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2010 | 19 | 5 |

Tytuł artykułu

Environmental degradation of ramie fibre reinforced biocomposites

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
The estimation of environmental degradability of different ramie fibre reinforced biocomposites in Baltic Sea water and in compost with activated sludge under natural conditions is the subject of this paper. The characteristic parameters of environments were monitored during incubation time and their influence on the rate of degradation of biocomposites was discussed. The degradation processes of two kinds of biocomposites, ramie fibre/Ecoflex® and ramie fibre/cellulose nanofibre reinforced corn starch resin, were studied by macro- and microscopic observations of polymer surfaces, changes of weight, and tensile strength during incubation under natural conditions. The macro and microscopic observations and weight changes confirmed the decrease of the tensile strength both of the composites after incubation in compost and in sea water. It was demonstrated that the biocomposites with natural fibre of ramie were degraded in compost faster than in sea water, due to different microbial communities. The ramie/Ecoflex® biocomposite was degraded more distinctly than ramie/cellulose nanofibre reinforced corn starch resin biocomposite in both natural environments.

Wydawca

-

Rocznik

Tom

19

Numer

5

Opis fizyczny

p.937-945,fig.,ref.

Twórcy

autor
  • Department of Chemistry and Industrial Commodity Science, Faculty of Business Administration and Commodity Science, Gdynia Maritime University, Morska 83, 81-225 Gdynia, Poland
autor
  • Department of Chemistry and Industrial Commodity Science, Faculty of Business Administration and Commodity Science, Gdynia Maritime University, Morska 83, 81-225 Gdynia, Poland
autor
  • Department of Chemistry and Industrial Commodity Science, Faculty of Business Administration and Commodity Science, Gdynia Maritime University, Morska 83, 81-225 Gdynia, Poland
autor
  • Polymer Technology Department, Chemical Faculty, Gdansk University of Technology, Narutowicza 11/12, 80-952 Gdansk, Poland
  • Department of Polymer Science and Rubber Technology, Cochin University of Science and Technology, Cochin-22, Kerala, 682 022 - India
autor
  • Department of Mechanical Engineering, Yamaguchi University Tokiwadai, Ube, Yamaguchi 755-8611, Japan
autor
  • School of Chemical Sciences, Mahatma Gandhi University, Priyadarshini Hills P.O., Kottayam, Kerala, 686 560 - India

Bibliografia

  • 1. SGRICCIA N., HAWLEY M. C., MISRA M. Characterization of natural fibre surfaces and natural fibre composites, Composites Part A 39, 1632, 2008.
  • 2. BURGUENO R., QUAGLIATA M. J., MISRA M. G, MOHANTY A. K., MISRA M., DRZAL L. T. Sustainable Cellular Biocomposites from Natural Fibres and Unsaturated Polyester Resin for Housing Panel Applications, J. Polym. Environ. 13, (2), 139, 2005.
  • 3. BRUHLMANN F., LEUPIN M., ERISMANN K. H., FIECHTER A. Enzymatic degumming of ramie bast fibres, J. Biotech. 76, (1), 43, 2000.
  • 4. GODA K., SREEKALA M. S., GOMES A., KAJI T., OHGI J. Improvement of plant based natural fibres for toughening green composites – Effect of load application during mercerization of ramie fibres, Composites Part A 37, 2213, 2006.
  • 5. CLEMONS C. M., CAULFIELD D. F. Functional Fillers for Plastics, Part III: Natural Fibres, Weinheim: Viley-VCH Verlag GMbH&Co. KgaA, pp. 195-207, 2005.
  • 6. WITT U., EINIG T., YAMAMOTO M., KLEEBERG I., DECKWER W. D., MULLER R. J. Biodegradation of aliphatic–aromatic copolyesters: evaluation of the final biodegradability and ecotoxicological impact of degradation intermediates, Chemosphere 44, (2), 289, 2001.
  • 7. MULLER R., KLEEBERG I., DECKWER W. Biodegradation of polyesters containing aromatic constituents, J. Biotech. 86, (2), 87, 2001.
  • 8. MARTEN E., MULLER R., DECKWER W. Studies on the enzymatic hydrolysis of polyesters. II. Aliphatic–aromatic copolyesters, Polym. Degrad. and Stab. 88, (3), 371, 2005.
  • 9. KRASOWSKA K., RUTKOWSKA M., KOWALCZUK M. Compostability of polymeric materials based on aliphaticaromatic copolyester under natural weather depending conditions, Proceedings of International Conference (Bio)Degradable Polymers from Renewable Resources, pp. 162-169, 2008.
  • 10. LU Y., WENG L., CAO X. Morphological, thermal and mechanical properties of ramie crystallites-reinforced plasticized starch biocomposites, Carbohydrate Polym. 63, (2), 198, 2006.
  • 11. STOLT M., KRASOWSKA K., RUTKOWSKA M., JANIK H., ROSLING A., SODERGARD A. More on the poly(Llactide) prepared by using ferrous acetate as catalyst, Polym. Internat. 54, 362, 2005.
  • 12. JANIK H. Microscopy in the studies of polymer biodegradation, Macromol. Symp. 130, 179, 1998.
  • 13. RUTKOWSKA M., KRASOWSKA K., HEIMOWSKA A., STEINKA I., JANIK H. Degradation of polyurethanes in sea water, Polym. Degrad. Stab. 76, (2), 233, 2002.
  • 14. LENZ W. R. Biodegradable Polymers, Berlin, Springer- Velay, 1993.
  • 15. HAUG R. T. The practical handbook of compost engineering, London, Lewis, 1993.
  • 16. WITT U. Biodegradation and ecotoxicity of copolyesters, Proceedings of 7th Conference Biodegradable Polymers, I1- I15, 2000.
  • 17. HEIMOWSKA A. Degradation of a selected polymeric materials in sea water, PhD Thesis, Gdynia 2006 [In Polish].
  • 18. LI S., TENON M., GARREAU H., BRAUD C., VERT M. Enzymatic degradation of stereocopolymers derived from l-, dl- and meso-lactides, Polym. Degrad. Stab. 67, (1), 85, 2000.
  • 19. ARBELAIZ A., FERNANDEZ B., RAMOS J. A., RETEGI A., LLANO-PONTE R., MONDRAGON I. Mechanical properties of short flax fibre bundle/polypropylene composites: Influence of matrix/fibre modification, fibre content, water uptake and recycling, Compos. Sci. Technol. 65, (10), 1582, 2005.
  • 20. SZOSTAK-KOTOWA J. Biodeterioration of textiles, Inter. Biodeter. Biodegrad. 53, (3), 165, 2004.
  • 21. ANGELINI L. G., LAZZERI A., LEVITA G., FONTANELLI D., BOZZI C. Ramie (Boehmeria nivea (L) Gaud.) and spanish broom (Spartium junceum L.) fibres for composite materials: agronomical aspects, morphology and mechanical properties, Indust. Crops. Prod. 11, (2-3), 145, 2000.

Typ dokumentu

Bibliografia

Identyfikatory

Identyfikator YADDA

bwmeta1.element.agro-de241fa1-7f96-4526-9af2-3c30e4b6aa83
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