PL EN


Preferencje help
Widoczny [Schowaj] Abstrakt
Liczba wyników
2005 | 14 | 6 |

Tytuł artykułu

Phenols degradation by Fenton reaction in the presence of chlorides and sulfates

Warianty tytułu

Języki publikacji

EN

Abstrakty

EN
Since they often inhibit abundant bacteriological populations in municipal wastewater treatment plants, alternative treatment methods should be investigated – including advanced oxidation processes. This paper studies the degradation of three representatives of phenolic compounds using the Fenton system in the presence of chlorides and sulfates: phenol, 2-chlorophenol and 2-nitrophenol. The presence of anions influenced degradation rates of all studied compounds, which is attributed to the reduction in hydroxyl radical generation due to the formation of iron-complexes as well as the formation of much less reactive inorganic radicals. Differences between degradation rates of studied compounds and their degradation products in comparison to the rates observed for pure components show higher resistance of formed intermediates in comparison to phenol or 2-nitrophenol. Additionally, it was found that present anions influence further biodegradation of phenolic compounds but not similarly for all the compounds.

Wydawca

-

Rocznik

Tom

14

Numer

6

Opis fizyczny

p.823-828,fig.,ref.

Twórcy

  • University of Gdansk, Sobieskiego 18, 80-952 Gdansk, Poland

Bibliografia

  • 1. GOGATE P. R., PANDIT A. B., A review of imperative technologies for wastewater treatment I: oxidation technologies at ambient conditions, Adv. Environ. Res. 8 (3-4) 501, 2004.
  • 2. CAREY J. H. An introduction to advanced oxidation processes (AOP) for destruction of organic wastewater. Water Pollut. Res. J. Canada. 27 (1), 1, 1992.
  • 3. ALHAKIMI G., GEBRIL S., STUDNICKI L. H. Comparative photocatalytic degradation using natural and artificial UV-light of 4-chlorophenol as a representative compound in refinery wastewater. J. Photochem. Photobiol, A: Chem. 157, 103, 2003.
  • 4. GLAZE W. M., KANG J. W. AND CHAPIN D. H. The chemistry of water treatment processes involving ozone, hydrogen peroxide and ultraviolet radiation. Ozone Sci. Eng. 9, 335, 1987.
  • 5. GULYAS H. Processes for the removal of recalcitrant organics from industrial wastewaters. Water. Sci. Technol. 36 (2-3) 9, 1997.
  • 6. MARTIN M. A., RAPOSO F., BORJA R., MARTIN A. Kinetic study of the anaerobic digestion of vinasse pretreated with ozone, ozone plus ultraviolet light, and ozone plus ultraviolet light in the presence of titanium dioxide. Proc. Biochem. 37, 699, 2002.
  • 7. STEPNOWSKI P., SIEDLECKA E. M., BEHREND P., JASTORFF B. Enhanced photo-degradation of contaminants in petroleum refinery wastewater. Water Res. 36 (9) 2167, 2002.
  • 8. STEPNOWSKI P., ZALESKA A. Comparison of different advanced oxidation processes for the degradation of room temperature ionic liquids, J. Photochem. Photobiol. A: Chem. 170, 45, 2005.
  • 9. WALLING C. Fenton reagent revisited, Acc. Chem. Res., 121, 1975.
  • 10. SYCHEV A. Y., ISAAK V. G. Iron compounds and the mechanisms of the homonogenous catalysis of the activation of O₂ and H₂O₂ and of oxidation of organic substrates. Russ. Chem. Rev., 64, 1105, 1995.
  • 11. SAFARZADEH-AMIRI A., BOLTEN J. R., CATER S. R. The use of iron in advanced oxidation processes, J. Adv. Oxid. Technol., 1 (1) 18, 1996.
  • 12. DE LAAT J., TRUONG G. L., LEGUBE B. A comparative study of the effects of chloride, sulfate and nitrate ions on the rates of decomposition of H₂O₂, and organic compounds by Fe (II)/H₂O₂ and Fe (III)/H₂O₂. Chemosphere 55, 715, 2004.
  • 13. PERA-TITUS M., GARCIA-MOLINA V., BANOS M. A., GIMENEZ J., ESPLUGAS S. Degradation of chlorophe nols by means of advanced oxidation processes: a general review. Appl. Catal. B: Environ. 47, 219, 2004.
  • 14. CHAMARRO E., MARCO A., ESPLUGAS S. Use of Fenton reagent to improve organic chemical biodegradability. Wat. Res. 35, 1047, 2001.
  • 15. KIWI J., PULGARIN C., PERINGER P. Effect of Fenton and photo-Fenton reaction on the degradation and biodegradability of 2- and 4-nitrophenols in water treatment. Appl. Catal. B: Environ. 3, 335, 1994.
  • 16. MARCO A., ESPLUGAS S., SAUM G. How and why combine chemical and biological processes for wastewater treatment. Water Science and Technology 35 (4), 321, 1997.
  • 17. KITIS M., ADAMS C. D., DAIGGER G. T. The effects of Fenton’s reagent pretreatment on the biodegradability of nonionic surfactants. Water Research 33, 2561, 1999.
  • 18. NAM K., RODRIGEZ W., KUKOR J. J. Enhanced degradation of polycyclic aromatic hydrocarbons by biodegradation combined with a modified Fenton reaction. Chemosphere, 45, 11, 2001.
  • 19. NETA P., HUIE R. E., ROSS A. B. rate constants for reactions for inorganic radicals in aqueous solution. J. Phys. Chem. Ref. data 17, 1027, 1988.
  • 20. KING D. W., FARLOW R. Role of carbonate speciation on the oxidation of Fe (II) by H₂O₂. Mar. Chem., 70, 201, 2000.
  • 21. LIPCZYŃSKA-KOCHANY E., SPRAH G., HARMS S. Influence of some groundwater and surface waters constituents on the degradation of 4-chlorophenol by the Fenton reaction. Chemosphere 30 (1), 9, 1995.
  • 22. LU M. C., CHEN J. N., CHANG C. P. Effect of inorganic ions on the oxidation of dichlorvos insecticide with Fenton’s reaction. Chemosphere 35, 2285, 1997.
  • 23. PIGNATELLO J. J. Dark and photoassisted Fe³⁺-catalysed degradation of chlorophenoxy herbicides by hydrogen peroxide. Environ. Sci. Technol., 26, 944, 1992.
  • 24. TRUONG G. L., DE LAAT J., LEGUBE B. Effect of chloride and sulfate on the rate of oxidation of ferrous ion by H₂O₂. Water Research 38, 2383, 2004.
  • 25. SIEDLECKA E. M., STEPNOWSKI P., JASTORFF B. Effect of H₂O₂ on characteristics and biological treatment of petroleum refinery wastewater. Fresenius Environ. Bull., 11 (5), 223, 2002.
  • 26. METCALF AND EDDY INC. Wastewater Engineering – treatment disposal and reuse, Int. ed.; McGraw-Hill Book Company, New York, 1991.

Typ dokumentu

Bibliografia

Identyfikatory

Identyfikator YADDA

bwmeta1.element.agro-article-b81fd135-5bc0-4bd6-9d66-3dc7bc9df3c2
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.