Oxidation stability of biodiesel fuel produced from fatty wastes

• Autorzy: Sendzikiene E , Makareviciene V. , Janulis P.
• Języki publikacji: EN

Abstrakty

EN

The aim of this work was to examine possibilities to use wastes of animal fat and vegetable oil for the production of biodiesel fuel, evaluating the conformity of the product obtained to the oxidation stability requirements. The oxidation stability of rapeseed oil, linseed oil, tallow and lard fatty acid methyl esters samples and their mixtures was measured by commercial equipment Rancimat 743 applying accelerated oxidation test (Rancimat test) specified in EN 14112. It was found that fatty acid methyl esters of vegetable origin are more stable for oxidation comparing with methyl esters of animal origin. The optimal level of synthetic antioxidants such as butylated hydroxyanizole (BHA) and butylated hydroxytoluene (BHA) for stabilization of fatty acid methyl esters was determined to be 400 ppm (also using synergist – citric acid, 20% of the antioxidant quantity). Mixtures of methyl esters of animal and vegetable origin with antioxidants were more stable compared with pure products. The highest oxidation stability showed mixtures containing 80-90% of fatty acid methyl esters of animal fat and 10-20% of fatty acid methyl esters of vegetable oil with synthetic antioxidants added.

Słowa kluczowe

EN

waste; fatty waste; oxidative stability; environment pollution; induction period; antioxidant; biodiesel fuel; fatty acid methyl ester

• Wydawca: -
• Czasopismo: Polish Journal of Environmental Studies
• Rocznik: 2005
• Tom: 14
• Numer: 3
• Opis fizyczny: p.335-339,fig.,ref.

Twórcy

autor

Sendzikiene E

• Lithuanian University of Agriculture, Studentu 11, LT-53067 Akademija, Kaunas r., Lithuania

autor

Makareviciene V.

autor

Janulis P.

Bibliografia

• 1. Austrian Biofuels Institute. Review on Commercial production of Biodiesel World-wide. Report for the International Energy Agency. Vienna, Austria, 1998.
• 2. EN 14214:2003 Automotive fuels – Fatty acid methyl esters (FAME) for diesel engines – Requirements and test methods.
• 3. EN 14112:2003 Fat and oil derivatives – Fatty Acid Methyl Esters (FAME) Determination of oxidation stability (accelerated oxidation test).
• 4. PEDERSEN J. R., INGEMARSSON A., OLSSON J. O. Oxidation of Rapeseed Oil, Rapeseed Methyl Ester (RME) and Diesel Fuel Studied with GS/MS. Chemosphere, 38 (11), 2467, 1999.
• 5. LIANG CH., SCHWARZER K. Comparison of Four Accelerated Stability Methods for Lard and Tallow With and Without Antioxidants. Ibid., 75, 1441, 1998.
• 6. DU PLESIS L.M., DE VILLERS B.M., VAN DER WALT W.H. Stability studies on Methyl and Ethyl Fatty Acid Esters of Sunflowerseed Oil. J.Am.Oil.Chem.Soc., 62, 748, 1985.
• 7. THOMPSON J.C., PETERSON C.L., REECE D.L., BECK S.M. Two-Year Storage Study with Methyl and Ethyl Esters of Rapeseed. Trans ASAE., 41, 931, 1998.
• 8. HASENHUETTI G.L., WAN P.J. Temperature Effects on the Determination of Oxidative Stabilty with the Metrohm Rancimat. J.Am. Oil. Chem.Soc., 69, 525, 1992.
• 9. BONDIOLI P., GASPAROLI A., LANZANI A., FEDELI E., VERONESE S., SALA M. Storage Stability of Biodiesel. Ibid., 72, 699, 2001.
• 10. SIMKOVSKY N.M., ECKER A. Effect of Antioxidants on the Oxidative stability of Rapeseed Oil Methyl Esters. Erdol, Erdgas, Kohle, 115, 317, 1999.
• 11. CANAKCI M., MONYEM A., VAN GERPEN J. Accelerated Oxidation Processes in Biodiesel. Trans. ASAE, 42, 1565, 1999.
• 12. DUNN R.O. Effect of Oxidation under Accelerated Conditions on Fuel Properties of Methyl Soyate. J.Am. Oil. Chem. Soc., 79, 915, 2002.
• 13. EN 14214 Automotive fuels – Fatty acid methyl esters (FAME) for diesel engines – Requirements and test methods. European Committee for Standardization (CEN). Brussels, 2003.
• 14. EN 14103 Fat and oil derivatives – Fatty Acid Methyl Esters (FAME) – Determination of ester and linolenic acid methyl ester contents. European Committee for Standardization (CEN). Brussels, 2003.
• 15. ISO 9936 Animal and vegetable fats and oils – Determination of tocopherols and tocotrienols contents – Method using high-performance liquid chromatography. International Organization for Standardization (ISO). Geneva, 1997.
• 16. EN 14112 Fat and oil derivatives – Fatty Acid Methyl Esters (FAME) – Determination of oxidation stability (Accelerated oxidation test). European Committee for Standardization (CEN). Brussels, 2003.