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We have compared the mean contents of Al, combined Ca + Mg as well as of the total content of elements (Ca, Mg, K, Na, Al, Fe, Mn, NH4, Cl, SO4 and NO3) in solutions obtained for the Ofh, AE and Bv soil horizons. Soils were sampled in dry coniferous (Bs), fresh coniferous (Bsw) and mixed deciduousconiferous (BMsw) forest sites. Higher values of combined Ca and Mg content and of total element content were found in the soil solution of all horizons in BMsw sites than in those in Bs and Bsw sites. The amount of Al migrating to aqueous solution is lower in Ofh horizons of BMsw sites than in Bs and Bsw sites. The soil sorption complex of BMsw sites, likewise respective soil solutions, is more abundant in combined bivalent basic cations than that of Bs and Bsw sites. Exchangeable Al content in the Ofh horizon is lowest in BMsw site, and highest in Bsw site. No direct effect was found on the forest floor vegetation on the concentration of soil solutions (expressed as element sum) or on the ionic composition of these solutions taking into account the elements analyzed.
On the basis of 136 soil samples collected from an area of Poland, the effect of the content of organic carbon in the soil on the chemical composition of soil solution was analyzed. With an increase of organic carbon content in the soil, a significant increase of calcium and to a lesser extent of magnesium, bicarbonates and phosphates in the soil solution was observed. No correlation was noted between the organic carbon soil content and the concentration of aluminium in the soil solution. The contents of organic matter in the soil influenced the concentrations of microelements in the soil solution more than the macroelements content in this soil. The concentrations of manganese, iron, zinc and copper were positively correlated, the concentration of molybdenum was negatively correlated and the concentration of boron did not show any relationship with the soils content of organic carbon.
The aim of the present research was to evaluate whether or not, and to what extent, exclusive mineral fertilisation affects the content of water-soluble ions determining the soil salinity. The soil was sampled from the arable layer of a multi-year field experiment carried out in 1974-2007. The research involved differentiated nitrogen fertilisation (factor I, n=3) and potassium fertilisation (factor II, n=4). The content of water-soluble ions was defined in water extract, in the soil to water ratio of 1:5; cations K+, Na+, Ca2+ were determined with the method of emission spectrometry and Mg2+ – with atomic absorption. Anions were analysed with the argentometric (Cl-) and nephelometric (SO4 2-) methods. In addition, electrolytic conductivity (R) was tested with the conductometric method, based on which the salt concentration in the solution (C) and the ionic strength (I) were calculated. The present results were statistically verified. The prolonged application of intensive nitrogen and potassium fertilisation (32 years) significantly differentiated the content of cations: K+, Na+, Ca2+ and Mg2+ as well as anions: Cl- and SO4 2- in soil solution. The contents of K+, Na+, Ca2+, Mg2+ in the soil solutions differed and fell within the range of (mean value) 0.136-0.507 (0.281) K+, 0.398-0.555 (0.472) Na+, 1-2.192 (1.350) Ca2+ and 0.211- 0.365 (0.272) Mg2+ mmol(+)⋅kg-1. The highest nitrogen dose significantly limited the concentration of SO4 2- in the soil solution, while the different doses of potassium did not result in such significant changes in the concentration of the above ions. The content of chlorine ions in the soil solution did not depend significantly on differentiated nitrogen and potassium fertilisation. No effect of the long-term mineral fertilisation on soil salinity was noted.
The aim of the research was to analyse the impact of soil water potential on the concentration of aluminium and selected mineral nutrients in soil solution. Soil acidification is a natural process accelerated by agriculture, and one of the most important factors limiting crop production worldwide. Concentrations of aluminium and selected mineral nutrients in solutions obtained from soil at initial pH 4.2 and after liming at various soil water potential were measured in centrifuged soil solution. Our results showed a significant gradual increase in the concentration of Al and most of mineral nutrients (Ca, Mg and P) with decreasing soil water potential from −3.5 kPa to −0.205 MPa. The results are important in the evaluation and interpretation of plant response to aluminium toxicity when accompanied by changes in water availability.
Investigations were carried out on sandy forest soils from Wielkopolski National Park (west-central Poland), which have been exposed for a long time to anthropogenic pressure. Two comparative extract recovery methods were performed for aqueous soil extracts (ME) at ratios 1:1, and those obtained from so-called saturated paste (MP). Recovered extracts were analyzed for sodium, potassium, magnesium, calcium, aluminium, chloride, fluoride, nitrate and sulphate concentrations, at various depths of two slightly different soil profiles. Higher levels of alkaline cations were obtained in extracts recovered at ratios 1:1, in the case of sandy soils along the entire profile, whereas in profiles with variable lithology, the granulometric composition clearly affected the mechanism of ion release. The patterns of changes in the contents of chlorides and sulphates were similar to those of calcium and magnesium, while fluoride levels in the topsoil differed significantly, depending on the method applied. Differences between the two methods were also significant in the case of aluminium content. The elaboration of aluminium toxicity indices should consider such approaches.
The study was carried out to asses the influence of soil mineral fertilization, manure application and soil liming on changes in the concentration of microelements (B, Cu, Fe, Mn and Zn) in soil solution. The tests were performed on samples of sandy soil collected from long-term fertilization experiments being conducted on lessive soil of the granulometric structure of clayish sand. Soil solution was prepared with the suction method. The concentration of microelements in soil solution was determined by means of the ICP method. The results showed an increase in Fe, Mn, Zn and Cu and a decrease in B and Mo in soil solution when soil was fertilized with nitrogen. The concentration of microelements in soil solution was not significantly influenced when soil was fertilized with phosphorous and potassium. Liming had a significant effect on a decrease in the concentration of Fe, Mn, Zn and Cu and an increase in B and Mo in soil solution. Soil application of manure significantly increased the concentration of microelements in soil solution.
Based on a large number of samples collected from within Polish territory, the concentration of microelements (Fe, Mn, Zn, Cu, B, and Mo) in a soil solution of arable soils of Poland was measured and evaluated, and the possibility of various soil factors as causal agents of this concentration was assessed.
Penguin rookeries are one of the main sources of nutrients for the poor ecosystems of Antarctica. At the current penguin rookeries, and in their vicinity, nitrogen rich ornithogenic soils are formed. Relict ornithogenic soils created at the abandoned rookeries hundreds or even thousands years ago are rich in phosphates. In the region of maritime Antarctica, water plays an important role in distribution and redistribution of nutrients (surface flows and percolation). Soil decomposition processes result in cations and nutrient release. In nutrients originating from relict ornithogenic soils of the Antarctic tundra, phosphates are the dominating elements; while in nutrients originating from contemporary ornithogenic soils nitrogen (mainly ammonia) is the main ingredient. Mineral soils free of penguin influence contain minute amounts of nutrients. Low pH of soil solutions (<4) causes increase of dissolving of phosphate complexes. Near penguin rookery, pH was lowest (2.73-3.33) and intermediate (2.92-3.77) in relict soils. The values of pH were the highest in soil solutions from mineral soil (5.43-7.33). High concentration of cations (mainly K) in soil solutions from the ornithogenic soils and relict ornithogenic soils, suggest their organic (animal) origin.
The effect of intensive irrigation with wastewater on the zinc (Zn) and cadmium (Cd) concentration in soil solution was investigated. The experiment was parallel conducted on two soil profiles. The soil microcosms were watered with purified wastewater and purified wastewater with an the addition of zinc and cadmium. The results indicate clearly that neither intensive overhead irrigation of the soil nor its flooding with these wastewater and exceeded sorptive capacity. The application of treated wastewater and wastewater with heavy metals addition did not appear to pose a threat to the natural environment. In all the cases under analysis, zinc and cadmium concentrations in the soil solution were several-fold lower than the permissible levels.
Badanie nad wykorzystaniem filtru glebowego do oczyszczania wód powiekowych zostały przeprowadzone na poletkach doświadczalnych z udziałem roślin w pobliżu oczyszczalni ścieków Hajdów koło Lublina. Pomiary rozkładu stężeń form azotu takich jak: NH4+, N03", N02‘ na wejściu ścieków oraz na różnych głębokościach filtru glebowego zostały przeprowadzone w czasie, po zastosowaniu nawodnień. Równolegle prowadzono pomiary stanu oksydoredukcyjnego gleby (Eh), na stałe zamontowanymi elektrodami. Praca zawiera wyniki zmian form azotu w roztworze glebowym w czasie nawodnień w funkcji Eh gleby, wykazując dodatnią korelację z azotanami (V) i ujemną z azotanami (III)
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