The effects of some inorganic and organic species on oxidation with atmospheric oxygen of manganese in natural water

• Autorzy: Tufekci N. , Celik S.O.
• Języki publikacji: EN

Abstrakty

EN

Manganese (Mn) is an important element in environmental geochemistry. In many natural aquatic systems, high concentrations of manganese are present with organic and inorganic matters. The oxidation of Mn(II) in aqueous systems has been extensively studied. But inorganic and organic matter effects on oxidation have not been fully clarified. It is clear that Mn(II) oxidation in the presence of inorganic and organic matter runs differently. The aim of this study is to investigate the effects of some inorganic species (Mg(II), Ca(II), Ni(II), Zn(II)) and also some organic species (gallic acid and tartaric acid) on oxidation of manganese Mn(II) with atmospheric oxygen in natural water. Experimental studies have been carried out in a three-stage batch system. All experiments have been conducted in a condition of alkalinity: 1.2・10⁻² eq/L, pH=9.5, T=25⁰C, pO₂=0.21 atm. According to the results, magnesium and calcium concentrations of 50 mg/L and above slowed down the oxidation of Mn(II), and nickel and zinc did not have any significant effect on oxidation. Similarly, it was found that gallic acid decelerated oxidation when tartaric acid did not have any important effect on oxidation.

• Wydawca: -
• Czasopismo: Polish Journal of Environmental Studies
• Rocznik: 2011
• Tom: 20
• Numer: 1
• Opis fizyczny: p.201-207,fig.,ref.

Twórcy

autor

Tufekci N.

• Faculty of Engineering, Department of Environmental Engineering, Istambul University, Avcilar Kampusu, 34320, Istambul, Turkey

autor

Celik S.O.

Bibliografia

• 1. MORGAN J.J. Chemical equilibria and kinetic properties of manganese in natural waters. S.D. faust and J.V.Hunter, Ed., Principles and Applications of Water Chemistry. Wiley and Sons, Inc.New York, 1967.
• 2. CARPENTER R. Quantitative electron spin resonance (ESR) determinations of forms and total amounts of Mn in aqueous environmental samples. Geochim. Cosmochim. Acta 47, 875, 1983.
• 3. DAVIES S.H.R. Mn(II) oxidation in the presence of metal oxides. Doctoral Thesis by Simon Henry Richard Davies, California Institute of Technology, Pasadena, California, 1985.
• 4. STONE A.T. The Reduction and Dissolution of Mn(II) and Mn(IV) Oxides by Organics, California Institute of Technology, Doctoral Thesis by Stone A.T., Pasadena, California, 1983.
• 5. SUNDA W.G., HUNTSMAN S.A., HARVEY G.R. Photoreduction of manganese oxides in seawater and its geochemical and biological implications. Nature 301, 234, 1983.
• 6. STONE A.T., MORGAN J.J. Reduction and Dissolution of Manganese(I I I) and Manganese(IV) Oxides by Organics: 2. Survey of the Reactivity of Organics Environ. Sci. Technol. 18, 617, 1984.
• 7. JUN Y.S., MARTIN S.T. Microscopic observations of reductive manganite dissolution under oxic conditions. Environ. Sci. Technol. 37, 2363, 2003.
• 8. VAN CAPPALLEN P., WANG P. Cycling of iron and manganese in surface sediments: A general theory for the coupled transport and reaction of carbon, oxygen, nitrogen, sulphur, iron and manganese. American Journal of Science. 296, 197, 1996.
• 9. HEM J.D. Chemistry of Manganese in Natural Water: Chemical Equilibria and Rates of Manganese Oxidation, U.S. Geological Survey, pp. 64, 1963.
• 10. MORGAN J.J., STUMM W. Oxygenation of manganese in aqueous systems. American Chemical Society 145th National Meeting, 13-16. Reprints, Division of Water, Air, and Waste Chemistry, 1963.
• 11. MORGAN J.J. Chemistry of Aqueous Manganese II and IV. Ph.D. thesis, Harvard University. Cambridge, Massachusetts, 1964.
• 12. DİEM D., STUMM W. Is dissolved Mn2+ being oxidized by O2 in absence of Mn-bacteria or surface catalysts? Geochim. Cosmochim. Acta 48, 1571, 1984.
• 13. Water Quality and Treatment, 4th ed., American Water Works Association, Mc Graw-Hill Inc., 1990.
• 14. TUFEKCİ N., SARIKAYA H. Z. Catalytic effects of high Fe(III) concentrations on Fe(II) oxidation. Water Science and Technology, 34, (7-8), 389, 1996.
• 15. AYDIN S., TUFEKCİ N., ARAYICI S., OZTURK İ. Catalytic Effects of High Mn(IV) Concentrations on Mn(II) Oxidation Water Science and Technology, 42, (1-2), 387,2000.
• 16. SUNG W., MORGAN J. J. Oxidative removal of Mn(II) from solution catalyzed by the lepidocrocite surface. Geochim. Cosmochim. Acta 45, 2377, 1981.
• 17. SINGH S.K., SUBRAMANIAN V. Hydrous Fe and Mn oxides –scavengers of heavy metals in the aquatic environment. CRC Crit Rev. in Environ. Control. 1, 33, 1984.
• 18. MADDEN A. S., HOCHELLA JR. M. F. A test of geochemical reactivity as a function of mineral size: Manganese oxidation promoted by hematite nanoparticles, Geo. Chim. Cocmochim. Acta. 69, 389, 2005.
• 19. MORGAN J. J. Kinetics of reaction between O2 and Mn(II) species in aqueous solutions. Geochimica et Cosmochimica Acta. 69, (1), 35, 2005.
• 20. STUMM W., GİOVANOLİ R. On the nature of particulate manganese in simulated lake waters. Chimia 30, 423, 1976.
• 21. SUNG W. Catalytic Effects of the Y-FeOOH (lepidocrocite) Surface on the Oxygenation Removal Kinetics of Fe(II) and Mn(II), California Institute of Technology, Doctoral Thesis by Windsor Sung., Pasadena, California, 1980.
• 22. DAVİES S.H.R., MORGAN J.J. Manganese (II) oxidation kinetics on metal oxide surface. J.Colloid Interfac. Sci. 129, 63, 1989.
• 23. SANTANA-CASIANO J. M., GONZALEZ-DAVILA M., RODRIGUEZ M. J., MILLERO F. J. The effect of organic compounds in the oxidation kinetics of Fe(II). Marine Chemistry 70, 211, 2000.
• 24. APHA (American Public Health Association), AWWA (American Water Works Association), WPCF. Standard methods for the examination of water and wastewater. 20th edition, Washington, DC. 1998.
• 25. TUFEKCI N., DEMIR G., OZGUL G., KINACI C. The effect of organic matters on ferrous oxidation. Fresenius Environmental Bulletin. 12, (7), 771, 2003.
• 26. YASAVUL E., TUFEKCI N., DEMIR G. The effect of organic matters on manganese oxidation. Fresenius Environmental Bulletin. 11, (10b), 874, 2002