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2009 | 18 | 4 |

Tytuł artykułu

The role of Au-support interactions in creation of catalytic performance of Au-Ce 0.75 Zr 0.25 O2 in CO oxidation

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
The aim of this work was to obtain more detailed insight into the role of Au-support interactions in the creation of catalytic performance of Au/Ce0.75Zr0.25O₂ in CO oxidation. The Ce0.75Zr0.25O₂ oxide and Au/Ce0.75Zr0.25O₂ catalysts were synthesized, characterized by BET, XRD, HRTEM, AAS, TPR-H₂, and tested in CO oxidation. An approximate evaluation of H₂ consumption for the surface reduction of the studied samples was estimated, applying the model developed by Johnson and Mooi, based on the qualitative relationship between the magnitude of the capping oxygen and BET surface area.

Wydawca

-

Rocznik

Tom

18

Numer

4

Opis fizyczny

p.587-591,fig.,ref.

Twórcy

  • Facultad de Ciencias Exactas y Naturales, Universidad Nacional de Colombia, Sede Manizales, Colombia
  • G.I.A.N.T., Grupo de Investigacion en Aplicacion de Nuevas Tecnologias, Universidad Nacional de Colombia, Sede Manizales, Colombia
  • Institute of General and Ecological Chemistry, Technical University of Lodz, Zeromskiego 116, 90-924 Lodz, Poland

Bibliografia

  • 1. BOND G.C., THOMPSON D.T., Catalysis by Gold. Cat. Rev. – Sci. Eng. 41, 319, 1999.
  • 2. HASHMI A.S.K., HUTCHINGS G.J., Review-Gold catalysis. Angew. Chem. Int. Ed. 45, 7896, 2006.
  • 3. GRZYBOWSKA-ŚWIERKOSZ B., Nano-Au/oxide support catalysts in oxidation reactions: provenance of active oxygen species. Catal.Today 112, 3, 2006.
  • 4. TROVARELLI A. (Ed.), Catalysis by ceria and related materials. ICP, 2002.
  • 5. DOBROSZ-GÓMEZ I., KOCEMBA I., RYNKOWSKI J.M., Au/Ce1-xZrxO₂ as effective catalysts for low-temperature CO oxidation. Appl. Catal. B: Environ. 83, 240, 2008 [and references therein].
  • 6. JOHNSON M. F. L., MOOI J., Cerium dioxide crystallite sizes by temperature-programmed reduction. J. Catal. 103, 502, 1987; Erratum: J. Catal. 140, 612, 1993.
  • 7. GUZMAN J., CARRETTIN S., CORMA A., Spectroscopic evidence for the supply of reactive oxygen during CO oxidation catalyzed by gold supported on nanocrystalline CeO₂. J. Am. Chem. Soc. 127, 3286, 2005.

Typ dokumentu

Bibliografia

Identyfikatory

Identyfikator YADDA

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