K., Maeda K. [2006]: Application of functional coatings by sol-gel method. Journal of Sol-Gel Science and Technology 40: 267–272
  • Ratajczak, I. [2010]: Wiązanie preparatów impregnacyjnych z drewnem i jego głównymi składnikami (Binding of impregnants to wood and its main components). Rozprawy naukowe 411. Wydawnictwo Uniwersytetu Przyrodniczego w Poznaniu. Poznań
  • Ratajczak, I., Wichłacz-Szentner, K., Mazela, B., Hochmańska, P., Rissmann, I. [2010]: Silicon compounds as additives improving coating performance: fixation of silicon compounds with cellulose. European Journal of Wood and Wood Products 68: 483–486
  • Sèbe G., Tingaut P., Safou-Tchiama R., Petraud M., Grelier S., De Jeso B. [2004]: Chemical reaction of maritime pine sapwood (Pinus pinaster Soland) with alkoxysilane molecules: A study of chemical pathways, Holzforschung 58: 511–518
  • Sèbe, G., Brook, M.A. [2001]: Hydrophobization of wood surfaces: covalent grafting of silicone polymers. Wood Sci. Tech. 35: 269–282
  • Tingaut P., Wiegenand O., Mai C., Militz H., Sebe G. [2006]: Chemical reaction of alkoxysilane molecules in wood modified with silanol groups. Holzforschung 60: 271–277
  • Tshabalala, MA., Kingshott, P., Van Landingham, MR., Plackett, D. [2003]: Surface Chemistry and Moisture Sorption Properties of Wood Coated with Multifunctional Alkoxysilanes by Sol-Gel Process. Journal of Applied Polymer Science 88: 2828–2841

Typ dokumentu

Bibliografia

Identyfikatory

Identyfikator YADDA

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