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Conformational properties of N',N'-dimethylamides of N-acetyldehydroalanine and N-acetyl-[Z]-dehydrophenylalanine

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Siodlak D., Broda M. A., Rzeszotarska B., Koziol A. E., Dybala I.

Acta Biochimica Polonica

2001

tom 48

nr 4

Conformational preferences of Ac-ΔAla-NMe2 and Ac-(Z)-ΔPhe-NMe2 were studied and compared with those of their monomethyl counterparts as well as with those of their saturated analogues. X-Ray data and energy calculations revealed a highly conservative conformation of the dehydro dimethylamides, which is located in a high-energy region of the Ramachandran map.

Ograniczanie wyników

1 Acta Biochimica Polonica

1 Broda M. A.

1 Dybala I.

1 Koziol A. E.

1 Rzeszotarska B.

1 Siodlak D.

1 2001

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Conformational properties of N',N'-dimethylamides of N-acetyldehydroalanine and N-acetyl-[Z]-dehydrophenylalanine