Comparison of ion chromatography and isotachophoresis for the determination of selected anions in atmospheric wet deposition samples

• Autorzy: Klimaszewska K , Konieczka P. , Polkowska Z. , Gorecki T. , Namiesnik J.
• Języki publikacji: EN

Abstrakty

EN

Isotachophoresis using coupled capillaries (ITP) and ion chromatography (IC) – two analytical procedures for the determination of anions in atmospheric wet deposition – were compared. Both techniques were used for the determination of anions in small volume samples of dew, rime and fog deposition. IC was characterized by lower limits of detection and quantitation. The wide dynamic range of the technique made it suitable for accurate and precise determination of the analytes in samples of widely different matrices and analyte levels. No significant differences were observed between the two techniques in terms of time- and labor intensity.

Słowa kluczowe

EN

atmosphere; wet deposition; wet sample; anion; dew; fog; determination; ion chromatography; isotachophoresis; rime

• Wydawca: -
• Czasopismo: Polish Journal of Environmental Studies
• Rocznik: 2010
• Tom: 19
• Numer: 1
• Opis fizyczny: p.93-99,fig.,ref.

Twórcy

autor

Klimaszewska K

• Gdansk University of Technology, Narutowicza 11/12, 80-233 Gdansk, Poland

autor

Konieczka P.

autor

Polkowska Z.

autor

Gorecki T.

autor

Namiesnik J.

Bibliografia

• 1. SKARŻYŃSKA K., POLKOWSKA Ż., NAMIEŚNIK J. Sampling of atmospheric precipitation and deposits for analysis of atmospheric pollution. J. Autom. Metods. Manage. Chem. 1, 1, 2006.
• 2. KONIECZKA P., NAMIEŚNIK J. Quality assurance and quality control in the analytical chemical laboratory: a practical approach. CRC Press, 2009.
• 3. LOPEZ-RUIZ B. Advances in the determination of inorganic anions by ion chromatography. J. Chromatogr. A. 881, 607, 2000.
• 4. KENNDLER E. Capillary zone electrophoresis and isotachophoresis: A comparison by information theory. Chromatographia. 30, 713, 1990.
• 5. FORET F., KRIVANKOVA L., BOCEK P. Capillary Zone Electrophoresis. VCH Publishers, Inc., NY 1993.
• 6. VALSECCHI S.M., POLESELLO S. Analysis of inorganic species in environmental samples by capillary electrophoresis. J. Chromatogr. A. 834, 363, 1999.
• 7. JANDIK P., JONES W.R. Optimization of detection sensitivity in the capillary electrophoresis of inorganic anions. J. Chromatogr. A. 546, 431, 1991.
• 8. JACKSON P.E., HADDAD P.R. Capillary electrophoresis of inorganic ions and low-molecular-mass ionic solutes. TrAC. 12, 231, 1993.
• 9. HADDAD P.R. Comparison of ion chromatography and capillary electrophoresis for the determination of inorganic ions. J. Chromatogr. A. 770, 281, 1997.
• 10. PACAKOVA V., STULIK K. Capillary electrophoresis of inorganic anions and its comparison with ion chromatography. J. Chromatogr. A. 789, 169, 1997.
• 11. FUKUSHIA K., TAKEDAB S., CHAYAMAC K., WAKIDAB S-I. Application of capillary electrophoresis to the analysis of inorganic ions in environmental samples. J. Chromatogr. A. 834, 349, 1999.
• 12. ROCHA F. R., SILVA J.A.F., LAGO C.L., FORNARO A., GUTZ I.G.R. Wet deposition and related atmospheric chemistry in the Sao Paulo metropolis, Brazil: Part 1. Major inorganic ions in rainwater as evaluated by capillary electrophoresis with contactless conductivity detection. Atmos. Environ. 37, 105, 2003.
• 13. VALSECCHI S., TARTARI G., POLESELLO S. Determination of anions in rainwater by capillary electrophoresis with conductivity detection. J. Chromatogr. A. 760, 326, 1997.
• 14. KANIANSKY D., MASAR M., MARAK J., BODOR R. Capillary electrophoresis of inorganic anions. J. Chromatogr. A. 834, 133, 1999.
• 15. PACAKOVA V., COUFAL P., STULIK K. Capillary electrophoresis of inorganic cations. J. Chromatogr. A. 834, 257, 1999.
• 16. FUKUSHI K., TAKEDA S., CHAYAMA K., WAKIDA S.I. Application of capillary electrophoresis to the analysis of inorganic ions in environmental samples. J. Chromatogr. A. 834, 349, 1999.
• 17. MAINKA A., EBERT P., KIBLER M., PROKOP T., TENBERKEN B., BACHMANN K. Development of new methods for the analysis of carboxylic acids and carbonyl compounds in size classified raindrops by CE for application in modelling atmospheric processes. Chromatographia. 45, 158, 1997.
• 18. TENBERKEN B., BACHMANN K. Analysis of individual raindrops by capillary zone electrophoresis. J. Chromatogr. A. 755, 121, 1996.
• 19. TENBERKEN B., BACHMANN K. Development of new methods for the analysis of single cloud-, fog- and raindrops by capillary electrophoresis. J. Chromatogr. A. 775, 372, 1997.
• 20. TENBERKEN B., EBERT P., HARTMANN M., KIBLER M., MAINKA A., PROKOP T., RODER A., BACHMANN K.. Analysis of single raindrops in the nl range by capillary electrophoresis. J. Chromatogr. A. 745, 209, 1996.
• 21. BRUMLEY W.C. Techniques for handling environmental samples with potential for capillary electrophoresis. J. Chromatogr. Sci. 33, 670, 1995.
• 22. NIELEN M.W.F. Trace enrichment of environmental samples in capillary zone electrophoresis. TrAC. 12, 357, 1993.
• 23. SONG L., XU Z., KANG J., CHENG J. Analysis of environmental pollutants by capillary electrophoresis with emphasis on micellar electrokinetic chromatography. J. Chromatogr. A. 780, 297, 1997.
• 24. DABEK-ZLOTORZYNSKA E. Capillary electrophoresis in the determination of pollutants. Electrophoresis. 18, 2453, 1997.
• 25. TIMERBAEV A.R. Analysis of inorganic pollutants by capillary electrophoresis. Electrophoresis. 18, 185, 1997.
• 26. ZEMANN A.J. Conductivity detection in capillary electrophoresis. TrAC. 20, 346, 2001.
• 27. FUNG Y.S., LAU K.M. Development and validation of analytical methodology using capillary electrophoresis for separation and determination of anions in rainwater. Talanta. 45, 641, 1998.
• 28. MEISSNER T., EISENBEISS F., JASTORFF B. Determination of anionic trace impurities in acetic acid by two-dimensional capillary isotachophoresis. Fresen. J. Anal. Chem. 361, 459, 1998.
• 29. MADAJOVA V., TURCELOVA E., KANIANSKY D. Influence of poly(vinylpyrrolidone) on isotachophoretic separations of inorganic anions in aqueous electrolyte systems. J. Chromatogr. A. 589, 329, 1992.
• 30. PREST J.E., FIELDEN P.R. The simultaneous determination of chloride, nitrate and sulphate by isotachophoresis using bromide as a leading ion. Talanta. 75, 841, 2008.
• 31. MUSELLI M., BEYSENS D., MARCILLAT J., MILIMOUK I., NILSSON T., LOUCHE A. Dew water collector for potable water in Ajaccio. Atmos. Res. 64, 297, 2002
• 32. Elaboration of Slovak Technical Norms for Institute for Normalisation, Metrology and Testing for Slovak Republic, STN 75 7430 - “Izotachoforeticke stanovenie chloridov, dusicnanov, siranov, dusitanov, fluoridov a fosforecnanov vo vodach” (Isotachophoretic Determination of Chlorides, Nitrates, Sulphates, Nitrites, Fluorides and Phosphates in Waters).
• 33. MEISSNER T., EISENBEISS F., JASTORFF B. New leading electrolyte for the direct determination of chloride and other anions in analytical isotachophoresis. J. Chromatogr. A. 838, 81, 1999.