Adsorption characteristics of magnesium-modified bentonite clay with respect to acid blue 129 in aqueous media

• Autorzy: Hussain S. , Ullah Z. , Gul S. , Khattak R. , Kazmi N. , Rehman F. , Khan S. , Ahmad K. , Imad M. , Khad A.
• Języki publikacji: EN

Abstrakty

EN

Locally available bentonite clay has been modified by magnesium and used to eliminate acid blue 129 from aqueous solutions. The adsorption was studied under different experimental conditions such as dye concentrations, temperature, and shaking time. The adsorption of the dye increased with time and followed the pseudo-first-order kinetic with rate constant “k” 0.126 min-1 at 283 K. Thermodynamic parameters such as ΔH°, ΔS°, and ΔG° were calculated from the slope and intercept of the linear plots of ln K against1/T. Analysis of adsorption results obtained at temperatures of 283, 293, 303, and 313 K showed that the adsorption pattern on bentonite seems to follow Langmuir and Freundlih. The increase in temperature reduces adsorption capacity by magnesium-modified bentonite due to the enhancement of the desorption step in the mechanism. The activation energy of the adsorption process was found to be 3.55 kJ mol-1. The Mg-bentonite showed better adsorption than Ba and Al-bentonite. Our study reveals that abundantly available local clay may be used to eliminate dyes from aqueous solutions.

• Wydawca: -
• Czasopismo: Polish Journal of Environmental Studies
• Rocznik: 2016
• Tom: 25
• Numer: 5
• Opis fizyczny: p.1947-1953,fig.,ref.

Twórcy

autor

Hussain S.

• Faculty of Materials and Chemical Engineering, GIK Institute of Engineering Sciences and Technology Topi, 23460, KPK, Pakistan

autor

Ullah Z.

• Institute of Chemical Sciences, University of Peshawar, 25120, KPK, Pakistan

autor

Gul S.

• Department of Biochemistry, Shaheed Benazir Bhutto Women’s University, Peshawar, KPK, Pakistan

autor

Khattak R.

• Department of Biochemistry, Shaheed Benazir Bhutto Women’s University, Peshawar, KPK, Pakistan

autor

Kazmi N.

• Institute of Chemical Sciences, University of Peshawar, 25120, KPK, Pakistan

autor

Rehman F.

• Interdisciplinary Research Center In Biomedical Materials (IRCBM), COMSAT Institute, Lahore, Pakistan

autor

Khan S.

• Institute of Chemistry, State University of Campinas, CEP 13083-970 Campinas, SP, Brazil

autor

Ahmad K.

• Institute of Chemistry, State University of Campinas, CEP 13083-970 Campinas, SP, Brazil

autor

Imad M.

• Faculty of Materials and Chemical Engineering, GIK Institute of Engineering Sciences and Technology Topi, 23460, KPK, Pakistan

autor

Khad A.

• Institute of Chemical Sciences, University of Peshawar, 25120, KPK, Pakistan

Bibliografia

• 1. Kadirvelu K., Kavipriya M., Karthika C., Radhika M., Vennilamani N., Pattabhi S. Utilization of various agricultural wastes for activated carbon preparation and application for the removal of dyes and metal ions from aqueous solutions. Bioresour. Technol. 87, 129, 2003.
• 2. Won S.W., Choi S.B., Yun Y-S. On the reason why acid treatment of biomass enhances the biosorption capacity of cationic pollutants. Korean J. Chem. Eng. 31, 68, 2013.
• 3. Robinson T., Chandran B., Nigam P. Effect of pretreatments of three waste residues, wheat straw, corncobs and barley husks on dye adsorption. Bioresour. Technol. 85, 119, 2002.
• 4. Mittal A., Thakur V., Mittal J., Vardhan H. Process development for the removal of hazardous anionic azo dye Congo red from wastewater by using hen feather as potential adsorbent. Desalin. Water Treat. 52, 227, 2014.
• 5. Zhang J., Chen S., Zhang Y., Quan X., Zhao H., Zhang Y. Reduction of acute toxicity and genotoxicity of dye effluent using Fenton-coagulation process. J. Hazard. Mater. 274, 198, 2014.
• 6. De Luna L.A.V., da Silva T.H.G., Nogueira R.F.P., Kummrow F., Umbuzeiro G.A. Aquatic toxicity of dyes before and after photo-Fenton treatment. J. Hazard. Mater. 276, 332, 2014.
• 7. Alves de Lima R.O., Bazo A.P., Salvadori D.M.F., Rech C.M., de Palma Oliveira D., de Aragão Umbuzeiro G. Mutagenic and carcinogenic potential of a textile azo dye processing plant effluent that impacts a drinking water source. Mutat. Res. - Genet. Toxicol. Environ. Mutagen. 626, 53, 2007.
• 8. Verma A.K., Dash R.R., Bhunia P. A review on chemical coagulation/flocculation technologies for removal of colour from textile wastewaters. J. Environ. Manage. Jan 93, 154, 2012.
• 9. Ferella F., De Michelis I., Zerbini C., Vegli ò F. Advanced treatment of industrial wastewater by membrane filtration and ozonization. Desalination. 313, 1, 2013.
• 10. Asghar A., Abdul Raman A.A., Wan Daud W.M.A. Advanced oxidation processes for in-situ production of hydrogen peroxide/hydroxyl radical for textile wastewater treatment: a review. J. Clean. Prod. 87, 826, 2015.
• 11. Zodi S., Merzouk B., Potier O., Lapicque F., Leclerc J.P. Direct red 81 dye removal by a continuous flow electrocoagulation/flotation reactor. Sep. Purif. Technol. 108, 215, 2013.
• 12. Kurt E., Koseoglu -Imer D.Y., Dizge N., Chellam S., Koyuncu I. Pilot-scale evaluation of nanofiltration and reverse osmosis for process reuse of segregated textile dyewash wastewater. Desalination. 302, 24, 2012.
• 13. Gomes L., Miwa Douglas W., Malpass G.R.P, Motheo a.J. Electrochemical Degradation of the Dye Reactive Orange 16 using Electrochemical Flow-Cell. J. Brazilian Chem. Soc. 1, 2011.
• 14. Catanho M., Malpass G.R.P., Motheo A.J. Photoelectrochemical treatment of the dye reactive red 198 using DSA® electrodes. Appl. Catal. B Environ. Feb., 62, 193, 2006.
• 15. Mittal J., Thakur V., Mittal A. Batch removal of hazardous azo dye Bismark Brown Rusing waste material hen feather. Ecol. Eng. Nov. 60, 249, 2013.
• 16. Hussain S., Gul S., Khan S., ur Rehman H. Retention studies of chromium (VI) from aqueous solution on the surface of a novel carbonaceous material. Arab. J. Geosci. Nov; 6, 4547, 2012.
• 17. Mittal A., Kurup L.. Column operations for the removal and recovery of a hazardous dye “acid red - 27” from aqueous solutions, using waste rnateria!s - bottom ash and de-oiled soya. Ecol. Environ. Conserv. 12, 181, 2006.
• 18. Gupta V.K., Mittal A., Jain R., Mathur M., Sikarwar S. Adsorption of Safranin-T from wastewater using waste materials- activated carbon and activated rice husks. J. Colloid Interface Sci. 303, 80, 2006.
• 19. Santos S.C.R., Boaventura R.A.R. Adsorption modelling of textile dyes by sepiolite. Appl. Clay Sci. 42, 137, 2008.
• 20. Gupta V.K., Mittal A., Kurup L., Mittal J. Adsorption of a hazardous dye, erythrosine, over hen feathers. J. Colloid Interface Sci. 304, 52, 2006.
• 21. Ghaedi M., Nasab A.G., Khodadoust S., Sahraei R., Daneshfar A. Characterization of zinc oxide nanorods loaded on activated carbon as cheap and efficient adsorbent for removal of methylene blue. J. Ind. Eng. Chem. 21, 986, 2015.
• 22. Alver E., Metin A. ü. Anionic dye removal from aqueous solutions using modified zeolite: Adsorption kinetics and isotherm studies. Chem. Eng. J. 200-202, 59, 2012.
• 23. Sharma P., Borah D.J., Das P., Das M.R. Cationic and anionic dye removal from aqueous solution using montmorillonite clay: evaluation of adsorption parameters and mechanism. Desalin. Water Treat. 1, 2015.
• 24. Bhattacharyya K.G., Gupta S. Sen , Sarma G.K. Kinetics, equilibrium isotherms and thermodynamics of adsorption of Congo red onto natural and acid-treated kaolinite and montmorillonite. Desalin. Water Treat. 53, 530, 2013.
• 25. Chaari I., Feki M., Medhioub M., Bouzid J., Fakhfakh E., Jamoussi F. Adsorption of a textile dye “Indanthrene Blue RS (C.I. Vat Blue 4)” from aqueous solutions onto smectite-rich clayey rock. J. Hazard. Mater. 172, 1623, 2009.
• 26. Anirudhan T.S., Ramachandran M. Adsorptive removal of basic dyes from aqueous solutions by surfactant modified bentonite clay (organoclay): Kinetic and competitive adsorption isotherm. Process Saf. Environ. Prot. 95, 215, 2015.
• 27. Wang C.C., Juang L.C., Hsu T.C., Lee C.K., Lee J.F., Huang F.C. Adsorption of basic dyes onto montmorillonite. J. Colloid Interface Sci. 273, 80, 2004.
• 28. Velde B. Introduction to clay minerals. Springer Netherlands; 1992.
• 29. Shen Y-H. Preparations of organobentonite using nonionic surfactants. Chemosphere. Aug; 44, 989, 2001.
• 30. Mittal A., Gupta V.K. Adsorptive removal and recovery of the azo dye Eriochrome Black T. Toxicol. Environ. Chem. 1813, 2010.
• 31. Hussain S., Gul S., Khan S., Rehman H., Ishaq M., Khan A., Jan F.A., Din ZU. Removal of Cr(VI) from aqueous solution using brick kiln chimney waste as adsorbent. Desalin. Water Treat. Sep; 1, 2013.
• 32. Rehman M.S.U., Munir M., Ashfaq M., Rashid N., Nazar M.F., Danish M., Han J-I. Adsorption of Brilliant Green dye from aqueous solution onto red clay. Chem. Eng. J. Jul; 228, 54, 2013

Identyfikatory

DOI

10.15244/pjoes/62272