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2014 | 23 | 6 |

Tytuł artykułu

Optimization of solid-phase extraction for pretreatment of selected estrogens in sewage by response surface methodology

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
In order to increase the recoveries of steroid estrogens (SEs) for quantitative determination in sewage, response surface methodology (RSM) was adopted to optimize the solid-phase extraction (SPE) procedure. Quadratic models were established for predicting SE recoveries, and the effectiveness of models and the interaction of factors were analyzed. SE concentrations of typical sewage treatment plants (STPs) in Jiangsu province were detected under the optimized conditions. The optimal operating conditions of SPE were obtained with elution volume of 10.68 mL, a sample rate of 10.47 mL·min-1 and elution rate of 4.07 mL·min-1. The predicted recoveries were 81.63% for E1, 88.86% for E2, and 84.55% for EE2. SEs were detected in all the three STPs, and concentrations in the influents and effluents ranged from 13.4 to 78.0 ng·L-1 and from 5.3 to 20.5 ng·L-1, respectively.

Słowa kluczowe

Wydawca

-

Rocznik

Tom

23

Numer

6

Opis fizyczny

p.2287-2294,fig.,ref.

Twórcy

autor
  • School of Civil Engineering, Southeast University, Nanjing 210096, China
autor
  • School of Civil Engineering, Southeast University, Nanjing 210096, China
autor
  • School of Civil Engineering, Southeast University, Nanjing 210096, China
autor
  • School of Civil Engineering, Southeast University, Nanjing 210096, China
autor
  • School of Civil Engineering, Southeast University, Nanjing 210096, China
autor
  • School of Energy and Environment, Southeast University, Nanjing 210096, China

Bibliografia

  • 1. PURDOM C.E., HARDIMAN P.A., BYE V.V.J., ENO N.C., TYLER C.R., SUMPTER C.R. Estrogenic effects of effluents from sewage treatment works. Chem. Ecol. 8, 275, 1994.
  • 2. LIU R., ZHOU J.L., WILDING A. Simultaneous determi­nation of endocrine disrupting phenolic compounds and steroids in water by solid-phase extraction-gas chromatogra- phy-mass spectrometry. J. Chromatogr. A. 1022, 179, 2004.
  • 3. KUCH H.M., BALLSCHMITER K. Determination of endocrine-disrupting phenolic compounds and estrogens in surface and drinking water by HRGC-(NCI)-MS in the picogram per liter range. Environ. Sci. Technol. 35, 3201, 2001.
  • 4. ATKINSON S., ATKINSON M.J., TARRANT A.M. Estrogens from sewage in coastal marine environments. Environ. Health Perspect. 111, 531, 2003.
  • 5. BRADLEY P.M., BARBER L.B., CHAPELLE F.H., GRAY J.L., KOLPIN D.W., MCMAHON P.B. Biodegradation of 17P-estradiol, estrone and testosterone in stream sediments. Environ. Sci. Technol. 43, 1902, 2009.
  • 6. ZUEHLKE S., DUENNBIER U., HEBERER T., FRITZ B. Analysis of endocrine disrupting steroids: Investigation of their release into the environment and their behavior during bank filtration. Ground Water Monitor. Remed. 24, 78, 2007.
  • 7. METCALFE C. D., METCALFE T. L., KIPARISSIS Y., KOENIG B. G., KHAN C., HUGHES R. J., CROLEY T. R., MARCH R. E., POTTER T. Estrogenic potency of chemi­cals detected in sewage treatment plant effluents as deter­mined by in vivo assays with Japanese Medaka (Oryzias Latipes). Environ. Toxicol. Chem. 20, 297. 2001.
  • 8. SCHAFER A.I., NGHIEM L.D., WAITE T.D. Removal of the natural hormone estrone from aqueous solutions using nanofiltration and reverse osmosis. Environ. Sci. Technol. 37, 182, 2003.
  • 9. MES T.D., ZEEMAN G., LETTINGA G. Occurrence and fate of estrone, 17P-estradiol and 17a-ethynylestradiol in STPs for domestic wastewater. Environ. Sci. Biotechnol. 4, 275, 2005.
  • 10. KARPOVA T., PREIS S., KALLAS J. Selective photocat- alytic oxidation of steroid estrogens in water treatment: urea as co-pollutant. J. Hazard. Mater. 146, 465, 2007.
  • 11. JOHNSON A.C., BELFROID A., CORCIA A.D. Estimating steroid oestrogen inputs into activated sludge treatment works and observations on their removal from the effluent. Sci. Total Environ. 256, 163, 2000.
  • 12. LAI K.M., SCRIMSHAW M.D., LESTER J.N. Prediction of the bioaccumulation factors and body burden of natural and synthetic estrogens in aquatic organisms in the river sys­tems. Sci. Total Environ. 289, 159, 2002.
  • 13. FURUICHI T., KANNANB K., GIESY J., MASUNAGA S. Contribution of known endocrine disrupting substances to the estrogenic activity in Tama River water samples from Japan using instrumental analysis and in vitro reporter gene assay. Water Res. 38, 4491, 2004.
  • 14. CARGOUET M., PERDIZ D., MOUATASSIM-SOUALI A., TAMISIER-KAROLAK S., LEVI Y. Assessment of river contamination by estrogenic compounds in Paris area (France). Sci. Total Environ. 324, 55, 2004.
  • 15. KOLPIN D.W., FURLONG E.T., MEYER M.T., THUR- MAN E.M., ZAUGG S.D, BARBER L.B., BUXTON H.T. Pharmaceuticals, hormones, and other organic wastewater contaminants in U.S. streams, 1999-2000: A National Reconnaissance. Environ. Sci. Technol. 36, 1202, 2002.
  • 16. FU J.F., ZHAO Y.Q., WU Q.L. Optimising photoelectro- catalysis oxidation of fulvic acid using response surface methodology. J. Hazard. Mater. 144, 499, 2007.
  • 17. ROSSI D.T., ZHANG N. Automating solid-phase extrac­tion: current aspecs and future prospekts. J. Chromatogr. A. 885, 97, 2000.
  • 18. BEZERRA M.A., SANTELLI R.E., OLIVEIRA E.P., VIL­LAR L.S., ESCALEIRA L.A. Response surface methodolo­gy (RSM) as a tool for optimization in analytical chemistry. Talanta. 76, 965, 2008.
  • 19. PEDROUZO M., BORRULL F., POCURULL E., MARCE R.M. Estrogens and their conjugates: Determination in water samples by solid-phase extraction and liquid chromatogra- phy-tandem mass spectrometry. Talanta. 78, 1327, 2009.
  • 20. XIAO X,Y., MCCALLEY D,V., MCEVOY J. Analysis of estrogens in river water and effluents using solid-phase extraction and gas chromatography-negative chemical ion­ization mass spectrometry of the pentafluorobenzoyl deriva­tives. J. Chromatogr. A. 923, 195, 2001.
  • 21. WANG S., HUANG W., FANG G., HE J., ZHANG Y. On­line coupling of solid-phase extraction to high-performance liquid chromatography for determination of estrogens in environment. Analytica. Chimica. Acta. 606, 194, 2008.
  • 22. BELFROID A.C., VAN DER HORST A., VETHAAK A.D., SCHÄFER A.J., RIJS G.B.J, WEGENER J., COFINO W.P. Analysis and occurrence of estrogenic hormones and their glucuronides in surface water and waste water in The Netherlands. Sci. Total Environ. 225, 101, 1999.
  • 23. BUTWELL A.J., GARDNER M.J., GORDON W.S. Scoping study for a national demonstration programme on EDC removal. UK, UKWIR. 2005.

Uwagi

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Typ dokumentu

Bibliografia

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