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2013 | 27 | 3 |

Tytuł artykułu

Characteristics of rapeseed oil cake using nitrogen adsorption

Treść / Zawartość

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
Adsorption of nitrogen on the rapeseed oil cake and rapeseed oil cake with wheat meal extrudates was investigated. The results are presented as adsorption-desorption isotherms. The Brunauer-Emmet and Teller equation was used to analyse the experimental sorption data. To obtain estimates of the surface area and surface fractal dimension, the sorption isotherms were analyzed using the Brunauer-Emmet and Teller and Frenkel-Halsey-Hill equations. Mesopore analysis was carried out using the Dollimore and Heal method. The properties and surface characteristic of rapeseed oil cake extrudates are related to different basic properties of particular samples and duration of the extrusion process. Extrusion conditions lead to essential differences in particular products. For all kinds of rapeseed oil cakes the amount of adsorbed nitrogen was different, but for the rapeseed oil cake extrudates a large amount of adsorbed nitrogenwas observed. The average surface area of the rapeseed oil cake extrudates was about 6.5-7.0 m2 g-1, whereas it was equal to about 4.0-6.0 m2 g-1 for rapeseed oil cake with the wheat meal extrudates. In the case of non-extruded rapeseed oil cake and wheat meal, the dominant group included ca. 2 and 5 nmpores. The values of surface fractal dimension suggested that the surface of the extrudates was more homogenous than that of the raw material. Duration of the extrusion process to 80 s resulted in a decrease in the specific surface area, surface fractal dimension, and porosity of the extrudates.

Słowa kluczowe

Wydawca

-

Rocznik

Tom

27

Numer

3

Opis fizyczny

p.329-334,fig.,ref.

Twórcy

  • Institute of Agrophysics, Polish Academy of Sciences, Doswiadczalna 4, 20-290 Lublin, Poland
autor
  • Institute of Agrophysics, Polish Academy of Sciences, Doswiadczalna 4, 20-290 Lublin, Poland
autor
  • Institute of Agrophysics, Polish Academy of Sciences, Doswiadczalna 4, 20-290 Lublin, Poland
autor
  • Institute of Agrophysics, Polish Academy of Sciences, Doswiadczalna 4, 20-290 Lublin, Poland
autor
  • Polish Patent Office, Niepodleglosci 188/192, P.O. Box 203, 00-950 Warsaw, Poland

Bibliografia

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  • Dollimore D. and Heal G.R., 1964. An improved method for calculation of pore size distribution from adsorption data. J. Appl. Chem., 14, 109-114.
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  • Gregg S.J. and Sing K.S.W., 1978. Adsorption. Surface Area and Porosity. Acad. Press, London, N.Y.
  • Jamroz J., Hajnos M., and Sokołowska Z., 1999. Application of the mercury porosimetry to the porosity study of wheat floor extrudates. Int. Agrophysics, 13, 445-449.
  • Jaroniec M., 1995. Evaluation of the fractal dimension from a single adsorption isotherm. Langmuir, 11, 2316-2317.
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