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Hydrochemical studies were performed from May to December 2004 at four stations in the polymictic, polyhumic Siemianówka Dam Reservoir (SDR) located on the upper Narew River in northeastern Poland. The total manganese (TMn) concentrations in the reservoir waters varied from 118 μg/dm3 to 638 μg/dm3 , and their increased values are caused by forming complexes with organic matter present in waters flowing from wetlands and forests. Until the moment when the maximum manganese concentration occurred in the reservoir, its upper part was characterized by the higher manganese concentration than the lower part. A long retention time of water delays the occurrence of total manganese maximum in the lower part in SDR. Maximal TMn concentrations were noted in the lower part of the reservoir in the end of summer, while minimal for the upper part in winter. The organic dissolved manganese fractions (ODMn), were the largest part of TMn, slightly less was the particular manganese (PMn) fraction, and the smallest part constituted the reactive dissolved manganese fraction (RDMn). Low concentrations of reactive manganese in winter are due to a low pH value and low concentrations of dissolved organic matter (DOC). Manganese sorption on colloids increases in summer and is accompanied by a pH increase during an intensive photosynthesis of algae and cyanoprocaryota.
Quantitative and qualitative differentiation of organic matter in the bottom sediments are analysed. It has been demonstrated that the coverage of the immediate catchment basin affects the composition of the organic matter in the sediments in the littoral and the changes in the composition of organic matter with depth. The conditions existing in the examined lake favour the formation of humic acids in the profundal zone of autochtonie origin.
In the direction of the frontal dam of the reservoir mean concentrations of substances dissolved in water were reduced while those of oxygen, phosphorus, and ammonium ions increased, bringing about distinct differences between the three parts of the impoundment, conditioned by the seasonality of water inflow to the reservoir. In summer and autumn in the different parts of the reservoir a similar chemical composition of waters was observed, while in winter and during the spring rise it was distinctly differentiated.
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