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Soil subject to a three-year pot experiment was analyzed, in which the following factors were considered: (i) soil contamination with nickel (0, 75, 150 and 225 mg Ni kg⁻¹ of soil); (ii) liming (0 Ca and Ca in a dose calculated according to 1 Hh of soil); (iii) organic fertilization (with no organic fertilization, rye straw and brown coal from the Turów coalmine). The test plant was orchardgrass, which was harvested in the amount of four cuts each year of the experiment. The copper and zinc fractions were assessed using the BCR method, whereas the pH was calculated using the potentiometer method. The total content of copper and zinc in the analyzed soil did not exceed the values of the geochemical background of the soils of Poland. No impact of the varied content of nickel in the soil on the total content and distribution of Cu and Zn was found in the investigated fractions. Liming caused an increase in the total content of zinc in the analyzed soil and a decrease in the content of Cu and Zn in the F1 fraction. The straw and brown coal caused an increase in the content of both metals in the soil in the F3 fraction.
The objective of the study was to evaluate the impact of liming and the application of waste organic material, i.e. sewage sludge, on the content and distribution of nickel in the fractions extracted with the BCR procedure from soil contaminated with this metal. The study was carried out on soil after a 3-year pot experiment, which included the following factors: I – nickel used in the incremental amounts 0, 50, 100 mg Ni kg-1 soil; II – liming (0 Ca and Ca according to 1 Hh of soil); and III – the addition of sewage sludge (with and without the addition of sewage sludge at the introducing dose of 2 g C kg-1 soil). The test plant was cocksfoot harvested four times (four swaths) in each plant growing season. The total content of nickel was determined with ICP-AES and its fractions with the three-stage BCR procedure. The introduction of nickel into the soil resulted in an increase in its total content and in all fractions as well as in its percentage in the exchangeable fraction. Liming reduced the mobility of nickel and decreased its content in the reducible fraction, whil inccreasing it in the residual fraction. The application of sewage sludge contributed to an increase in the total content of nickel in soil and its proportion in the oxidizable fraction. Liming and the application of sewage sludge reduced the mobility of nickel. Lime and waste organic material (i.e. sewage sludge) were found to be suitable materials for reduction of the mobility of nickel in soil contaminated with this metal.
Our objective has been to determine the total content of magnesium, iron, chromium and zinc, as well as the heavy metal fractions in selected natural fertilisers, such as swine and bovine manure and poultry litter from laying hens and broilers. The total content of the metals was determined by the ICP-AES method following dry mineralisation in a muffle furnace at 450°C and dissolving the ash in HCl (1:1). Fractions of Fe, Zn and Cr were isolated by the 3-step sequential fractionation method proposed by the Community Bureau of Reference (BCR). This study has shown that the analysed organic materials had different content of the determined metals. The largest amount of Mg was found in litter from laying hens and the largest amounts of Fe, Cr and Zn were in litter from broiler chickens. The smallest amount of Mg was found in swine manure, Fe and Cr were the least abundant in litter from laying hens, and the lowest Zn content was in bovine manure. The content of these four heavy metals was significantly differentiated by the origin of fertiliser. The exchangeable fraction F1 had the smallest share in the total Fe content among all the fertilisers. As for chromium, this fraction made the smallest contribution to the total Cr content in litter from laying hens and broilers while the reducible fraction F2 was the smallest part of the total content in both types of manure. Fraction F1 of zinc was the smallest in the total content in swine and bovine manure and while the oxidisable fraction F3 made up the smallest share in the total content of this metal in litter from broilers.
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